Ink composition, process for producing same, and ink-jet ink set and ink-jet printing system both including said ink composition
An ink composition according to the present invention contains a polymerizable compound and a photopolymerization initiator, wherein an amount of organic sulfonic acid measured at a temperature of 25° C. by using a water extraction method is 50 ppm or less, and an amount of water measured by a Karl Fischer method is 0.50 mass % or less with respect to a total mass of the ink composition. Also, an ink-jet ink set according to the present invention includes the above-described ink composition of the present invention. Also, an ink-jet printing system according to the present invention uses the above-described ink composition of the present invention and an ink-jet recording apparatus, and the ink-jet recording apparatus includes an ink heating portion and an ink filter.
1. A process for producing an ink composition, the process comprising the steps of:
preparing an ink composition precursor containing a polymerizable compound that is a monofunctional monomer having one ethylenic double bond or a multifunctional monomer having a plurality of ethylenic double bonds, a photopolymerization initiator, and an organic sulfonic acid derived from a catalyst used when synthesizing the polymerizable compound;
adding an alkali metal salt to the ink composition precursor and stirring the ink composition precursor at a temperature of 40° C. or more and 70° C. or less for a period of 10 minutes or more and 120 minutes or less;
holding and aging the stirred ink composition precursor at a temperature of −20° C. or more and 35° C. or less; and
filtrating the aged ink composition precursor to produce an ink composition.
2. A process for producing an ink composition, the process comprising the steps of:
preparing an ink composition precursor containing a polymerizable compound that is a monofunctional monomer having one ethylenic double bond or a multifunctional monomer having a plurality of ethylenic double bonds, a photopolymerization initiator, and an organic sulfonic acid derived from a catalyst used when synthesizing the polymerizable compound;
stirring the ink composition precursor at a temperature of 40° C. or more and 70° C. or less for a period of 10 minutes or more and 120 minutes or less;
holding and aging the stirred ink composition precursor at a temperature of −20° C. or more and 35° C. or less; and
filtrating the aged ink composition precursor to produce an ink composition,
wherein at least one of the polymerizable compound and the photopolymerization initiator contains alkali metal ions.
3. The process for producing an ink composition according to claim 1 , further comprising a dewatering step.
4. The process for producing an ink composition according to claim 1 ,
wherein the polymerizable compound contains an amine-modified polymerizable compound.
5. The process for producing an ink composition according to claim 1 ,
wherein the ink composition precursor further contains a coloring agent.
6. The process for producing an ink composition according to claim 2 , further comprising a dewatering step.
7. The process for producing an ink composition according to claim 2 ,
wherein the polymerizable compound contains an amine-modified polymerizable compound.
8. The process for producing an ink composition according to claim 2 ,
wherein the ink composition precursor further contains a coloring agent.