Method for tuning characteristics of a polyamide nanofiber nonwoven
A method for tuning characteristics of a polyamide nanofiber nonwoven comprising the step of targeting a specific average nanofiber diameter and/or a specific relative viscosity for the polyamide nanofiber nonwoven. The specific average nanofiber diameter is within a range from 100 nm to 1000 nm and/or the specific relative viscosity is within a range from 5 to 75, e.g., from 15 to 50. The process further comprises the steps of extruding a polyamide composition having a moisture content with a pressurized gas through a fiber forming channel having a channel temperature to form the polyamide nanofiber nonwoven having the target average nanofiber diameter and/or relative viscosity and controlling the moisture content, the pressure of pressurized gas, and/or the channel temperature based on the specific average nanofiber diameter and/or the specific relative viscosity.
1. A method for tuning characteristics of a polyamide nanofiber nonwoven comprising the steps of:
targeting a specific average nanofiber diameter and/or a specific relative viscosity for the polyamide nanofiber nonwoven, wherein the specific average nanofiber diameter is within a range from 100 nm to 1000 nm and/or the specific relative viscosity is within a range from 5 to 75;
extruding a polyamide composition having a moisture content with a pressurized gas through a fiber forming channel having a channel temperature to form the polyamide nanofiber nonwoven having the target average nanofiber diameter and/or relative viscosity; and
controlling the moisture content by drying the polyamide composition to have a moisture content of less than 0.02 wt. %, and rehydrating the dried polyamide composition.
2. The method of claim 1 , wherein the specific average nanofiber diameter is within a range of 200 nm to 700 nm.
3. The method of claim 1 , wherein the specific relative viscosity is within a range from 15 to 50.
4. The method of claim 1 , wherein the moisture content is controlled from 0.005 wt. % to 1 wt. %.
5. The method of claim 1 , wherein the pressure of the pressurized gas is controlled to range from 160 kPa to 220 kPa.
6. The method of claim 1 , wherein the channel temperature is controlled to range from 270° C. to 330° C.
7. The method of claim 1 , wherein the fiber forming channel comprises a die and/or a capillary.
8. The method of claim 1 , wherein the polyamide nanofiber nonwoven is melt-blown and/or is free of solvent.
9. The method of claim 1 , wherein the polyamide composition comprises a catalyst.
10. A method for tuning the relative viscosity of a polyamide nanofiber nonwoven comprising the steps of:
targeting a specific relative viscosity for the polyamide nanofiber nonwoven, wherein the specific relative viscosity is within a range from 5 to 75;
extruding a polyamide composition having a moisture content to form the polyamide nanofiber nonwoven having the target relative viscosity; and
controlling the moisture content based on the target relative viscosity.
11. The method of claim 10 , wherein the relative viscosity is targeted to a targeted relative viscosity within the range from 15 to 50.
12. The method of claim 10 , wherein the moisture content is controlled to range from 0.005 wt. % to 1 wt. %.
13. The method of claim 10 , wherein the moisture content is controlled to range from 0.02 wt. % to 0.3 wt. %.
14. The method of claim 10 , wherein the controlling comprises:
drying the polyamide composition to have a moisture content of less than 0.02 wt. %; and
rehydrating the dried polyamide composition.
15. The method of claim 10 , wherein the polyamide composition is extruded through a fiber forming channel having a channel temperature and the channel temperature is controlled to range from 270° C. to 330° C.
16. The method of claim 10 , wherein the polyamide nanofiber nonwoven is melt-blown and/or is free of solvent.
17. The method of claim 10 , wherein the polyamide composition comprises a catalyst.
18. The method of claim 1 , wherein the polyamide nanofiber nonwoven further comprises zinc oxide.
19. The method of claim 10 , wherein the polyamide nanofiber nonwoven further comprises zinc oxide.