Curved two-dimensional nanocomposites for battery electrodes
A battery electrode composition is provided that comprises a composite material comprising one or more nanocomposites. The nanocomposites may each comprise a planar substrate backbone having a curved geometrical structure, and an active material forming a continuous or substantially continuous film at least partially encasing the substrate backbone. To form an electrode from the electrode composition, a plurality of electrically-interconnected nanocomposites of this type may be aggregated into one or more three-dimensional agglomerations, such as substantially spherical or ellipsoidal granules.
1. An Li-ion anode composition, comprising:
a porous nanocomposite material including:
electrically conductive, curved single-layer graphene coated with Si nanoparticles, and
a mechanically stable, deformable, protective coating capable of preventing electrolyte solvent access to the Si nanoparticles, accommodating expansion of the Si nanoparticles during lithiation without forming cracks or voids, limiting an external surface area of a surface of the nanocomposite material on which solid electrolyte interphase (SEI) is formed, and stabilizing the SEI that is formed on the surface of the nanocomposite material.
2. The Li-ion anode composition of claim 1 , further comprising:
a polymer binder.
3. The Li-ion anode composition of claim 2 , wherein the polymer binder comprises a polyacrylic composition.
4. The Li-ion anode composition of claim 1 , wherein the protective coating comprises pores.
5. The Li-ion anode composition of claim 1 , wherein the protective coating comprises carbon.
6. The Li-ion anode composition of claim 1 , wherein the protective coating comprises polymer.
7. The Li-ion anode composition of claim 1 , wherein the protective coating comprises an oxide.
8. The Li-ion anode composition of claim 1 , wherein the protective coating comprises two or more layers.
9. The Li-ion anode composition of claim 1 , wherein the Si nanoparticles are coated with a Li-ion permeable and electrically conductive material.
10. The Li-ion anode composition of claim 9 , wherein the Li-ion permeable and electrically conductive material comprises carbon.
11. The Li-ion anode composition of claim 1 , wherein one or more pores of the porous nanocomposite material are at least partially filled with a Li-ion conductive material.
12. The Li-ion anode composition of claim 1 , wherein the curved single-layer graphene exhibits a radius of curvature in the range of about 0.3 nm to about 0.03 mm.
13. The Li-ion anode composition of claim 1 , wherein the curved single-layer graphene exhibits a specific surface area of at least 940 m 2 ·g −1 .
14. The Li-ion anode composition of claim 1 , wherein the curved single-layer graphene comprises one or more micropores.
15. The Li-ion anode composition of claim 1 , wherein the curved single-layer graphene comprises a concentration of defects.
16. The Li-ion anode composition of claim 15 , wherein the concentration of defects exceeds a concentration threshold such that the presence of Raman D-band has an intensity comparable or higher than Raman G-band.
17. The Li-ion anode composition of claim 1 , wherein the porous nanocomposite material exhibits a substantially spherical or ellipsoidal shape.
18. A method of fabricating a Li-ion anode composition, comprising:
coating Si nanoparticles on electrically conductive, curved single-layer graphene to produce a porous nanocomposite material; and
coating a mechanically stable, deformable, protective coating on the porous nanocomposite material,
wherein the protective coating is capable of preventing electrolyte solvent access to the Si nanoparticles, accommodating expansion of the Si nanoparticles during lithiation without forming cracks or voids, limiting an external surface area of a surface of the nanocomposite material on which solid electrolyte interphase (SEI) is formed, and stabilizing the SEI that is formed on the surface of the nanocomposite material.
19. The method of claim 18 , wherein the Si nanoparticles are coated on the curved single-layer graphene via chemical vapor deposition (CVD).
20. The method of claim 19 , wherein silane gas (SiH4) is used as a precursor for the CVD of the Si nanoparticles.
21. The method of claim 18 , wherein at least part of the protective coating is deposited via chemical vapor deposition (CVD) or atomic layer deposition (ALD).
22. The method of claim 21 ,
wherein the at least part of the protective coating is deposited via CVD, and
wherein a hydrocarbon gaseous precursor is used for the CVD deposition of the at least part of the protective coating.
23. The method of claim 18 , wherein the protective coating comprises aluminum oxide.