POROUS MEMBRANE AND METHOD FOR PRODUCING POROUS MEMBRANE
A porous membrane includes a porous membrane base containing a polymer compound and having pores interconnected in a thickness direction, and a metal oxide film on inner wall surfaces of the pores.
1 . A porous membrane comprising:
a porous membrane base containing a polymer compound and having pores interconnected in a thickness direction; and
a metal oxide film on inner wall surfaces of the pores.
2 . The porous membrane according to claim 1 , wherein the pores have a size of 0.1 μm or more and 50 μm or less.
3 . The porous membrane according to claim 2 , wherein the pores have a size of 0.5 μm or more and 10 μm or less.
4 . The porous membrane according to claim 1 , wherein the metal oxide film has a mean thickness of 0.01 μm or more and 0.2 μm or less.
5 . The porous membrane according to claim 1 , wherein the pores have a size of 0.5 μm or more and 10 μm or less, and the metal oxide film has a mean thickness of 0.01 μm or more and 0.2 μm or less.
6 . The porous membrane according to claim 1 , wherein a degree of thickness uniformity obtained from the following formula (1) is 20% or less,
Degree of thickness uniformity=( X−Y )/( X+Y )×100 Formula (1):
where X represents a maximum thickness of the metal oxide film and Y represents a minimum thickness of the metal oxide film.
7 . The porous membrane according to claim 1 , wherein the metal oxide film contains an oxide of a group 13 element.
8 . The porous membrane according to claim 6 , wherein the metal oxide film contains gallium oxide.
9 . The porous membrane according to claim 1 , wherein the porous membrane has a mean thickness of 50 μm or more and 500 μm or less.
10 . The porous membrane according to claim 1 , wherein the porous membrane has a tensile strength at break of 5 MPa or more.
11 . The porous membrane according to claim 1 , wherein the porous membrane has a tensile elongation at break of 50% or more.
12 . The porous membrane according to claim 1 , wherein a permeation flux of water pressurized at a pressure of 20 kPa through the porous membrane is 0.2 L/(m 2 ·h) or more.
13 . The porous membrane according to claim 1 , wherein the porous membrane is a water treatment membrane or a dialysis membrane.
14 . A method for producing a porous membrane having a metal oxide film on inner wall surfaces of pores, the method comprising:
supplying a film forming gas to a reaction inactive region of a reactor that includes, in an inside thereof, a porous membrane including a porous membrane base containing a polymer compound and having pores interconnected in a thickness direction, is designed to use excitation and decomposition of the film forming gas supplied to the inside so as to deposit a film having an element of the film forming gas as a constituent element, and has a reaction active region where the film-forming gas is capable of being excited and decomposed and the reaction inactive region continuous with the reaction active region;
exciting and decomposing the film forming gas in the reactor;
repeatedly moving the porous membrane between the reaction inactive region and the reaction active region by driving a holding member while the porous membrane is held by the holding member, wherein the film forming gas is supplied to the reaction active region from the reaction inactive region along with movement of the porous membrane; and
exhausting gas from the reactor through an exhaust pipe in the reactor, the gas having passed through the pores of the porous membrane base of the porous membrane held by the holding member.