Compositions and methods for long lasting disinfection

1. A liquid hard surface treatment composition comprising:

a. an antimicrobial component comprising at least one quaternary ammonium compound in an amount ranging from about 100 ppm to about 20,000 ppm;

b. a cationic polysaccharide derived from a natural source in an amount ranging from about 200 ppm to about 5,000 ppm;

c. an organic acid from about 500 ppm to about 7,000 ppm; and

d. a surfactant selected from the group consisting of cationic surfactants, amphoteric surfactants, nonionic surfactants, and combinations thereof,

wherein a film formed from the composition kills at least 95% of microorganisms for at least 3 abrasion cycles according to RSS-12 h.

2. The composition of claim 1 , wherein the antimicrobial component is selected from the group consisting of monoalkyldimethylbenzyl ammonium salts, dialkyldimethyl ammonium salts, and combinations thereof.

3. The composition of claim 1 , wherein the cationic polysaccharide is selected from the group consisting of cationic guar, cationic cellulose, cationic starch, and combinations thereof.

4. The composition of claim 3 , wherein the cationic polysaccharide is cationic guar.

5. The composition of claim 4 , wherein the cationic guar is selected from the group consisting of guars hydroxypropyltrimonium chloride, hydroxypropyl guar hydroxypropyltrimonium chloride, and combinations thereof.

6. The composition of claim 1 , wherein the organic acid is selected from the group consisting of citric, malic, maleic, lactic, succinic, glutaric, adipic acids and combinations thereof.

7. The composition of claim 1 , wherein the surfactant comprises a cationic surfactant selected from the group consisting of cationic amine oxides, cationic betaines, propionates, amphoacetates and combinations thereof.

8. The composition of claim 1 , wherein the surfactant comprises an amphoteric surfactant selected from the group consisting of sultaines, taurates, and combinations thereof.

9. The composition of claim 1 further comprising a polar solvent.

10. The composition of claim 1 , wherein a film formed from the composition kills at least 95% of gram-positive bacteria and gram-negative bacteria, or enveloped and non-enveloped viruses according to Environmental Protection Agency (EPA) Protocol #01-1A residual self-sanitizing activity test.

11. A liquid hard surface treatment concentrate composition comprising:

a. an antimicrobial component comprising at least one quaternary ammonium compound in an amount ranging from 800 ppm to about 40,000 ppm;

b. a cationic polysaccharide derived from a natural source in an amount ranging from about 800 ppm to about 30,000 ppm;

c. an organic acid in an amount ranging from about 1,000 ppm to about 35,000 ppm; and

d. a surfactant selected from the group consisting of cationic surfactants, amphoteric surfactants, nonionic surfactants, and combinations thereof in an amount ranging from about 2,000 ppm to about 90,000 ppm,

wherein the concentrate composition or a diluted solution of the concentrate composition forms a film that kills at least 95% of microorganisms for at least 3 abrasion cycles according to RSS-12 h.

12. A method of providing a surface with residual antimicrobial action that comprises the step of applying the composition of claim 1 to the surface.

13. A substrate with residual antimicrobial action comprising a substrate wherein at least a portion of the substrate is coated with the composition of claim 1 .

14. The composition of claim 1 further comprising water.