High strength dissolvable compositions for use in subterranean wells
A polymetaphosphate composition and method for temporarily sealing a perforation in a wellbore to facilitate a treatment therein and a well tool which can include a flow path, and a flow blocking device which selectively prevents flow through the flow path. The well tool can include a polymetaphosphate composition. A method of constructing a downhole well tool can include forming a structure of a solid mass comprising a polymetaphosphate composition, and incorporating the structure into the well tool.
1. A method of plugging perforations in a casing comprising:
(a) flowing down said casing a wellbore fluid having dispersed therein a composition comprising a polymetaphosphate of the formula
( l/n )[XM(PO 3 ) 3 ] n
wherein X is selected from Li, Na or K, M is selected from Be, Mg, Ca, Zn, Pb, Cu or Ni and n is from about 1 to about 100; and
(b) continuing the flow of said wellbore fluid until at least a portion of the perforations are sealed by the composition.
2. The method of claim 1 wherein the composition has a coating of a polymer selected from the group consisting of polylactide, crosslinked polylactide, polyglycolide, crosslinked polyglycolide and mixtures thereof.
3. The method of claim 1 wherein the composition is spherical with a diameter greater than one-quarter inch.
4. The method of claim 1 wherein X is Na and M is Ca or Mg.