Process for preparing a paraffin product
View Patent ↗The Fischer-Tropsch process can be used for the conversion of hydrocarbonaceous feed stocks into normally liquid and/or solid hydrocarbons (i.e. measured at 0° C., 1 bar). The feed stock (e.g. natural gas, associated gas, coal-bed methane, residual oil fractions, biomass and/or coal) is converted in a first step into a mixture of hydrogen and carbon monoxide. This mixture is often referred to as synthesis gas or syngas. The present invention relates to process for preparing a paraffin product from a carbonaceous feedstock and a system for preparing a paraffin product from a carbonaceous feedstock.
1. A system for preparing a paraffin product from a carbonaceous feedstock comprising the following:
i. one or more reactors for converting the carbonaceous feedstock into a gas mixture comprising hydrogen and carbon monoxide;
ii. one or more reactors for conducting a Fischer-Tropsch reaction, comprising a Fischer-Tropsch catalyst; and
iii. one or more gas separation units comprising a carbon molecular sieve membrane for separating gas; wherein the one or more gas separation units:
is connected to the one or more reactors for conducting a Fischer-Tropsch reaction such that the one or more reactors for conducting a Fischer-Tropsch reaction provides an off-gas to the one or more gas separation units; and
is connected to the one or more reactors for converting carbonaceous feedstock such that a retentate gas obtained in the one or more gas separation units is provided to said one or more reactors for converting carbonaceous feedstock; and
wherein the system comprises at least two carbon molecular sieve membranes having different gas separation properties.
2. The system according to claim 1 , further comprising one or more pretreatment units.
3. The system according to claim 2 , wherein the pretreatment unit comprises an adsorption-based unit.
4. The system according to claim 3 , wherein the adsorption-based unit is selected from a thermal swing adsorption unit, a pressure swing adsorption unit and an adsorption unit comprising adsorption material which cannot be regenerated.
5. The system according to claim 1 , comprising downstream of the Fischer-Tropsch reactor and upstream of the gas separation unit at least one CO shift reactor.
6. The system according to claim 1 , wherein one of the at least two carbon molecular sieve membranes has a carbon dioxide/methane selectivity of at least 35 and one has a nitrogen/methane selectivity of at least 4.5.
7. The system according to claim 1 , wherein the carbon molecular sieve membrane is selected from the group consisting of a hollow fiber membrane, a hollow fiber membrane comprising an asymmetric membrane, a substantially non-collapsed, asymmetric hollow fiber membrane, and combinations thereof.
8. The system according to claim 1 , wherein the catalyst is selected a Group VIII metal.
9. The system according to claim 1 , wherein the catalyst is selected from the group consisting of cobalt, iron, ruthenium and combinations thereof.
10. The system according to claim 1 , wherein the catalyst is cobalt.