Compositions and methods for long lasting disinfection

1. A hard surface treatment composition comprising:

a. an antimicrobial component comprising at least one quaternary ammonium compound;

b. a synthetic polymer comprising:

i. at least one cationic monomer Ab,

ii. optionally, at least one anionic monomer B a , and

iii. optionally, at least one non-ionic monomer Ca;

c. an organic acid; and

d. a surfactant selected from the group consisting of cationic surfactants, amphoteric surfactants and combinations thereof,

wherein the composition is free of non-ionic surfactants.

2. The composition of claim 1 , wherein a film formed from the composition kills at least 95% of microorganisms for at least 3 abrasion cycles according to RSS-12h.

3. The composition of claim 1 , wherein the antimicrobial component is selected from the group consisting of monoalkyldimethylbenzyl ammonium salts, dialkyldimethyl ammonium salts, and combinations thereof.

4. The composition of claim 1 , wherein the monomer Ab is selected from the group consisting of diallyldimethylammonium halides.

5. The composition of claim 1 , wherein the polymer comprises monomer B a selected from the group consisting of acrylic acid, methacrylic acid, and combinations thereof.

6. The composition of claim 1 , wherein the polymer comprises monomer Ca selected from the group consisting of 2-(dimethylamino)ethyl methacrylate (DMAEMA); N-vinyl pyrrolidone (NVP); N-vinylimidazole; acrylamide; methacrylamide; and combinations thereof.

7. The composition of claim 1 , wherein the organic acid is selected from the group consisting of citric, malic, maleic, lactic, succinic, glutaric, adipic acids and combinations thereof.

8. The composition of claim 1 , wherein the surfactant comprises a cationic surfactant selected from the group consisting of cationic amine oxides.

9. The composition of claim 1 , wherein the surfactant comprises an amphoteric surfactant selected from the group consisting of sultaines, taurates, and combinations thereof.

10. The composition of claim 1 further comprising a polar solvent.

11. The composition of claim 1 , wherein a film formed from the composition kills at least 95% of gram-positive bacteria and gram-negative bacteria, or enveloped and non-enveloped viruses according to Environmental Protection Agency (EPA) Protocol #01-1A residual self-sanitizing activity test.

12. A method of providing a surface with residual antimicrobial action that comprises the step of applying the composition of claim 1 to the surface.

13. A substrate with residual antimicrobial action comprising a substrate wherein at least a portion of the substrate is coated with the composition of claim 1 .

14. A hard surface treatment concentrate composition comprising:

a. an antimicrobial component comprising at least one quaternary ammonium compound in an amount ranging from 800 ppm to about 40,000 ppm;

b. a synthetic polymer in an amount ranging from about 800 ppm to about 30,000 ppm comprising:

i. at least one cationic monomer A b ,

ii. optionally, at least one anionic monomer B a , and

iii. optionally, at least one non-ionic monomer Ca;

c. an organic acid in an amount ranging from about 1,000 ppm to about 35,000 ppm; and

d. a surfactant selected from the group consisting of cationic surfactants, amphoteric surfactants and combinations thereof in an amount ranging from about 2,000 ppm to about 90,000 ppm,

wherein the composition is free of non-ionic surfactants.