Integrated SCR catalyst and LNT for NOx abatement
Certain catalytic articles, systems or methods provide for excellent NOx conversion and are especially suitable for low temperature NOx conversion. The articles, systems and methods are suitable for instance for the treatment of exhaust gas of diesel engines. Certain articles or systems contain an upstream SCR composition and a downstream LNT composition. The substrate(s) may advantageously be electrically heated.
1. An exhaust gas treatment system comprising:
a SCR catalyst composition; and
a LNT composition;
wherein the LNT composition is in fluid communication with the SCR catalyst composition and at least a portion of the LNT composition is downstream of at least a portion of the SCR catalyst composition;
wherein the entire SCR composition is in direct contact with a first substrate;
wherein the SCR catalyst composition is close-coupled; and
wherein the LNT composition comprises a NOx sorbent and a platinum group metal component dispersed on a refractory metal oxide; and
further comprising a downstream underfloor diesel oxidation catalyst, catalyst soot filter, and second SCR catalyst and
a 2-20 kW electrical heater that electrically heats the SCR catalyst composition and LNT composition.
2. The exhaust gas treatment system of claim 1 , wherein the LNT composition is disposed on a second substrate.
3. The exhaust gas treatment system of claim 1 , wherein the LNT composition is disposed on the first substrate.
4. The exhaust gas treatment system of claim 3 , wherein the SCR catalyst composition extends an entire length of the first substrate and the LNT composition overlays a portion of the SCR catalyst composition.
5. The exhaust gas treatment system of claim 3 , wherein the LNT composition overlays the SCR catalyst composition.
6. The exhaust gas treatment system of claim 3 , wherein the SCR catalyst composition and the LNT composition do not overlay each other.
7. The exhaust gas treatment system of claim 1 , further comprising an ammonia oxidation catalyst.
8. The exhaust gas treatment system of claim 1 , further comprising a reductant injector in fluid communication with and upstream of the SCR catalyst composition.
9. The exhaust gas treatment system of claim 2 , where the first substrate is close-coupled and the second substrate is under-floor.
10. The exhaust gas treatment system of claim 1 , wherein the SCR catalyst composition comprises base metal-containing 8-ring small pore molecular sieves.
11. A method for treating an exhaust stream containing NOx, comprising passing the exhaust stream through the exhaust gas treatment system of claim 1 .
12. The method of claim 11 , wherein the exhaust stream is ≤190° C.
13. A catalytic article comprising a substrate having a first, upstream end and a second, downstream end defining an axial length and having a zoned catalytic coating thereon, the catalytic coating comprising:
an upstream zone comprising a selective catalytic reduction (SCR) catalyst composition, wherein the SCR catalyst composition is close-coupled; and
a downstream zone comprising a lean NOx trap (LNT) composition, wherein the LNT composition comprises a NOx sorbent and a platinum group metal component dispersed on a refractory metal oxide;
and wherein the entire SCR composition is in direct contact with the substrate.
14. The catalytic article of claim 13 , wherein the substrate is a porous wall-flow filter.
15. The catalytic article of claim 13 , wherein the substrate is a flow-through monolith.