IP Library Granted Patent US 11,512,149
Granted Patent B2
US 11,512,149 · App. 16/338,848 · Granted Nov 29, 2022

Method and system for producing a polymer

Inventors: Wolfgang Fischer (Heidelberg, DE); Peter Ittemann (Dannstadt-Schauernheim, DE); Florian Patcas (Ludwigshafen, DE); Michael Ruf (Schwetzingen, DE)
Assignee: INEOS STYROLUTION GROUP GMBH
C08F2/01C08F2/06C08F2/34C08F212/10C08F220/14C08F220/44
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Quick Facts
Patent No.
US 11,512,149
App. No.
16/338,848
Granted
Nov 29, 2022
Kind
B2
Abstract

A method for producing a polymer from a first component and a second component using a reactor ( 50 ) offers technical advantages, wherein reaction heat produced in the reactor ( 50 ) is discharged via a boiling cooler ( 40 ) by supplying gaseous vapors produced in the reactor ( 50 ) to the boiling cooler ( 40 ). A product flow containing condensed vapors is returned to the reactor ( 50 ) from the boiling cooler ( 40 ) via a separation vessel ( 60 ), and an aqueous phase is separated from the product flow in the separation vessel ( 60 ). A system is provided for producing a polymer from a first component and a second component, comprising a reactor ( 50 ) and a boiling cooler ( 40 ) for discharging reaction heat produced in the reactor ( 50 ). A separation vessel ( 60 ) is arranged between the boiling cooler ( 40 ) and the reactor ( 50 ) such that a product flow containing condensed vapors is returned to the reactor ( 50 ) from the boiling cooler ( 40 ) via the separation vessel ( 60 ).

Claims (27)

1. A process for producing a (co)polymer from at least one first component and a second component by a reactor, where

heat of reaction arising in the reactor is removed by an evaporative cooler,

by feeding gaseous vapor formed in the reactor to the evaporative cooler wherein

a product stream containing condensed vapor is recirculated from the evaporative cooler via a separator vessel to the reactor, wherein

the product stream is cooled in a heat exchanger before entry into the separator vessel, wherein

an aqueous phase is separated off from the product stream in the separator vessel and wherein

the product stream flows from the separator vessel under the force of gravity into the reactor.

2. The process of claim 1 , wherein the first component contains styrene and wherein the second component contains acrylonitrile.

3. The process of claim 1 , wherein the second component contains acrylonitrile and wherein the first component contains alpha-methylstyrene.

4. The process of claim 1 , wherein the first component contains styrene and wherein the second component contains methyl methacrylate.

5. The process of claim 1 , wherein in the separator vessel a separation layer formed above the aqueous phase is separated off from the product stream.

6. The process of claim 1 , wherein the first component and/or the second component are introduced at least partly via the evaporative cooler and goes via the separator vessel from the evaporative cooler into the reactor.

7. The process of claim 1 , wherein the first component and/or the second component are partly introduced directly to the reactor.

8. The process of claim 6 , wherein the first component and/or the second component are fed at least partly in liquid form to the evaporative cooler and/or the reactor.

9. The process of claim 6 , wherein solvents and also unreacted monomers of the first component and/or the second component are recirculated from a condensation unit via a return conduit into the evaporative cooler.

10. A system for producing a polymer from at least one first component and a second component, comprising:

a reactor and;

an evaporative cooler for removing heat of reaction arising in the reactor, wherein

a separator vessel is arranged between the evaporative cooler and the reactor in such a way that a product stream containing condensed vapor is conveyed from the evaporative cooler via the separator vessel back into the reactor, wherein

a heat exchanger is arranged between the evaporative cooler and the separator vessel in such a way that the product stream is cooled in the heat exchanger before entry into the separator vessel, and wherein

the reactor, the evaporative cooler, and the separator vessel are arranged in such a way that the product stream flows from the separator vessel under the force of gravity into the reactor.

11. The system of claim 10 , wherein the evaporative cooler has at least one feed opening for introducing the first component and/or the second component.

12. The system of claim 10 , wherein the reactor, the evaporative cooler, and the separator vessel are arranged in such a way that vapor formed in the reactor ascends against the force of gravity into the evaporative cooler, and wherein

the product stream flows under the force of gravity into the separator vessel.

13. The process of claim 7 , wherein the first component and/or the second component are fed at least partly in liquid form to the evaporative cooler and/or the reactor.

14. The process of claim 7 , wherein solvents and also unreacted monomers of the first component and/or the second component are recirculated from a condensation unit via a return conduit into the evaporative cooler.

15. The process of claim 8 , wherein solvents and also unreacted monomers of the first component and/or the second component are recirculated from a condensation unit via a return conduit into the evaporative cooler.

Assignments (2)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Oct 21, 2021
From: RUF, MICHAEL; PATCAS, FLORIAN; FISCHER, WOLFGANG; ITTEMANN, PETER
To: INEOS STYROLUTION GROUP GMBH
Reel/Frame 057867/0905 →
FIRST LIEN INTELLECTUAL PROPERTY SECURITY AGREEMENT Recorded Apr 30, 2021
From: INEOS STYROLUTION GROUP GMBH
To: HSBC CORPORATE TRUSTEE COMPANY (UK) LIMITED
Reel/Frame 056103/0236 →
Priority Claims (1)
EP 16192168 · Oct 4, 2016 · regional
Continuity (1)
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