Lithium-ion battery
The present disclosure provides a lithium-ion battery, the lithium-ion battery comprises a positive electrode plate, a negative electrode plate, a separator and an electrolyte. The positive active material comprises a material having a chemical formula of Li a Ni x Co y M z O 2 , the negative active material comprises a graphite-type carbon material, the lithium-ion battery satisfies a relationship 58%≤KY a /(KY a +KY c )×100%≤72%. In the present disclosure, by reasonably matching the relationship between the anti-compression capability of the positive active material and the anti-compression capability of the negative active material, it can make the positive electrode plate and the negative electrode plate both have good surface integrity, and in turn make the lithium-ion battery have excellent dynamics performance and excellent cycle performance at the same time.
1. A lithium-ion battery comprising a positive electrode plate, a negative electrode plate, a separator and an electrolyte, the positive electrode plate comprising a positive current collector and a positive film, the positive film being provided on at least one surface of the positive current collector and comprising a positive active material, the negative electrode plate comprising a negative current collector and a negative film, the negative film being provided on at least one surface of the negative current collector and comprising a negative active material;
wherein
the positive active material comprises a material having a chemical formula of Li a Ni x Co y M z O 2 , 0.95≤a≤1.2, x>0, y≥0, z≥0, M is one or two selected from a group consisting of Mn and Al;
a porosity of the positive film is 20% ˜30%;
the negative active material comprises a graphite material;
the lithium-ion battery satisfies a relationship 62%≤KY a /(KY a +KY c )×100%≤68%;
KY a =10/ρ a , ρ a represents a compaction density of a powder of the negative active material under a pressure of 2000 kg, and a unit of ρ a is g/cm 3 ;
KY c =10/ρ c , ρ c represents a compacted density of a powder of the positive active material under a pressure of 2000 kg, and a unit of ρ c is g/cm 3 ;
the positive active material satisfies 3.02 cm 3 /g ≤KY c ≤3.40 cm 3 /g; and
the negative active material satisfies 5.35 cm 3 /g≤KY a ≤6.64 cm 3 /g.
2. The lithium-ion battery according to claim 1 , wherein
an average particle size D50 of the positive active material is 2 μm˜11 μm.
3. The lithium-ion battery according to claim 2 , wherein
the average particle size D50 of the positive active material is 2.5 μm˜6.7 μm.
4. The lithium-ion battery according to claim 1 , wherein an average particle size D50 of the negative active material is 6 μm˜15.6 μm.
5. The lithium-ion battery according to claim 4 , wherein the average particle size D50 of the negative active material is 6 μm˜12.9 μm.
6. The lithium-ion battery according to claim 1 , wherein a graphitization degree of the negative active material is 92%˜96.2%.
7. The lithium-ion battery according to claim 6 , wherein the graphitization degree of the negative active material is 92.1%˜95.0%.
8. The lithium-ion battery according to claim 1 , wherein a pressing density of the positive film is 3.1 g/cm 3 ˜3.5 g/cm 3 .
9. The lithium-ion battery according to claim 1 , wherein a pressing density of the negative film is 1.3 g/cm 3 ˜1.7 g/cm 3 .
10. The lithium-ion battery according to claim 1 , wherein a porosity of the negative film is 30%˜40%.
11. The lithium-ion battery according to claim 1 , wherein x+y+z=1.
12. The lithium-ion battery according to claim 1 , wherein doping modification and/or coating modification are further performed on Li a Ni x Co y M z O 2 .
13. The lithium-ion battery according to claim 1 , wherein the graphite material is one or more selected from a group consisting of artificial graphite, natural graphite and modified graphite.
14. The lithium-ion battery according to claim 1 , wherein
the positive active material further comprises one or more selected from a group consisting of lithium cobalt oxide, lithium nickel oxide, layered lithium manganese oxide, spinel lithium manganese oxide, spinel lithium nickel manganese oxide and polyanion-type positive active material; and/or
the negative active material further comprises one or more selected from a group consisting of soft carbon, hard carbon, carbon fiber, mesocarbon microbeads, silicon-based material, tin-based material and lithium titanate.