IP Library Granted Patent US 10,770,619
Granted Patent B2
US 10,770,619 · App. 16/415,037 · Granted Sep 8, 2020

Light-emitting devices and displays with improved performance

Inventors: Seth Coe-Sullivan (Redondo Beach, CA); Marshall Cox (Brooklyn, NY); Caroline J. Roush (Somerville, MA); Jonathan S. Steckel (Cupertino, CA)
Assignee: SAMSUNG ELECTRONICS CO., LTD.
H01L33/06B82Y20/00B82Y30/00C09K11/02C09K11/565C09K11/883H01L27/156H01L33/0029H01L33/28H01L51/502H01L51/5012H05B33/145
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Quick Facts
Patent No.
US 10,770,619
App. No.
16/415,037
Granted
Sep 8, 2020
Kind
B2
Abstract

Light-emitting devices and displays with improved performance are disclosed. A light-emitting device includes a first electrode including an anode opposite a second electrode including a cathode, a hole injection layer adjacent the first electrode, a hole transporting layer disposed on the hole injection layer, and an emissive layer of inorganic semiconductor nanocrystals disposed between the hole transporting layer and the second electrode. The inorganic semiconductor nanocrystals comprising a plurality of semiconductor nanocrystals capable of emitting light upon excitation.

Claims (45)

1. A light-emitting device comprising:

a first electrode comprising an anode opposite a second electrode comprising a cathode;

a hole injection layer adjacent to the first electrode; and

an emissive layer of inorganic semiconductor nanocrystals disposed between the hole injection layer and the second electrode, the inorganic semiconductor nanocrystals comprising a plurality of semiconductor nanocrystals capable of emitting light upon excitation,

wherein the device has an external quantum efficiency of at least about 2.2 percent.

2. The light-emitting device in accordance with claim 1 , wherein at least a portion of the semiconductor nanocrystals comprise a core including a first semiconductor material comprising a ternary semiconductor material and a shell overcoating the core, the shell comprising a second semiconductor material.

3. The light-emitting device in accordance with claim 2 , wherein the first semiconductor nanocrystal comprises a ternary semiconductor nanocrystal comprising a Group II-VI compound, a Group III-V compound, or a combination thereof.

4. The light-emitting device in accordance with claim 1 , further comprising:

a hole transporting layer disposed between the hole injection layer and the emissive layer of inorganic semiconductor nanocrystals.

5. The light-emitting device in accordance with claim 1 , further comprising:

an electron transporting layer disposed between the second electrode and the emissive layer of inorganic semiconductor nanocrystals.

6. The light-emitting device in accordance with claim 1 , wherein the device emits light having a CIE color coordinate of x greater than 0.63.

7. The light-emitting device in accordance with claim 1 wherein the emissive layer comprises semiconductor nanocrystals capable of emitting green light upon excitation or semiconductor nanocrystals capable of emitting red light upon excitation.

8. A light-emitting device comprising:

a first electrode comprising an anode opposite to a second electrode comprising a cathode;

a hole injection layer adjacent to the first electrode; and

an emissive layer of inorganic semiconductor nanocrystals disposed between the hole injection layer and the second electrode, the inorganic semiconductor nanocrystals comprising a plurality of semiconductor nanocrystals capable of emitting light upon excitation,

wherein the device is capable of emitting light with a brightness of at least 100 nits when driven at a voltage less than or equal to 4 volts.

9. The light-emitting device in accordance with claim 8 , wherein at least a portion of the semiconductor nanocrystals comprise a core including a first semiconductor material comprising a ternary semiconductor material and a shell overcoating the core, the shell comprising a second semiconductor material.

10. The light-emitting device in accordance with claim 9 , wherein the first semiconductor nanocrystal comprises a ternary semiconductor nanocrystal comprising a Group II-VI compound, a Group III-V compound, or a combination thereof.

11. The light-emitting device in accordance with claim 8 , further comprising:

a hole transporting layer disposed between the hole injection layer and the emissive layer of inorganic semiconductor nanocrystals.

12. The light-emitting device in accordance with claim 8 , further comprising:

an electron transporting layer disposed between the second electrode and the emissive layer of inorganic semiconductor nanocrystals.

13. The light-emitting device in accordance with claim 8 , wherein the device emits light having a CIE color coordinate of x greater than 0.63.

14. The light-emitting device in accordance with claim 8 , wherein the device has an external quantum efficiency of at least about 2.2 percent.

15. A light-emitting device comprising:

a first electrode comprising an anode opposite a second electrode comprising a cathode;

a hole injection layer adjacent the first electrode; and

an emissive layer of inorganic semiconductor nanocrystals disposed between the hole injection layer and the second electrode, the inorganic semiconductor nanocrystals comprising a plurality of semiconductor nanocrystals capable of emitting light upon excitation,

wherein at least a portion of the semiconductor nanocrystals comprise a core including a first semiconductor material comprising a ternary semiconductor material and a shell overcoating the core, the shell comprising a second semiconductor material, and

wherein the ternary semiconductor material comprises a Group II-VI compound, a Group III-V compound, or a combination thereof.

16. The light-emitting device in accordance with claim 15 , further comprising:

a hole transporting layer disposed between the hole injection layer and the emissive layer of inorganic semiconductor nanocrystals.

17. The light-emitting device in accordance with claim 15 , further comprising;

an electron transporting layer disposed between the second electrode and the emissive layer of inorganic semiconductor nanocrystals.

18. A light-emitting device comprising:

a first electrode comprising an anode opposite a second electrode comprising a cathode;

a hole injection layer adjacent to the first electrode; and

an emissive layer of inorganic semiconductor nanocrystals disposed between the hole injection layer and the second electrode, the inorganic semiconductor nanocrystals comprising a plurality of semiconductor nanocrystals capable of emitting light upon excitation,

wherein the device emits light having a CIE color coordinate of x greater than 0.63.

19. The light-emitting device in accordance with claim 18 , further comprising:

a hole transporting layer disposed between the hole injection layer and the emissive layer of inorganic semiconductor nanocrystals.

20. The light-emitting device in accordance with claim 18 , further comprising:

an electron transporting layer disposed between the second electrode and the emissive layer of inorganic semiconductor nanocrystals.