Nonaqueous electrolyte secondary battery separator and method of producing same
A nonaqueous electrolyte secondary battery separator is provided in which thickness unevenness caused by wrinkles is reduced. The nonaqueous electrolyte secondary battery separator includes a polyolefin porous film, and when a test piece cut out from the nonaqueous electrolyte secondary battery separator is immersed in propylene carbonate, the test piece exhibits an elongation percentage difference of not more than 0.20%; the elongation percentage difference being a difference between (i) an elongation percentage in a longitudinal direction of the test piece as observed after 30 minutes of immersion in propylene carbonate and (ii) an elongation percentage in the longitudinal direction of the test piece as observed after 24 hours of immersion in propylene carbonate.
1. A method of producing a nonaqueous electrolyte secondary battery laminated separator including a polyolefin porous film, the method comprising:
a step of applying a coating solution including a resin to a separator original sheet including the polyolefin porous film,
a drying step in which the separator original sheet to which the coating solution has been applied is dried in at least two stages each having a respective temperature which is set such that at least two differing temperatures are utilized in the drying step,
the at least two stages of the drying step including a stage in which the separator original sheet to which the coating solution has been applied is heated at a temperature which is not less than 100° C. and not more than 115° C. and a stage in which the separator original sheet to which the coating solution has been applied is heated at a temperature which is not less than 116° C. and not more than 130° C.
2. A nonaqueous electrolyte secondary battery laminated separator comprising:
a nonaqueous electrolyte secondary battery separator including a polyolefin porous film; and
a porous layer,
wherein when a test piece cut out from the nonaqueous electrolyte secondary battery separator having a size of 100 mm by 8 mm is immersed in propylene carbonate, the test piece exhibits an elongation percentage difference of not more than 0.20%, the elongation percentage difference being a difference between (i) an elongation percentage in a longitudinal direction of the test piece as observed after 30 minutes of immersion in propylene carbonate and (ii) an elongation percentage in the longitudinal direction of the test piece as observed after 24 hours of immersion in propylene carbonate, the longitudinal direction of the test piece being a direction in which an elongation percentage of the nonaqueous electrolyte secondary battery separator is greatest.
3. The nonaqueous electrolyte secondary battery laminated separator according to claim 2 , wherein the porous layer contains at least one resin selected from the group consisting of a (meth)acrylate-based resin, a fluorine-containing resin, a polyamide-based resin, a polyimide-based resin, a polyester-based resin, and a water-soluble polymer.
4. The nonaqueous electrolyte secondary battery laminated separator according to claim 3 , wherein the polyamide-based resin is an aramid resin.
5. A nonaqueous electrolyte secondary battery comprising:
the nonaqueous electrolyte secondary battery laminated separator recited in claim 2 .
6. A nonaqueous electrolyte secondary battery member comprising:
a positive electrode;
the nonaqueous electrolyte secondary battery laminated separator recited in claim 2 ; and
a negative electrode,
the positive electrode, the nonaqueous electrolyte secondary battery laminated separator, and the negative electrode being arranged in this order.