Photovoltaic devices including doped semiconductor films
A photovoltaic cell can include a dopant in contact with a semiconductor layer.
1. A photovoltaic cell comprising:
a transparent conductive layer;
a first semiconductor window layer over the transparent conductive layer;
a dopant layer comprising a first dopant over the first semiconductor window layer;
a second semiconductor window layer over and in direct contact with the dopant layer;
wherein,
the second semiconductor window layer includes the first dopant;
the first and second semiconductor window layers comprise at least one of MgO or ZnO; and
the dopant layer comprising the first dopant has a thickness between 4 and 15 Angstroms; and
a semiconductor absorber layer over the second semiconductor window layer, wherein the semiconductor absorber layer comprises a mixture of CdTe and CdSe, doped p-type with a Group I element and a Group V element, wherein a concentration of the Group V element in the semiconductor absorber layer is between 0.5 ppma and 500 ppma.
2. The photovoltaic cell of claim 1 , wherein the Group I element comprises at least one of: lithium (Li), sodium (Na), potassium (K), rubidium (Rb), cesium (Cs), copper (Cu), silver (Ag), or gold (Au).
3. The photovoltaic cell of claim 1 , wherein the Group V element comprises at least one of phosphorous (P), arsenic (As), antimony (Sb), or bismuth (Bi).
4. The photovoltaic cell of claim 1 , wherein the Group V element comprises P.
5. The photovoltaic cell of claim 1 , wherein the Group V element comprises As.
6. The photovoltaic cell of claim 1 , further comprising a top layer over the semiconductor absorber layer, wherein the top layer comprises a metal nitride, and wherein the metal nitride, includes at least one of: aluminum, molybdenum, chromium, cobalt, nickel, titanium, or tungsten.