IP Library Granted Patent US 11,156,168
Granted Patent B2
US 11,156,168 · App. 16/337,073 · Granted Oct 26, 2021

Gas turbine plant having thermal decomposition of ammonia and pressurization of the decomposed gas and method thereof

Inventors: Masakazu Nose (Yokohama, JP); Hideyuki Uechi (Tokyo, JP); Satoshi Tanimura (Yokohama, JP)
Assignee: MITSUBISHI POWER, LTD.
F02C9/26F01K23/10F02C3/20F02C3/22F02C6/18F02C7/22F02C9/40
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Quick Facts
Patent No.
US 11,156,168
App. No.
16/337,073
Granted
Oct 26, 2021
Kind
B2
Abstract

A gas turbine plant is provided with a gas turbine, a heating device, a decomposition gas line, and a decomposition gas compressor. The heating device heats ammonia and thermally decomposes the ammonia to convert the ammonia into decomposition gas including hydrogen gas and nitrogen gas. The decomposition gas line sends the decomposition gas PG from the heating device to the gas turbine. The decomposition gas compressor increases the pressure of the decomposition gas to a pressure equal to or higher than a feed pressure at which the decomposition gas is allowed to be fed to the gas turbine.

Claims (47)

1. A gas turbine plant comprising:

a gas turbine that combusts fuel, is driven by combustion gas generated through combustion of the fuel, and exhausts the combustion gas as exhaust gas;

a heating device that heats ammonia and thermally decomposes the ammonia to convert the ammonia into decomposition gas including hydrogen gas and nitrogen gas;

a decomposition gas line that sends the decomposition gas flowing out of the heating device to the gas turbine; and

a decomposition gas compressor that is provided on the decomposition gas line and increases a pressure of the decomposition gas flowing out of the heating device to a pressure equal to or higher than a feed pressure at which the decomposition gas is allowed to be fed to the gas turbine.

2. The gas turbine plant according to claim 1 , further comprising:

a cooler that is provided on the decomposition gas line at a position closer to the heating device than the decomposition gas compressor is and cools the decomposition gas flowing out of the heating device.

3. The gas turbine plant according to claim 1 , further comprising:

a boost cooler that cools the decomposition gas of which the pressure is being increased by the decomposition gas compressor.

4. The gas turbine plant according to claim 1 ,

wherein the heating device includes a reactor that heats and thermally decomposes ammonia gas to generate the decomposition gas.

5. The gas turbine plant according to claim 4 ,

wherein the reactor includes a catalyst that comes in contact with the ammonia gas and facilitates the thermal decomposition of the ammonia gas.

6. The gas turbine plant according to claim 4 ,

wherein the heating device includes an evaporator that heats and vaporizes liquid ammonia to convert the liquid ammonia into the ammonia gas.

7. The gas turbine plant according to claim 6 ,

wherein the heating device includes a preheater that heats the liquid ammonia not yet heated by the evaporator.

8. The gas turbine plant according to claim 1 ,

wherein a pressure of the ammonia present in the heating device is lower than the feed pressure.

9. The gas turbine plant according to claim 1 , further comprising:

a pressure reducer that reduces a pressure of the ammonia and then sends the ammonia to the heating device.

10. The gas turbine plant according to claim 9 , further comprising:

a preheater that exchanges heat between the ammonia of which the pressure has been reduced by the pressure reducer and an external medium to heat the ammonia and then sends the ammonia to the heating device as ammonia gas.

11. The gas turbine plant according to claim 1 , further comprising:

a natural gas line that sends natural gas to the gas turbine as at least a part of the fuel; and

an adjuster that adjusts a ratio of a flow rate of the decomposition gas to a flow rate of all fuel gas including the natural gas and the decomposition gas supplied to the gas turbine.

12. The gas turbine plant according to claim 11 , further comprising:

a control device that instructs the adjuster of a value relating to the ratio of the flow rate of the decomposition gas to the flow rate of the all fuel gas that is a value predetermined according to a pressure of the ammonia present in the heating device.

13. The gas turbine plant according to claim 12 ,

wherein the predetermined value relating to the ratio of the flow rate of the decomposition gas to the flow rate of the all fuel gas is reduced as the pressure of the ammonia present in the heating device increases.

14. The gas turbine plant according to claim 1 , further comprising:

an exhaust gas line through which the exhaust gas exhausted from the gas turbine flows,

wherein the heating device includes a heat exchanger that is provided on the exhaust gas line and exchanges heat between the exhaust gas as a heat medium and the ammonia to heat the ammonia.

15. The gas turbine plant according to claim 14 , further comprising:

a boiler that is provided on the exhaust gas line and exchanges heat between water and the exhaust gas to heat the water and convert the water to steam,

wherein the exhaust gas line includes a first exhaust gas line and a second exhaust gas line,

the boiler is provided on the first exhaust gas line, and

the heat exchanger is provided on the second exhaust gas line.

16. The gas turbine plant according to claim 15 , further comprising:

a switcher that changes a flow of the exhaust gas between a first state where the exhaust gas flows through only the first exhaust gas line of the first and second exhaust gas lines and a second state where the exhaust gas flows through at least the second exhaust gas line.

17. An operating method for a gas turbine plant including a gas turbine that combusts fuel, is driven by combustion gas generated through combustion of the fuel, and exhausts the combustion gas as exhaust gas, the method comprising:

a heating step of heating ammonia and thermally decomposing the ammonia to convert the ammonia into decomposition gas including hydrogen gas and nitrogen gas;

a boosting step of increasing a pressure of the decomposition gas to a pressure equal to or higher than a feed pressure at which the decomposition gas is allowed to be fed to the gas turbine; and

a decomposition gas supply step of supplying the decomposition gas of which the pressure has been increased in the boosting step to the gas turbine as at least a part of the fuel.

18. The operating method for a gas turbine plant according to claim 17 , further comprising:

a cooling step of cooling the decomposition gas of which the pressure is not yet increased in the boosting step and increasing the pressure of the cooled decomposition gas in the boosting step.

19. The gas turbine plant according to claim 1 , wherein a pressure of the ammonia present in the heating device is lower than the feed pressure, and the pressure of the ammonia present in the heating device is equal to or greater than 0.3 MPa and less than 5 MPa.

Assignments (2)
CHANGE OF NAME Recorded Nov 6, 2020
From: MITSUBISHI HITACHI POWER SYSTEMS, LTD.
To: MITSUBISHI POWER, LTD.
Reel/Frame 054344/0001 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Mar 27, 2019
From: NOSE, MASAKAZU; UECHI, HIDEYUKI; TANIMURA, SATOSHI
To: MITSUBISHI HITACHI POWER SYSTEMS, LTD.
Reel/Frame 048713/0765 →
Priority Claims (1)
JP JP2016-218042 · Nov 8, 2016 · national
Continuity (1)
Related Publication 20200032676A1 · Jan 30, 2020
Cited By (9)
US 12,264,621 US 12,338,766 US 12,385,433 US 12,398,663 US 12,421,893 US 12,428,990 US 12,491,498 US 12,510,022 US 12,553,387