Organic electroluminescent devices comprising host compounds

1. An organic electroluminescent device comprising a light-emitting layer B containing at least one host compound H of formula (I):

wherein:

each of A 1 , A 2 , A 3 , and A 4 is independently from another selected from the group consisting of CH and CR a ;

one of R 5 , R 6 , R 7 , and R 8 and one of R′ 5 , R′ 6 , R′ 7 , and R′ 8 are each a binding site to the optionally substituted C 4 -C 6 -(hetero)arylene residue comprising the residues A 1 , A 2 , A 3 , and A 4 , and each of the remaining residues R 1 , R 2 , R 3 , R 4 , R 5 , R 6 , R 7 , R 8 , R′ 1 , R′ 2 , R′ 3 , R′ 4 , R′ 5 , R′ 6 , R′ 7 , and R′ 8 are;

X is O or S;

X′ is NR e , O, or S; and

each of R a and R e is selected from the group consisting of unsubstituted or substituted C 6 -C 18 -aryl, C 1 -C 20 -alkyl, C 7 -C 19 -alkaryl, C 1 -C 20 -heteroalkyl, and C 3 -C 17 -heteroaryl.

2. The organic electroluminescent device of claim 1 , wherein the organic electroluminescent device is a device selected from the group consisting of an organic light emitting diode, a light emitting electrochemical cell, and a light-emitting transistor.

3. The organic electroluminescent device of claim 1 , wherein at least two of A 1 , A 2 , A 3 , and A 4 are each CH.

4. The organic electroluminescent device of claim 1 , wherein A 1 , A 2 , A 3 , and A 4 are each CH.

5. The organic electroluminescent device of claim 1 , wherein A 1 , A 2 , A 3 , and A 4 are each CH and all of the residues R 1 , R 2 , R 3 , R 4 , R 5 , R 6 , R 7 , R 8 , R′ 1 , R′ 2 , R′ 3 , R′ 4 , R′ 5 , R′ 6 , R′ 7 , and R′ 8 which are not the binding site to the optionally substituted C 4 -C 6 -(hetero)arylene residue comprising the residues A 1 , A 2 , A 3 , and A 4 are each hydrogen.

6. The organic electroluminescent device of claim 1 , wherein X′ is NR e and R e is selected from the group consisting of an unsubstituted or substituted residue selected from the group consisting of phenyl, pyridyl, methyl, ethyl, biphenyl, and terphenyl.

7. The organic electroluminescent device of claim 1 , wherein the host compound H has a structure according to one of the following formulae (II)-(IV):

wherein X and X′ are defined as in claim 1 .

8. The organic electroluminescent device of claim 1 , wherein the host compound H has a structure of the following formula (V):

wherein the residues A 1 , A 2 , A 3 , A 4 , R 1 , R 2 , R 3 , R 4 , R 5 , R 6 , R 8 , R′ 1 , R′ 2 , R′ 3 , R′ 4 , R′ 5 , R′ 6 , R′ 8 , X, and X′ are defined as in claim 1 .

9. The organic electroluminescent device of claim 1 , wherein the host compound H has a structure according to one of the following formulae (VI)-(X):

10. The organic electroluminescent device of claim 1 , wherein the light-emitting layer B comprises:

(i) 5-99% by weight, of at least one host compound H of claim 1 ;

(ii) 1-50% by weight of at least one emitter compound E; and optionally

(iii) 0-94% by weight of at least one further host compound D not according to formula (I); and optionally

(iv) 0-94% by weight of a solvent.

11. The organic electroluminescent device of claim 10 , wherein the host compound H has a highest occupied molecule orbital HOMO(H) having an energy E HOMO (H) in the range of from −5 to −6 eV and at least one further host compound D has a highest occupied molecule orbital HOMO(D) having an energy E HOMO (D), wherein E HOMO (H)>E HOMO (D).

12. The organic electroluminescent device of claim 10 , wherein the host compound H has a lowest unoccupied molecule orbital LUMO(H) having an energy E LUMO (H) and at least one further host compound D has a lowest unoccupied molecule orbital LUMO(D) having an energy E LUMO (D), wherein E LUMO (H)>E LUMO (D).

13. The organic electroluminescent device of claim 10 , wherein:

the host compound H has a highest occupied molecule orbital HOMO(H) having an energy E HOMO (H) and a lowest unoccupied molecule orbital LUMO(H) having an energy E LUMO (H), and the at least one further host compound D has a highest occupied molecule orbital HOMO(D) having an energy E HOMO (D) and a lowest unoccupied molecule orbital LUMO(D) having an energy E LUMO (D),

the emitter compound E has a highest occupied molecule orbital HOMO(E) having an energy E HOMO (E) and a lowest unoccupied molecule orbital LUMO(E) having an energy E LUMO (E), wherein E HOMO (H)>E HOMO (D) and the difference between the energy level of the highest occupied molecule orbital HOMO(E) of the emitter compound E (E HOMO (E)) and the energy level of the highest occupied molecule orbital HOMO(H) of the host compound H (E HOMO (H)) is between −0.5 eV and 0.5 eV; and

E LUMO (H)>E LUMO (D) and the difference between the energy level of the lowest unoccupied molecule orbital LUMO(E) of emitter compound E (E LUMO (E)) and the lowest unoccupied molecule orbital LUMO(D) of the at least one further host compound D (E LUMO (D)) is between −0.5 eV and 0.5 eV.

