IP Library Granted Patent US 12,692,584
Granted Patent B2
US 12,692,584 · App. 16/371,901 · Granted Jul 28, 2026

Low alloy third generation advanced high strength steel and process for making

Inventors: Luis Gonzalo Garza-Martinez (Wyoming, OH); Erik James Pavlina (Lebanon, OH)
Assignee: Cleveland-Cliffs Inc.
C22C38/58C21D6/001C21D6/004C21D6/005C21D6/008C21D8/0226C21D9/0081C21D9/46C22C38/02C22C38/04C22C38/06C22C38/08C22C38/12C22C38/34C22C38/44C22C38/48
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Quick Facts
Patent No.
US 12,692,584
App. No.
16/371,901
Filed
Apr 1, 2019
Granted
Jul 28, 2026
Kind
B2
Art Unit
1735
USPC
420/108
Abstract

Prior third generation advanced high strength steels can produce ingots and hot bands that have a tendency to develop cracks. It has been found that an addition to third generation advanced high strength steels of one or more of molybdenum in an amount up to 0.50 wt % and nickel in an amount up to 1.5 wt %, eliminates the cracks in ingots, and improves the appearance of hot bands. More specifically the new exemplary alloys have shown to improve the toughness of ingots, as well as hot bands.

Claims (17)

1 . A steel comprising 0.20 to 0.30 wt % carbon, 3.0 to 5.0 wt % manganese, 0.5 to 2.5 wt % silicon, 0.5 to 2.0 wt % aluminum, 0.25-0.5 wt % molybdenum, greater than 1.0% up to 1.5 wt % nickel; 0-0.050 wt % niobium, 0-1.0 wt % chromium, and the balance being iron and impurities associated with steelmaking, wherein the steel comprises 15-50% austenite by total area ratio, wherein a hot band comprised of the steel has a Charpy V-notch (“CVN”) impact testing energy above 20 J (14.75 ft-lbf) in a full size CVN specimen or 0.25 J/mm 2 (1427 in-lbf/in{circumflex over ( )}2) in a thinner hot band, as measured at room temperature.

2 . The steel of claim 1 further comprising 0.25 to 0.35 wt % molybdenum.

3 . The steel of claim 1 further comprising greater than 1.0% up to 1.2 wt % nickel.

4 . The steel of claim 2 further comprising greater than 1.0% up to 1.2 wt % nickel.

5 . The steel of claim 1 wherein Si+Al is 3 wt % or less.

6 . The steel of claim 1 further comprising 3.0 to 4.0 wt % manganese.

7 . The steel of claim 1 further comprising 1.0 to 2.0 wt % silicon.

8 . The steel of claim 1 further comprising 1.0 to 1.5 wt % aluminum.

9 . The steel of claim 1 further comprising 0 to 0.65 wt % chromium.

10 . The steel of claim 1 wherein an as-cast slab comprised of the steel exhibits substantially no edge cracking at room temperature.

11 . A process of making the steel of claim 1 wherein the steel is intercritical annealed at a temperature of 700 to 800° C.

12 . The process of claim 11 wherein the steel is intercritical annealed as a hot band.

13 . The process of claim 11 wherein the steel is intercritical annealed in a hot dip coating line.

14 . The process of claim 11 wherein the steel is intercritical annealed in a continuous annealing line.

15 . A steel comprising 0.20 to 0.30 wt % carbon, 3.0 to 5.0 wt % manganese, 0.5 to 2.5 wt % silicon, 0.5 to 2.0 wt % aluminum, 0.25-0.5 wt % molybdenum, 0.5-1.5 wt % nickel; 0-0.050 wt % niobium, 0-1.0 wt % chromium, and the balance being iron and impurities associated with steelmaking, wherein the steel comprises greater than 40% up to 50% austenite by total area ratio, wherein a hot band comprised of the steel has a Charpy V-notch (“CVN”) impact testing energy above 20 J (14.75 ft-lbf) in a full size CVN specimen or 0.25 J/mm 2 (1427 in-lbf/in{circumflex over ( )}2) in a thinner hot band, as measured at room temperature.

16 . The steel of claim 15 further comprising greater than 1.0% up to 1.5 wt % nickel.

17 . A process of making the steel of claim 15 wherein the steel is intercritical annealed at a temperature of 700 to 800° C.

