Compositions and methods for fused filament fabrication
A composition for fused filament fabrication may include polylactic acid resin and talc. The composition may range from 50% by weight to 99% by weight polylactic acid resin, and from 7% by weight to 40% by weight talc. The composition may be configured as filaments or pellets adapted to be used in a fused filament fabrication process. A method for generating a resin-based structure may include providing a resin source that may include polylactic acid resin and talc. The resin source may include from 50% by weight to 99% by weight polylactic acid resin, and from 7% by weight to 40% by weight talc. The method may also include heating the resin source to a temperature greater than the melting temperature for semi-crystalline resins or significantly greater than glass transition temperature for amorphous resins, and depositing the heated resin source in a layered manner to form the resin-based structure.
1. A method for generating a resin-based structure, the method comprising:
providing a resin source comprising polylactic acid resin and talc, wherein the resin source comprises from 50% by weight to 99% by weight polylactic acid resin, and wherein the resin source comprises from 7% by weight to 40% by weight talc, wherein the resin source comprises at least one additional mineral, and wherein the at least one additional mineral is selected from the group consisting of kaolin, bentonite, montmorillonite, pyrophyllite, vermiculite, halloysite, wollastonite, mica, calcium carbonate, titania, perlite, sodium oxysulfate, and diatomaceous earth, and wherein the resin source comprises from greater than 0% by weight to 40% by weight of the at least one mineral;
heating the resin source to a temperature at least equal to the glass transition temperature of the resin source; and
depositing the heated resin source in a layered manner to form the resin-based structure.
2. The method of claim 1 , wherein the talc has a median particle size less than 12 microns.
3. The method of claim 1 , wherein the talc has a top particle size less than 150 microns.
4. The method of claim 1 , wherein the talc has a Hegman rating of 2 or greater.
5. The method of claim 1 , wherein the talc has a BET surface area greater than 2 m 2 /g.
6. The method of claim 1 , wherein the talc has an oil absorption less than 60 grams per 100 grams of talc.
7. The method of claim 1 , wherein the talc has a shape factor greater than 10.
8. The method of claim 1 , wherein the resin source comprises from 10% by weight to 30% by weight talc.
9. The method of claim 1 , further comprising adding at least one plasticizer, impact modifier, pigment, dye, colorant, stabilizer, process aid or lubricant to the resin source.