14. The organic electroluminescent device of claim 10 , wherein at least one further host compound D has or contains a structure of formula (XI):

wherein:

each of K 1 , K 2 , and K 3 is independently from another selected from the group consisting of CH, CR k , and N; wherein at least one of the residues K 1 , K 2 , and K 3 is N;

wherein R k is selected from the group consisting of unsubstituted or substituted C 1 -C 20 -alkyl, C 6 -C 18 -aryl, C 3 -C 17 -heteroaryl, C 7 -C 19 -alkaryl, and —SiR f R g R h , wherein C 6 -C 18 -aryl, C 3 -C 17 -heteroaryl, or C 7 -C 19 -alkaryl can at each occurrence be optionally substituted by a residue selected from the group consisting of C 1 -C 20 -alkyl, C 7 -C 19 -alkaryl, and C 6 -C 18 -aryl;

each of R n and R m is independently from another selected from the group consisting of hydrogen, C 1 -C 20 -alkyl, C 6 -C 18 -aryl, C 3 -C 17 -heteroaryl, C 1 -C 19 -alkaryl, and —SiR f R g R h , wherein C 6 -C 18 -aryl, C 3 -C 17 -heteroaryl, or C 7 -C 19 -alkaryl can at each occurrence be optionally substituted by a residue selected from the group consisting of C 1 -C 20 -alkyl, C 7 -C 19 -alkaryl, and C 6 -C 18 -aryl;

L b is selected from the group consisting of a single bond and optionally substituted C 6 -C 18 -arylene;

G is a group of or containing a structure of one of formulas (XII) to (XV)

wherein:

#is the binding site to L b ;

X″ is selected from the group consisting of O and S;

each of R XII , R XIII , R XIV , R XV , R XVI , R XVII , R XVIII , R XIX , R XX , R XXI , R XXII , R XXIII , R XXIV , R XXV , R XXVI , R XXVII , R XXVIII , R XXIX , R XXX , R XXXI , R XXXII , R XXXIII , R XXXIV , R XXXV , R XXXVI , R XXXVII , R XXXIII , and R XXXIX is independently from another selected from the group consisting of hydrogen, —Cl, —Br, —I, —CN, —CF 3 , C 1 -C 20 -alkyl, C 6 -C 18 -aryl, C 3 -C 17 -heteroaryl, C 7 -C 19 -alkaryl, and —SiR f R g R h , wherein C 6 -C 18 -aryl, C 3 -C 17 -heteroaryl, or C 7 -C 19 -alkaryl can at each occurrence be optionally substituted by a residue selected from the group consisting of C 1 -C 20 -alkyl, C 7 -C 19 -alkaryl, C 6 -C 18 -aryl, —CN, and —CH 3 ;

each of R p and R r is independently from another selected from the group consisting of hydrogen, C 1 -C 20 -alkyl, C 6 -C 18 -aryl, C 3 -C 17 -heteroaryl, C 7 -C 19 -alkaryl, and —SiR f R g R h wherein C 6 -C 18 -aryl, C 3 -C 17 -heteroaryl, or C 7 -C 19 -alkaryl can at each occurrence be optionally substituted by a residue selected from the group consisting of C 1 -C 20 -alkyl, C 7 -C 19 -alkaryl, C 6 -C 18 -aryl, —CN, and —CH 3 ; and

each of R f , R g , and R h is selected from the group consisting of unsubstituted or substituted C 6 -C 18 -aryl, C 1 -C 20 -alkyl, C 7 -C 19 -alkaryl, C 1 -C 20 -heteroalkyl, and C 3 -C 17 -heteroaryl.

15. The organic electroluminescent device of claim 1 , wherein the organic electroluminescent device comprises at least the following layers:

A) an anode layer A containing at least one component selected from the group consisting of indium tin oxide, indium zinc oxide, PbO, SnO, graphite, doped silicium, doped germanium, doped GaAs, doped polyaniline, doped polypyrrole, doped polythiophene, and mixtures of two or more thereof;

B) the light-emitting layer B; and

C) a cathode layer C containing at least one component selected from the group consisting of Al, Au, Ag, Pt, Cu, Zn, Ni, Fe, Pb, In, W, Pd, LiF, Ca, Ba, Mg, and mixtures or alloys of two or more thereof,

wherein the light-emitting layer B is located between the anode layer A and the a cathode layer C.

16. A method for generating light of a desired wavelength range, comprising the steps of:

(i) providing an organic electroluminescent device of claim 1 ; and

(ii) applying an electrical current to the organic electroluminescent device.