Assignments (11)
RELEASE OF SECURITY INTEREST Recorded Apr 5, 2024
From: U.S. BANK NATIONAL ASSOCIATION
To: CLEVELAND-CLIFFS INC.; CLEVELAND-CLIFFS STEEL CORPORATION (F/K/A AK STEEL CORPORATION); CLEVELAND-CLIFFS STEEL PROPERTIES INC. (F/K/A AK STEEL PROPERTIES, INC.)
Reel/Frame 067025/0974 →
RELEASE OF SECURITY INTEREST Recorded May 11, 2022
From: U.S. BANK TRUST COMPANY, NATIONAL ASSOCIATION, SUCCESSOR IN INTEREST TO U.S. BANK NATIONAL ASSOCIATION
To: CLEVELAND-CLIFFS INC.; CLEVELAND-CLIFFS STEEL CORPORATION (F/K/A AK STEEL CORPORATION),; CLEVELAND-CLIFFS STEEL PROPERTIES, INC. (F/K/A AK STEEL PROPERTIES, INC.); IRONUNITS LLC
Reel/Frame 063272/0001 →
CORRECTIVE ASSIGNMENT TO CORRECT THE RECEIVING PARTY DATA FROM CLEVELAND-CLIFFS STEEL PROPERTIES TO CLEVELAND-CLIFFS STEEL PROPERTIES INC. PREVIOUSLY RECORDED AT REEL: 056313 FRAME: 0443. ASSIGNOR(S) HEREBY CONFIRMS THE CHANGE OF NAME. Recorded Jul 2, 2021
From: AK STEEL PROPERTIES, INC.
To: CLEVELAND-CLIFFS STEEL PROPERTIES INC.
Reel/Frame 057941/0376 →
CORRECTIVE ASSIGNMENT TO CORRECT THE RECEIVING PARTY DATA PREVIOUSLY RECORDED AT REEL: 056228 FRAME: 0566. ASSIGNOR(S) HEREBY CONFIRMS THE ASSIGNMENT. Recorded May 20, 2021
From: AK STEEL PROPERTIES, INC.
To: CLEVELAND-CLIFFS STEEL PROPERTIES
Reel/Frame 056313/0443 →
CHANGE OF NAME Recorded May 13, 2021
From: AK STEEL PROPERTIES, INC.
To: CLEVELAND-CLIFFS STEEL PROPERTIES INC.
Reel/Frame 056228/0566 →
RELEASE OF SECURITY INTEREST Recorded Mar 15, 2021
From: U.S. BANK NATIONAL ASSOCIATION
To: AK STEEL CORPORATION; AK STEEL PROPERTIES, INC.
Reel/Frame 055587/0118 →
PATENT SECURITY AGREEMENT Recorded Apr 17, 2020
From: CLEVELAND-CLIFFS INC.; AK STEEL CORPORATION; AK STEEL PROPERTIES, INC.
To: U.S. BANK NATIONAL ASSOCIATION, AS NOTES COLLATERAL AGENT
Reel/Frame 052432/0166 →
PATENT SECURITY AGREEMENT Recorded Mar 13, 2020
From: CLEVELAND-CLIFFS INC.; AK STEEL CORPORATION; AK STEEL PROPERTIES, INC.
To: U.S. BANK NATIONAL ASSOCIATION, AS NOTES COLLATERAL AGENT
Reel/Frame 052162/0865 →
PATENT SECURITY AGREEMENT Recorded Mar 13, 2020
From: CLEVELAND-CLIFFS INC.; AK STEEL CORPORATION; AK STEEL PROPERTIES, INC.
To: BANK OF AMERICA, N.A., AS AGENT
Reel/Frame 052162/0782 →
PATENT SECURITY AGREEMENT Recorded Mar 13, 2020
From: AK STEEL CORPORATION; AK STEEL PROPERTIES, INC.
To: U.S. BANK NATIONAL ASSOCIATION, AS NOTES COLLATERAL AGENT
Reel/Frame 052162/0691 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Apr 12, 2019
From: GARZA-MARTINEZ, LUIS GONZALO; PAVLINA, ERIK JAMES
To: AK STEEL PROPERTIES, INC.
Reel/Frame 048869/0461 →