IP Library Granted Patent US 10,865,279
Granted Patent B2
US 10,865,279 · App. 16/441,851 · Granted Dec 15, 2020

Methods and systems for generating aqueous polymer solutions

Inventors: Do Hoon Kim (Katy, TX); Dennis A. Alexis (Richmond, TX); Varadarajan Dwarakanath (Houston, TX); David R. Espinosa (Houston, TX); Taimur Malik (Houston, TX); Peter G. New (Aberdeen, GB); Adam C. Jackson (Aberdeen, GB); Christopher Michael Niemi (Aberdeen, GB)
Assignee: Chevron U.S.A. Inc.
C08J3/005C08J3/03C09K8/588E21B43/16C08J2300/00C08J2333/26E21B43/26
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Quick Facts
Patent No.
US 10,865,279
App. No.
16/441,851
Granted
Dec 15, 2020
Kind
B2
Abstract

Provided herein are liquid polymer (LP) compositions comprising a synthetic (co)polymer (e.g., an acrylamide (co)polymer), as well as methods for preparing aqueous polymer solutions by combining these LP compositions with an aqueous fluid. The resulting aqueous polymer solutions can have a concentration of a synthetic (co)polymer (e.g., an acrylamide (co)polymer) of from 50 to 15,000 ppm, and a filter ratio of 1.5 or less at 15 psi using a 1.2 μm filter. Also provided are methods of using these aqueous polymer solutions in oil and gas operations, including enhanced oil recovery.

Claims (36)

1. A single-stage polymer mixing system, the system comprising:

(i) a main polymer feed line diverging to a plurality of polymer supply branches;

(ii) a main aqueous feed line diverging to a plurality of aqueous supply branches; and

(iii) a plurality of mixer arrangements, each of which comprises an in-line mixer having a mixer inlet and a mixer outlet;

wherein each of the plurality of mixer arrangements is supplied by one of the plurality of polymer supply branches and one of the plurality of aqueous supply branches; and

wherein the main polymer feed line is fluidly connected to a liquid polymer (LP) supply;

wherein the aqueous feed line is fluidly connected to an aqueous supply; and

wherein the mixer outlet of each of the plurality of mixer arrangements is fluidly connected to at least one injection well.

2. The single-stage polymer mixing system of claim 1 , wherein the main polymer feed line is fluidly connected to the plurality of polymer supply branches via a polymer distribution manifold.

3. The single-stage polymer mixing system of claim 2 , wherein the polymer distribution manifold independently controls the fluid flow rate through each of the plurality of polymer supply branches.

4. The single-stage polymer mixing system of claim 1 , wherein the polymer mixing system further comprises a flow control valve operably coupled to each the plurality of polymer supply branches to control fluid flow rate through each of the plurality of polymer supply branches.

5. The single-stage polymer mixing system of claim 1 , wherein the polymer mixing system further comprises a flow control valve operably coupled to each the plurality of aqueous supply branches to control fluid flow rate through each of the plurality of aqueous supply branches.

6. The single-stage polymer mixing system of claim 1 , wherein the in-line mixer of

each of the plurality of mixer arrangements comprises a dynamic mixer.

7. The single-stage polymer mixing system of claim 1 , wherein the plurality of mixer arrangements mix a liquid polymer (LP) composition provided from the liquid polymer (LP) supply and an aqueous fluid provided from the aqueous supply.

8. The single-stage mixing system of claim 7 , wherein a specific mixing energy of at least 0.10 kJ/kg is applied to the LP composition and the aqueous fluid while passing through the plurality of mixer arrangements.

9. The single-stage mixing system of claim 7 , wherein the LP composition and the aqueous fluid are passed through the plurality of mixer arrangements at a velocity of from 1 m/s to 4 m/s.

10. The single-stage polymer mixing system of claim 7 , wherein a difference in pressure between the mixer inlet and the mixer outlet as the LP composition and the aqueous fluid are passed through each of the plurality of mixer arrangements is from 15 psi to 400 psi.

11. The single-stage polymer mixing system of claim 7 , wherein the liquid polymer (LP) composition is dissolved to a concentration of from 50 to 15,000 ppm in the aqueous fluid in less than five minutes.

12. A single-stage polymer mixing system, the system comprising:

(i) a main polymer feed line diverging to a plurality of polymer supply branches;

(ii) a main aqueous feed line diverging to a plurality of aqueous supply branches; and

(iii) a plurality of mixer arrangements, each of which comprises a first in-line mixer having a first mixer inlet and a first mixer outlet in series with a second in-line mixer having a second mixer inlet and a second mixer outlet;

wherein each of the plurality of mixer arrangements is supplied by one of the plurality of polymer supply branches and one of the plurality of aqueous supply branches; and

wherein the main polymer feed line is fluidly connected to a liquid polymer (LP) supply;

wherein the aqueous feed line is fluidly connected to an aqueous supply; and

wherein the second mixer outlet of each of the plurality of mixer arrangements is fluidly connected to at least one injection well.

13. The single-stage polymer mixing system of claim 12 , wherein the main polymer feed line is fluidly connected to the plurality of polymer supply branches via a polymer distribution manifold.

14. The single-stage polymer mixing system of claim 13 , wherein the polymer distribution manifold independently controls the fluid flow rate through each of the plurality of polymer supply branches.

15. The single-stage polymer mixing system of claim 12 , wherein the mixing

system further comprises a flow control valve operably coupled to each the plurality of polymer supply branches to control fluid flow rate through each of the plurality of polymer supply branches.

16. The single-stage polymer mixing system of claim 12 , wherein the mixing

system further comprises a flow control valve operably coupled to each the plurality of aqueous supply branches to control fluid flow rate through each of the plurality of aqueous supply branches.

17. The single-stage polymer mixing system of claim 12 , wherein the first in-line

mixer of each of the plurality of mixer arrangements comprises a dynamic mixer and the second in-line mixer of each of the plurality of mixer arrangements comprises a static mixer.

18. The single-stage mixing system of claim 12 , wherein a specific mixing energy of at least 0.10 kJ/kg is applied to a LP composition provided from the liquid polymer (LP) supply and an aqueous fluid provided from the aqueous supply while passing through the plurality of mixer arrangements.

Assignments (1)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Jul 29, 2020
From: KIM, DO HOON; ALEXIS, DENNIS A.; DWARAKANATH, VARADARAJAN; ESPINOSA, DAVID R.; MALIK, TAIMUR; NEW, PETER G.; JACKSON, ADAM C.; NIEMI, CHRISTOPHER MICHAEL
To: CHEVRON U.S.A. INC.
Reel/Frame 053345/0380 →
Continuity (3)
Continuation 15835020 · Dec 7, 2017
Provisional Application 62431255 · Dec 7, 2016
Related Publication 20190367685A1 · Dec 5, 2019