High throughput methane pyrolysis reactor for low-cost hydrogen production
A system for hydrocarbon decomposition comprising a reactor volume, a mechanism to distribute the liquid catalyst as a liquid mist, a distributor to distribute a hydrocarbon reactant, a heat source, a separator to separate the solid product from the liquid catalyst, a re-circulation path and mechanism to re-circulate the liquid catalyst, and an outlet for at least one gaseous product. A system to distribute a liquid to an enclosed volume as a mist has a plurality of orifices designed to break the liquid into a mist. A method to decompose a hydrocarbon reactant includes generating a mist of a liquid catalyst, heating the reactor volume, introducing a hydrocarbon reactant into the reactor volume to produce a solid product and a gaseous product, separating the solid product from the liquid catalyst, removing the solid and gaseous products from the reactor volume, and recirculating the liquid catalyst to the reactor volume.
1. An apparatus to decompose a hydrocarbon reactant into a gaseous product and a solid product comprising:
a reactor volume,
a reservoir of liquid material;
a plurality of connected to the reservoir of liquid material, the plurality of nozzles configured to distribute the liquid material into the reactor volume from the reservoir as a liquid mist;
a gas inlet connected to a hydrocarbon gas source to receive hydrocarbon gas reactant;
a distributor connected to the inlet to distribute the hydrocarbon gas reactant into the reactor volume;
a heat source located adjacent the reactor volume configured to generate sufficient heat in the reactor volume to maintain a temperature between 1100° C. and 1400° C. in the reactor volume;
a separator to separate the solid product from the liquid material;
a re-circulation path connected between the reactor volume and the reservoir to re-circulate the liquid material from the reactor volume to the reservoir;
a gas outlet connected to the reactor volume configured to outlet hydrogen gas from the reactor volume; and
at least one filter connected to the gas outlet to remove entrained solid product from the hydrogen gas.
2. The apparatus as claimed in claim 1 , wherein the liquid material has a melting point between −40° C. and 1400° C. and comprises:
a first element of a concentration of up to 90 weight percent, the first element selected from the group consisting of lithium; sodium; calcium; potassium; cadmium; aluminum;
antimony; bismuth; cerium; copper, gallium; indium; lanthanum; lead; magnesium; mercury;
silver; tin and zinc; and
a second element of a concentration of at least 11 weight percent, the second element selected from the group consisting of nickel; iron; cobalt; manganese; chromium scandium;
titanium; vanadium; molybdenum; silicon; tantalum; technetium; tungsten; ruthenium; and
palladium.
3. The apparatus as claimed in claim 1 , wherein the liquid material comprises one or more components:
wherein the one or more component has an activation energy barrier for hydrocarbon pyrolysis of less than 300 kJ per mole; or
wherein the one or more component has a carbon solubility of at least 1 atomic percent.
4. The apparatus as claimed in claim 1 , wherein the liquid material reservoir is positioned adjacent the heat source.
5. The apparatus as claimed in claim 1 , wherein the plurality of nozzles to distribute the liquid material comprises one of either:
a plurality of nozzles configured to produce the mist of liquid material into the reactor volume through the breakup of a liquid jet wherein the mist has a surface area to volume ratio greater than 1 cm 2 per 1 cm 3 of reactor volume; or
a plurality of nozzles configured to produce the mist as liquid droplets having a size of a mass-averaged diameter between 0.1 and 1,000 microns.
6. The apparatus as claimed in claim 1 , where the nozzles comprises one of:
a plurality of misting nozzles to produce a mist of liquid material in the reactor volume through breakup of a liquid jet; or
a plurality of misting nozzles to accelerate the breakup of a liquid jet through patterned grooves within the misting nozzles.
7. The apparatus as claimed in claim 1 , wherein the reactor volume is configured to process one of co-current, counter-current, or cross-current flows of hydrocarbon reactant and liquid material mist.
8. The apparatus as claimed in claim 1 , wherein the liquid material is introduced into the reactor volume through an outlet at the top, side, or bottom of the reactor volume.
9. The apparatus as claimed in claim 1 , wherein the hydrocarbon reactant comprises at least one selected from group consisting of: natural gas;
liquefied petroleum gas; gasoline; diesel; kerosene; naphtha; kerosene-based fuel; methane;
ethane; propane; butane; pentane; hexane; benzene; xylene; toluene; and any combination thereof; alkynes; alkenes; alkanes; arenes; cyclic compounds and any combination thereof having a boiling point less than 600° C.