IP Library Granted Patent US 11,273,429
Granted Patent B2
US 11,273,429 · App. 16/344,943 · Granted Mar 15, 2022

Fischer-Tropsch catalyst body

Inventors: Ronald Jan Dogterom (Amsterdam, NL); Gerard Pieter Van Der Laan (Amsterdam, NL); Abderrahmane Chettouf (Amsterdam, NL)
Assignee: SHELL OIL COMPANY
B01J23/75B01J21/063B01J35/023B01J35/04B01J35/10B01J37/0215B01J37/0225B01J37/038C10G2/332
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Quick Facts
Patent No.
US 11,273,429
App. No.
16/344,943
Granted
Mar 15, 2022
Kind
B2
Abstract

The present application relates to a Fischer-Tropsch catalyst body having an open-celled foam structure, said catalyst body comprising a substrate material and a catalytic active material or precursor thereof wherein:—The substrate material: ⋅ is a metal alloy or ceramic material; ⋅ having a surface roughness of 50 μm or more; ⋅ has an open-celled foam structure with at least 15 pores per inch; and—The catalytically active material or precursor thereof which: ⋅ is present on the surface of the substrate material; ⋅ comprises cobalt, iron, ruthenium or a combination thereof; and ⋅ comprises a catalyst support selected from titania, alumina or silica.

Claims (49)

1. A Fischer-Tropsch catalyst body having an open-celled foam structure, said catalyst body comprising a substrate material and a catalytic active material or precursor thereof wherein:

the substrate material:

is a metal alloy or ceramic material;

having a surface roughness of 50 μm or more;

has an open-celled foam structure with at least 15 pores per inch; and

the catalytically active material or precursor thereof which:

is present on the surface of the substrate material;

comprises cobalt, iron, ruthenium or a combination thereof; and

comprises a catalyst support selected from titania, alumina or silica.

2. The Fischer-Tropsch catalyst body according to claim 1 ,

wherein the catalytically active material is present as a layer which is in direct contact with the substrate material; and

wherein the catalytically active material or precursor thereof are particles comprising cobalt, iron, ruthenium or a combination thereof; and a catalyst support selected from titania, alumina or silica.

3. The Fischer-Tropsch catalyst body according to claim 1 ,

wherein the catalytically active material or precursor thereof, is a Cobalt based catalyst material.

4. The Fischer-Tropsch catalyst body according to claim 3 , wherein the catalytically active material or precursor thereof has a layer thickness in a range of from 10 to 200 μm.

5. The Fischer-Tropsch catalyst body according to claim 1 ,

wherein 5-30 vol % of the FT catalyst body is catalytic active material.

6. The Fischer-Tropsch catalyst body according to claim 2 ,

wherein the layer is deposited on the surface by means of vacuum wash coating.

7. The Fischer-Tropsch catalyst body according to claim 1 ,

wherein the catalyst body is disc/cylinder-shaped, sphere-, rectangular-, squared- or polyhedral shaped.

8. The Fischer-Tropsch catalyst body according to claim 7 , wherein the catalyst body has a particle size of at least 5 mm.

9. The Fischer-Tropsch catalyst body according to claim 1 ,

wherein the substrate material has a rigidity of at least 0.7 MPa as measured with compression strength tests.

10. The Fischer-Tropsch catalyst body according to claim 1 ,

wherein the catalytically active material is adhered to and substantially covers the substrate material.

11. The Fischer-Tropsch catalyst body according to claim 1 ,

wherein the substrate material has a voidage of 70-96 vol.

12. A process for producing normally gaseous, normally liquid in a three-phase reactor comprising the steps of:

providing a Fischer-Tropsch catalyst body comprising a substrate material and a catalytic active material or precursor thereof to at least one reactor tube in a three phase Fischer-Tropsch reactor;

wherein the substrate material:

is a metal alloy or ceramic material;

having a surface roughness of 50 μm or more;

has a open-celled foam structure with at least 15 pores per inch; and

wherein the catalytically active material or precursor thereof which:

is present on the surface of the substrate material;

comprises cobalt, iron, ruthenium or a combination thereof; and

comprises a catalyst support selected from titania, alumina or silica;

providing a liquid to the reactor;

providing to the Fischer-Tropsch catalyst body a gas mixture comprising carbon monoxide and hydrogen in order for the synthesis to occur while the Fischer-Tropsch catalyst body remains stationary in the reactor tubes;

obtaining a synthesis product from the reactor comprising the normally gaseous, normally liquid, and optionally normally solid hydrocarbons.

13. The process according to claim 12 , wherein the hydrogen and carbon monoxide molar ratio of the synthesis gas is in the range from 0.4 to 2.5.

14. The process according to claim 12 , wherein the gaseous hourly space velocity is in the range from 500 to 20,000 NI/1/h.

15. The process according to claim 12 , wherein the process is carried out at a temperature in the range of from 125 to 150° C. and a pressure of from 5 to 150 bar abs.

16. The process according to claim 12 , wherein the synthesis product is withdrawn from the reactor by withdrawing liquid medium.

17. The process according to claim 12 , wherein a gas mixture is withdrawn from the reactor.

18. The process according to claim 12 , wherein the hydrogen and carbon monoxide molar ratio of the synthesis gas is in the range from 1.0 to 2.4.

19. The process according to claim 12 , wherein the process is carried out at a temperature in the range of from 175 to 275° C.

20. The process according to claim 12 , wherein the process is carried out at a pressure in the range of from 5 to 80 bar abs.

Assignments (2)
CHANGE OF NAME Recorded Mar 7, 2022
From: SHELL OIL COMPANY
To: SHELL USA, INC.
Reel/Frame 059694/0819 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Nov 30, 2021
From: DOGTEROM, RONALD JAN; VAN DER LAAN, GERARD PIETER; CHETTOUF, ABDERRAHMANE
To: SHELL OIL COMPANY
Reel/Frame 058245/0849 →
Priority Claims (1)
EP 16195968 · Oct 27, 2016 · regional
Continuity (1)
Related Publication 20190262802A1 · Aug 29, 2019