Organic electroluminescent element
Provided is an organic electroluminescent element having high efficiency, a long lifetime, and bending resistance. An organic electroluminescent element includes a light emitting layer and an electron transport layer adjacent to the light emitting layer between a positive electrode and a negative electrode. A host compound of the light emitting layer has an ionization potential deeper than that of a light emitting dopant of the light emitting layer by 0.3 eV or more. At least one organic compound contained in the electron transport layer has a molecular dipole moment of 6.0 debye or more.
1. An organic electroluminescent element comprising: a light emitting layer; and an electron transport layer adjacent to the light emitting layer between a positive electrode and a negative electrode, wherein
a host compound of the light emitting layer has an ionization potential deeper than that of a light emitting dopant of the light emitting layer by 0.3 eV or more and 2.0 eV or less, and
at least one organic compound contained in the electron transport layer has a molecular dipole moment of 8.0 debye or more and 16.0 debye or less,
wherein the organic compound is a compound represented by the following general formula (1):
wherein Z 1 and Z 2 each represent a pyridine ring which may have a substituent, Z 3 represents a simple bond, and R 101 represents an aryl group which may have a substituent or an aromatic heterocyclic group which may have a substituent.
2. The organic electroluminescent element according to claim 1 , wherein the molecular dipole moment of the organic compound is 10.0 debye or more and 16.0 debye or less.
3. The organic electroluminescent element according to claim 1 , wherein the molecular dipole moment of the organic compound is 12.0 debye or more and 16.0 debye or less.
4. The organic electroluminescent element according to claim 1 , wherein the organic compound is a compound represented by general formula (1), containing only carbon, nitrogen, and hydrogen.
5. The organic electroluminescent element according to claim 1 , wherein a whole of constituent layers of the organic electroluminescent element contains a polar fluorinated solvent in an amount of 1000 ppm by mass or less.
6. The organic electroluminescent element according to claim 5 , wherein the polar fluorinated solvent is any one or more selected from a fluorinated alcohol, a fluorinated ester, and a fluorinated ether.
7. The organic electroluminescent element according to claim 5 , wherein the polar fluorinated solvent contains a fluorinated alcohol having 3 to 5 carbon atoms.
8. The organic electroluminescent element according to claim 1 , wherein the light emitting layer is formed of a compound having a molecular weight of 500 or more and 3,000 or less.
9. The organic electroluminescent element according to claim 1 , wherein the light emitting layer has a film thickness of 50 nm or more and 5 μm or less.
10. The organic electroluminescent element according to claim 2 , wherein a whole of constituent layers of the organic electroluminescent element contains a polar fluorinated solvent in an amount of 1000 ppm by mass or less.
11. The organic electroluminescent element according to claim 2 , wherein the light emitting layer is formed of a compound having a molecular weight of 500 or more and 3,000 or less.
12. The organic electroluminescent element according to claim 2 , wherein the light emitting layer has a film thickness of 50 nm or more and 5 μm or less.
13. The organic electroluminescent element according to claim 3 , wherein a whole of constituent layers of the organic electroluminescent element contains a polar fluorinated solvent in an amount of 1000 ppm by mass or less.
14. The organic electroluminescent element according to claim 3 , wherein the light emitting layer is formed of a compound having a molecular weight of 500 or more and 3,000 or less.
15. The organic electroluminescent element according to claim 3 , wherein the light emitting layer has a film thickness of 50 nm or more and 5 μm or less.