Polypropylene film structure having increased life time
The present invention refers to a structure comprising a biaxially oriented polypropylene (BOPP) film having at least one layer comprising a homopolymer of propylene which layer is in contact with an oil phase, the homopolymer of propylene has a) a content of isotactic pentads in the range from 95% to 98%, and b) a content of ash of not more than 30 ppm, based on the total weight of the homopolymer of propylene, characterized in that the oil phase has an absorbance value of ≤0.1, relative to the pure oil, as determined spectrophotometrically at a wavelength of 860 nm by the reduction of transmitted light intensity. The present invention further refers to the use of a biaxially oriented polypropylene (BOPP) film for making capacitors comprising said structure, wherein the oil phase has an absorbance value of ≤0.1, relative to the pure oil, as determined spectrophotometrically at a wavelength of 860 nm by the reduction of transmitted light intensity as well as the use of the homopolymer of propylene for increasing the life time of a capacitor.
1. A structure comprising a biaxially oriented polypropylene (BOPP) film having at least one layer comprising a homopolymer of propylene which layer is in contact with an oil phase, the homopolymer of propylene having:
a) a content of isotactic pentads in the range from 95% to 98%, and
b) a content of ash of not more than 30 ppm, based on the total weight of the homopolymer of propylene,
wherein the oil phase has an absorbance value of ≤0.1, relative to the pure oil, as determined spectrophotometrically at a wavelength of 860 nm by the reduction of transmitted light intensity,
wherein the BOPP film comprises additives selected from the group consisting of stabilisers, acid scavengers, nucleating agents and mixtures thereof, wherein the stabilisers are selected from the group consisting of 1,3,5-trimethyl-2,4,6-tris(3,5-di-tert-butyl-4-hydroxybenzyl)benzene in an amount of from 400 to 2000 ppm and a combination of 1,3,5-trimethyl-2,4, 6-tri s(3,5-di-tert-butyl-4-hydroxybenzyl)benzene in an amount of from 400 to 2000 ppm and butylhydroxytoluene in an amount of from 100 to 1000 ppm, based on the total weight of the homopolymer of propylene.
2. The structure according to claim 1 , wherein the BOPP biaxially oriented polypropylene (BOPP) film comprises from 400 to 5000 ppm, based on the total weight of the homopolymer of propylene, of the additives.
3. The structure according to claim 1 , wherein the stabilisers consist of 1,3,5-trimethyl-2,4, 6-tri s(3,5-di-tert-butyl-4-hydroxybenzyl)benzene in an amount of from 400 to 1000 ppm and a combination of 1,3,5-trimethyl-2,4,6-tris(3,5-di-tert-butyl-4-hydroxybenzyl)benzene in an amount of from 400 to 1000 ppm and butylhydroxytoluene in an amount of from 100 to 800 ppm, based on the total weight of the homopolymer of propylene.
4. The structure according to claim 1 , wherein the oil phase comprises at least 20% by weight of aromatic hydrocarbons.
5. The structure according to claim 4 , wherein the oil phase comprises cyclic aromatic hydrocarbons.
6. The structure according to claim 5 , wherein the oil phase comprises at least 50% by weight of cyclic aromatic hydrocarbons.
7. The structure according to claim 1 , wherein the absorbance consists essentially of polypropylene components.
8. The structure according to claim 1 , wherein the oil phase has an absorbance value of from 0.01 to 0.1, relative to the pure oil, as determined spectrophotometrically at a wavelength of 860 nm by the reduction of transmitted light intensity.
9. The structure according to claim 1 , wherein the absorbance value, determined spectrophotometrically at a wavelength of 860 nm, of the oil phase of the BOPP film is at least 50% below the absorbance value of the oil phase of a BOPP film which is free of a homopolymer of propylene having a content of isotactic pentads in the range from 95% to 98%, and a content of ash of not more than 30 ppm.
10. The structure according to claim 1 , wherein the structure is a capacitor.
11. The structure according to claim 1 , wherein the oil phase comprises toluene derivatives.
12. A method of forming a capacitor, the method comprising forming the structure as defined in claim 1 , wherein the oil phase has an absorbance value of ≤0.1, relative to the pure oil, as determined spectrophotometrically at a wavelength of 860 nm by the reduction of transmitted light intensity.
13. The method according to claim 12 , wherein forming the capacitor comprises the steps of flat winding the BOPP film and an aluminium foil to obtain a wound structure and impregnating the wound structure with an oil phase.
14. Use of a homopolymer of propylene having:
a) a content of isotactic pentads in the range from 95% to 98%, and
b) a content of ash of not more than 30 ppm, based on the total weight of the homopolymer of propylene,
in a structure as defined in claim 1 for increasing the life time of a capacitor, characterized in that the increased life time is achieved if the oil phase has an absorbance value of ≤0.1, relative to the pure oil, as determined spectrophotometrically at a wavelength of 860 nm by the reduction of transmitted light intensity.