Secondary battery
The present disclosure provides a secondary battery, the secondary battery comprises a positive electrode plate, a negative electrode plate, a separator and an electrolyte, the negative electrode plate comprises a negative current collector and a negative film, the negative film is provided on at least one surface of the negative current collector and comprises a negative active material. The secondary battery satisfies relationships 3.9≤G×3.5+2.8/CB≤6.2 and 1.23≤0.55/V OI +CB×1.2≤2.80 at the same time. The battery of the present disclosure has the characteristics of high energy density and excellent dynamics performance, and the battery of the present disclosure also has the characteristic of long cycle life while charged under a large rate and a fast speed.
1. A secondary battery comprising a positive electrode plate, a negative electrode plate, a separator and an electrolyte, the negative electrode plate comprising a negative current collector and a negative film, the negative film being provided on at least one surface of the negative current collector and comprising a negative active material;
wherein
the negative active material comprises graphite, and the secondary battery satisfies relationships 3.9≤G×3.5+2.8/CB≤5.47 and 1.69≤0.55/V OI +CB×1.2≤2.32 at the same time;
G represents a graphitization degree of the negative active material, CB represents a capacity excess ratio of the battery, and V OI represents an OI value of the negative film,
the capacity excess ratio of the battery represented by CB represents a ratio of a capacity of the negative electrode plate to a capacity of the positive electrode plate under the same area;
V OI =C 004 /C 110 , C 004 represents a characteristic diffraction peak area of (004) crystal plane of the negative film, C 110 represents a characteristic diffraction peak area of (110) crystal plane of the negative film; and
the OI value of the negative film represented by V OI is from 3 to 40.
2. The secondary battery according to claim 1 , wherein the graphitization degree of the negative active material represented by G is 70%˜99%.
3. The secondary battery according to claim 2 , wherein the graphitization degree of the negative active material represented by G is 75%˜98%.
4. The secondary battery according to claim 1 , wherein the capacity excess ratio of the battery represented by CB is 1.01˜2.2.
5. The secondary battery according to claim 4 , wherein the capacity excess ratio of the battery represented by CB is 1.03˜1.8.
6. The secondary battery according to claim 1 , wherein the secondary battery further satisfies a relationship:
1.95≤(G×3.5+2.8/CB)/(0.55/V OI +CB×1.2)≤4.80.
7. The secondary battery according to claim 1 , wherein the negative active material further comprises one or more selected from a group consisting of soft carbon, hard carbon, carbon fiber, mesocarbon microbeads, silicon-based material, tin-based material and lithium titanate.
8. The secondary battery according to claim 1 , wherein a particle diameter of the negative active material represented by D50 is 1 μm˜20 μm.
9. The secondary battery according to claim 8 , wherein the particle diameter of the negative active material represented by D50 is 4 μm˜15 μm.
10. The secondary battery according to claim 1 , wherein an OI value of a powder of the negative active material represented by G OI is 0.5˜7,
G OI =C′ 004 /C′ 110 , C′ 004 represents a characteristic diffraction peak area of (004) crystal plane of the powder of the negative active material, and C′ 110 represents a characteristic diffraction peak area of (110) crystal plane of the powder of the negative active material.
11. The secondary battery according to claim 10 , wherein the OI value of the powder of the negative active material represented by G OI is 2˜4.5.
12. The secondary battery according to claim 1 , wherein the graphite is one or more selected from a group consisting of artificial graphite and natural graphite.