REDUCTION OF EDGE YELLOWING OF POLYVINYLACETAL LAMINATES
Provided herein are polyvinylacetal compositions, monolayer and multilayer films and sheets (interlayers), and laminates made with these interlayers, which have reduced edge yellowing after exposure to heat, which is accomplished by adding an oligomeric hindered amine light stabilizer with antioxidant functionality at levels generally about 0.2 percent by weight or less, wherein substantially no additional antioxidant or other HALS is present.
1 . A plasticized polyvinylacetal composition comprising (a) a polyvinylacetal resin having a hydroxyl number of from about 12 to about 34; (b) a plasticizer in an amount of about 60 parts per hundred (pph) or less based on the dry weight of the polyvinylacetal resin; and (c) a light stabilizer/antioxidant additive package comprising an oligomeric hindered amine light stabilizer with antioxidant functionality (oligomeric HALS), wherein substantially no additional antioxidant or hindered amine light stabilizer is present in the plasticized polyvinylacetal composition.
2 . The plasticized polyvinylacetal composition of claim 1 , wherein the polyvinylacetal is polyvinylbutyral.
3 . The plasticized polyvinylacetal composition of claim 1 , wherein the plasticizer is selected from the group consisting of triethyleneglycol di-(2-ethyl hexanoate) (3GO), dibutyl sebacate (DBS), dihexyl adipate (DHA), tetraethylene glycol di(2-heptanoate) (4G7) and mixtures thereof.
4 . The plasticized polyvinylacetal composition of claim 1 , wherein the plasticizer is triethyleneglycol di-(2-ethyl hexanoate) (3GO).
5 . The plasticized polyvinylacetal composition of claim 1 , wherein the oligomeric HALS is butanedioic acid, dimethylester, polymer with 4-hydroxy-2,2,6,6,-tetramethyl-1-piperidine ethanol.
6 . The plasticized polyvinylacetal composition of claim 1 , wherein the amount of oligomeric HALS is from about 0.03 to about 0.2 weight percent based on the total weight of the composition.
7 . The plasticized polyvinylacetal composition of claim 1 , wherein the light stabilizer/antioxidant additive package consists essentially of an oligomeric HALS and optionally a UV absorber.
8 . The plasticized polyvinylacetal composition of claim 1 , wherein the light/stabilizer/antioxidant package consists of an oligomeric HALS and optionally a UV absorber.
9 . The plasticized polyvinylacetal composition of claim 1 , wherein the composition further comprises an adhesion control agent.
10 . The plasticized polyvinylacetal composition of claim 9 , wherein the adhesion control agent is one or more alkali metal salts and/or alkaline earth metal salts.
11 . The plasticized polyvinylacetal composition of claim 10 , wherein the adhesion control agent is a potassium salt, a magnesium salt or a mixture thereof.
12 . The plasticized polyvinylacetal composition of claim 11 , wherein the adhesion control agent is a magnesium salt.
13 . The plasticized polyvinylacetal composition of claim 1 , wherein the composition further comprises a UV absorber.
14 . The plasticized polyvinylacetal composition of claim 1 , wherein the plasticizer is selected from the group consisting of triethyleneglycol di-(2-ethyl hexanoate) (3GO), dibutyl sebacate (DBS), dihexyl adipate (DHA), tetraethylene glycol di(2-heptanoate) (4G7) and mixtures thereof; the amount of oligomeric HALS is from about 0.03 to about 0.2 weight percent based on the total weight of the composition; and the composition further comprises an adhesion control agent.
15 . The plasticized polyvinylacetal composition of claim 14 , wherein the light stabilizer/antioxidant additive package consists essentially of an oligomeric HALS and optionally a UV absorber.
16 . A monolayer film or sheet comprising a plasticized polyvinylacetal composition comprising (a) a polyvinylacetal resin having a hydroxyl number of from about 12 to about 34; (b) a plasticizer in an amount of about 60 parts per hundred (pph) or less based on the dry weight of the polyvinylacetal resin; and (c) a light stabilizer/antioxidant additive package comprising an oligomeric hindered amine light stabilizer with antioxidant functionality (oligomeric HALS), wherein substantially no additional antioxidant or hindered amine light stabilizer is present in the plasticized polyvinylacetal composition.
17 . A multilayer sheet comprising at least one monolayer film or sheet as set forth in claim 16 .