Photopolymerizable base coat for a nail
A photopolymerizable composition suitable for forming a polymerized base coat of a substantially uniform mixture of nitrocellulose and crosslinked (meth)acrylate polymer is disclosed. The composition comprises an ethyl acetate solution including multiple (meth)acrylate monomers, nitrocellulose, a rapid release copolymer of alkyl acrylate monomers, a chain extended di-(hydroxyethylmethacryloyl) trimethylhexyl dicarbamate oligomer of weight average molecular weight of 10 to 20 kDa, one or more plasticizers and a photoinitiator.
1. A composition suitable for formation of a photopolymerized base coat on a nail, comprising: a mixture of components including multiple (meth)acrylate monomers comprising hydroxyethyl (meth)acrylate at a weight percentage of about 2 wt % to about 10 wt %, hydroxypropyl (meth)acrylate at a weight percentage of about 5 wt % to about 15 wt %, isobornyl (meth)acrylate at a weight percentage of about 2 wt % to about 4 wt % and acrylic acid at a weight percentage of about 0.1 wt % to about 1 wt % wherein the weight percentage of each of the monomers is relative to the total weight of the composition, nitrocellulose at a nitrogen weight percentage of about 10.7 wt % to about 12.3 wt % relative to the total weight of the nitrocellulose, a rapid release linear copolymer of butyl acrylate and a mixture of methyl and ethyl acrylates wherein the molar ratio of butyl acrylate to the mixture of methyl and ethyl acrylate is in a range of about 1:0.8 to about 1:1.5 and the weight average molecular weight of the rapid release linear copolymer is in a range from about 3 kDa to about 20 kDa, a polyethylene glycol chain extended di-(hydroxyethylmethacryloyl) trimethylhexyl dicarbamate oligomer of weight average molecular weight in the range of 10 kDa to 20 kDa a polydispersity of about 2.0 to about 5.0 and a weight percentage in a range of about 11.0 wt % to about 16 wt % relative to the total weight of the composition, one or more plasticizers and a photoinitiator wherein the mixture is in an ethyl acetate solution.
2. A composition according to claim 1 wherein the one or more plasticizers include camphor and trimethyl pentanyl diisobutyrate.
3. A composition according to claim 1 wherein the rapid release copolymer has a weight average molecular weight range from about 4 kDa to about 10 kDa and has a polydispersity of from about 1.3 to about 2.0.
4. A composition according to claim 1 comprising: about 5 wt % to about 30 wt % of the (meth)acrylate monomers, about 2 wt % to about 20 wt % of the nitrocellulose, about 2 to about 30 wt % of the rapid release copolymer, about 11 wt % to about 16 wt % of the dicarbamate oligomer, about a negligible but detectable wt % to about 10 wt % of the one or more plasticizers, about 0.1 wt % to about 10 wt % of the photoinitiator and about 30 wt % to about 70 wt % of the ethyl acetate.
5. A composition according to claim 1 wherein the weight percentage ranges of the (meth)acrylate monomers comprise about 5.8 wt % to about 6.8 wt % of hydroxypropyl (meth)acrylate; about 2.6 wt % to about 3.2 wt % for of hydroxyethyl (meth)acrylate, about 2.2 wt % to about 2.8 wt % of isobornyl (meth)acrylate and about 0.1 wt % to about 0.9 wt % of acrylic acid.
6. A composition of claim 1 wherein the chain extended oligomer is chain extended by a core formed of polyethylene glycol and trimethylhexyl diisocyanate.
7. A photopolymerized composition comprising a crosslinked (meth)acrylate polymer of multiple (meth)acrylate monomers comprising hydroxyethyl (meth)acrylate, hydroxypropyl (meth)acrylate, isobornyl (meth)acrylate and acrylic acid and which are crosslinked with a polyethylene glycol chain extended di-(hydroxyethylmethacryloyl) trimethylhexyl dicarbamate oligomer of weight average molecular weight in the range of 10 kDa to 20 kDa, a polydispersity of about 2.0 to about 5.0 and wherein the weight percentage of the dicarbamate oligomer is in a range about 22 wt % to about 32 wt % relative to the total weight of the photopolymerized composition, nitrocellulose at a nitrogen weight percentage of about 10.7 wt % to about 12.3 wt % relative to the total weight of the nitrocellulose, a rapid release linear copolymer of, butyl acrylate and a mixture of methyl and ethyl acrylates wherein the molar ratio of butyl acrylate to the methyl and ethyl acrylate mixture is in a range of about 1:0.8 to about 1:1.5 and the weight average molecular weight of the rapid release linear copolymer is in a range from about 3 kDa to about 20 kDa, and one or more plasticizers and a photoinitiator, wherein the nitrocellulose, the crosslinked (meth)acrylate polymer and the rapid release linear copolymer are in a substantially homogeneous single solid phase mixture with each other.
8. A photopolymerized composition of claim 7 wherein the chain extended oligomer is chain extended by a core formed of polyethylene glycol and trimethylhexyl diisocyanate.
9. A photopolymerized base coat suitable for covering a nail comprising a photopolymerized composition of a crosslinked (meth)acrylate polymer of multiple (meth)acrylate monomers comprising hydroxyethyl (meth)acrylate, hydroxypropyl (meth)acrylate, isobornyl (meth)acrylate and acrylic acid which are crosslinked by a polyethylene glycol chain extended di-(hydroxyethylmethacryloyl) trimethylhexyl dicarbamate oligomer of weight average molecular weight in the range of 10 kDa to 20 kDa, a polydispersity of about 2.0 to about 5.0 and a weight percentage of the dicarbamate oligomer in the range of about 22 wt % to about 32 wt % relative to the total weight of the photopolymerized base coat, nitrocellulose at a nitrogen weight percentage of about 10.7 wt % to about 12.3 wt % relative to the total weight of the nitrocellulose, a rapid release linear copolymer of butyl acrylate and a mixture of methyl and ethyl acrylates wherein the molar ratio of butyl acrylate to the mixture of methyl and ethyl acrylate is in a range of about 1:0.8 to about 1:1.5 and the weight average molecular weight of the rapid release linear copolymer is in a range from about 3 kDa to about 20 kDa, and one or more plasticizers and a photoinitiator, wherein the nitrocellulose, the crosslinked (meth)acrylate polymer and the rapid release linear copolymer are in a substantially homogeneous single solid phase mixture with each other.
10. A photopolymerized base coat according to claim 9 wherein the crosslinked polymer, nitrocellulose, rapid release copolymer, one or more plasticizers and photoinitiator are a substantially homogeneous solid mixture.
11. A photopolymerized base coat according to claim 9 comprising about 21 wt % to 27 wt % of the multiple (meth)acrylate monomers, about 25 wt % to about 27 wt % of the dicarbamate oligomer, about 13 to about 15 wt % of the nitrocellulose, about 9 wt % to about 11 wt % of the rapid release copolymer, about 9 wt % to about 11 wt % of the one or more plasticizers, and about 5 wt % to about 7 wt % of the photoinitiator.