Electrolytic copper foil for secondary battery and method for producing the same
The present invention relates to an electrolytic copper foil for a secondary battery and a method of producing the same, and more particularly, to an electrolytic copper foil for a secondary battery, which has little change in a physical property of a copper foil before and after vacuum drying in a process of producing an electrolytic copper foil, thereby exhibiting excellent cycle life in a battery test at a high-density negative electrode, and preventing cracking. The electrolytic copper foil for a secondary battery is produced from a plating solution containing Total Organic Carbon (TOC), zinc, and iron by using a drum, in which a ratio of the TOC to the zinc and the iron contained in the electrolytic copper foil follows Formula 1 below: TOC/(zinc+iron)=1.3 to 1.5 Formula 1
1. An electrolytic copper foil for a secondary battery, comprising:
a first layer that contains total organic carbon (TOC) and metallic additives that contain zinc, and iron,
wherein the first layer is produced from a plating solution containing TOC, zinc, and iron by using a drum, and wherein a concentration of the TOC contained in the plating solution is in a range of 450 ppm-1080 ppm,
wherein a ratio of the TOC to the zinc and the iron contained in the first layer follows Formula 1 below:
TOC/(zinc+iron)=1.3 to 1.5. Formula 1
2. The electrolytic copper foil of claim 1 , wherein a negative electrode active material is applied to the first layer and wherein, upon performing a vacuum drying process to the electrolytic copper foil having the negative electrode active material, a ratio of tensile strength and elongation percentages of the electrolytic copper foil having the negative electrode active material before and after the vacuum drying process follows Formula 2 below:
((tensile strength after vacuum drying/tensile strength before vacuum drying)/(elongation percentage after vacuum drying/elongation percentage before vacuum drying)×tensile strength after vacuum drying)=28 to 50 kgf/mm 2 , and Formula 2
wherein the vacuum drying process is performed at a temperature range of 110° C. to 150° C. for 6 hours to 10 hours.
3. The electrolytic copper foil of claim 1 , wherein, upon performing a vacuum drying process to the electrolytic copper foil, a ratio of tensile strength after the vacuum drying process to tensile strength before the vacuum drying process follows Formula 3 below:
Tensile strength after vacuum drying/tensile strength before vacuum drying=0.8 to 1.01, and Formula 3
wherein the vacuum drying process is performed at a temperature range of 110° C. to 150° C. for 6 hours to 10 hours.
4. The electrolytic copper foil of claim 1 , wherein, upon performing a vacuum drying process to the electrolytic copper foil, a ratio of an elongation percentage after the vacuum drying process to an elongation percentage before the vacuum drying process follows Formula 4 below:
Elongation percentage after vacuum drying/elongation percentage before vacuum drying=0.9 to 1.4, and Formula 4
wherein the vacuum drying process is performed at a temperature range of 110° C. to 150° C. for 6 hours to 10 hours.
5. The electrolytic copper foil of claim 1 , wherein tensile strength of the electrolytic copper foil at room temperature is 39.5 kgf/mm 2 to 48.4 kgf/mm 2 .
6. The electrolytic copper foil of claim 1 , wherein a thickness of the electrolytic copper foil is 4 μm to 12 μm.
7. The electrolytic copper foil of claim 1 , wherein an elongation percentage of the electrolytic copper foil is 2% to 18%.
8. The electrolytic copper foil of claim 1 , wherein a negative electrode active material is applied to the first layer and wherein, upon performing a vacuum drying process to the electrolytic copper foil having the negative electrode active material, a ratio of tensile strength and elongation percentages of the electrolytic copper foil having the negative electrode active material before and after the vacuum drying process follows Formula 2 below:
((tensile strength after vacuum drying/tensile strength before vacuum drying)/(elongation percentage after vacuum drying/elongation percentage before vacuum drying)×tensile strength after vacuum drying)=28 to 50 kgf/mm 2 . Formula 2
9. The electrolytic copper foil of claim 1 , wherein, upon performing a vacuum drying process to the electrolytic copper foil, a ratio of tensile strength after the vacuum drying process to tensile strength before the vacuum drying process follows Formula 3 below:
Tensile strength after vacuum drying/tensile strength before vacuum drying=0.8 to 1.01. Formula 3
10. The electrolytic copper foil of claim 1 , wherein, upon performing a vacuum drying process to the electrolytic copper foil, a ratio of an elongation percentage after the vacuum drying process to an elongation percentage before the vacuum drying process follows Formula 4 below:
Elongation percentage after vacuum drying/elongation percentage before vacuum drying=0.9 to 1.4. Formula 4