IP Library Granted Patent US 11,274,043
Granted Patent B2
US 11,274,043 · App. 16/435,638 · Granted Mar 15, 2022

Increased particle loading by surface modification with polyethersilane

Inventors: Zhifeng Li (Acton, MA); Helmut Mack (Traunstein, DE)
Assignees: Evonik Operations GmbH; Evonik Corporation
C01B33/149C09K3/1409C09K3/1436
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Quick Facts
Patent No.
US 11,274,043
App. No.
16/435,638
Granted
Mar 15, 2022
Kind
B2
Abstract

A modified colloidal silica is produced by mixing an effective amount of an alkyl silicate to form a colloidal silica, followed by treating the colloidal silica with an effective amount of a polyethersilane to form a modified colloidal silica.

Claims (20)

1. A modified colloidal silica produced by a process comprising:

mixing an alkyl silicate to form a colloidal silica and

treating a surface of the colloidal silica with an amount of a polyethersilane to form a modified colloidal silica with the surface modified, wherein the polyethersilane is 2-[methoxy(polyethyleneoxy)propyl]dimethylmethoxysilane.

2. The modified colloidal silica of claim 1 , wherein 0.1-10 wt % of the polyethersilane, based on the weight of a mother liquid of colloidal silane, is used to treat the mother liquid of the colloidal silica.

3. The modified colloidal silica of claim 1 , wherein the alkyl silicate is a tetraalkyl orthosilicate.

4. The modified colloidal silica of claim 3 , wherein the tetraalkyl orthosilicate is at least one selected from the group consisting of tetramethyl orthosilicate and tetraethyl orthosilicate.

5. A polishing material, comprising: the modified colloidal silica of claim 1 .

6. A method for producing a modified colloidal silica, comprising:

1) preparing a mother liquid comprising an alkali catalyst and water;

2) adding an amount of a hydrolyzed liquid obtained by hydrolyzing an alky] silicate to the mother liquid forming a colloidal silica; and

3) treating a surface of the colloidal silica with an amount of polyethersilane to form a modified colloidal silica with the surface modified, wherein the polyethersilane is 2-[methoxy(polyethyleneoxy)propyl]dimethylmethoxysilane.

7. The method of claim 6 , wherein 0.1-10 wt % of the polyethersilane, based on the weight of a mother liquid of colloidal silane, is used to treat the mother liquid of the colloidal silica.

8. The method of claim 6 , further comprising:

preparing the hydrolyzed liquid by hydrolyzing the alkyl silicate in absence of the catalyst.

9. The method of claim 6 , wherein the mother liquid further comprises seed particles.

10. The method of claim 6 , wherein the alkyl silicate is tetraalkyl orthosilicate.

11. The method of claim 10 , wherein the alkyl silicate is tetramethyl orthosilicate or tetraethyl orthosilicate.

12. The modified colloidal silica of claim 1 , wherein during the treating a methoxysilane group of the polyethersilane reacts with the surface of the colloidal silica causing the polyethersilane to graft on the colloidal silica surface.

13. An aqueous solution of the modified colloidal silica of claim 1 , wherein the aqueous solution has a solid content of 25 wt % to 40 wt %.

14. The method of claim 6 , wherein during the treating a methoxysilane group of the polyethersilane reacts with the surface of the colloidal silica causing the polyethersilane to graft on the colloidal silica surface.

Assignments (5)
CHANGE OF ADDRESS Recorded Mar 13, 2023
From: EVONIK CORPORATION
To: EVONIK CORPORATION
Reel/Frame 063068/0259 →
CHANGE OF NAME Recorded Nov 18, 2019
From: EVONIK DEGUSSA GMBH
To: EVONIK OPERATIONS GMBH
Reel/Frame 051045/0872 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Aug 15, 2019
From: LI, ZHIFENG
To: EVONIK CORPORATION
Reel/Frame 050061/0682 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Aug 15, 2019
From: MACK, HELMUT
To: EVONIK RESOURCE EFFICIENCY GMBH
Reel/Frame 050062/0049 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Aug 15, 2019
From: EVONIK RESOURCE EFFICIENCY GMBH
To: EVONIK DEGUSSA GMBH
Reel/Frame 050062/0109 →
Continuity (2)
Provisional Application 62684059 · Jun 12, 2018
Related Publication 20190375643A1 · Dec 12, 2019