Paper substrates incorporating covert marking pigments, and processes for obtaining and using same
Paper substrates which incorporate covert marking pigments (CMPs) which are one or more infrared (IR) anti-Stokes pigments. Also, processes for incorporating such CMPs into a paper substrate other than by a printing technique, such as, for example, by using a size press or spraying, as well as processes for identifying the presence of such CMPs incorporated into a paper substrate sheet with an infrared (IR) pigment sensor of, for example, a copier or printer for the purpose of adjusting the quantity of printer pigment deposited on a paper substrate sheet or to determine whether the paper substrate sheet is an authentic or counterfeit document.
1. A covertly marked paper substrate article comprising:
a paper substrate; and
a covert marking pigment having a particle size in the range of from about 0.1 to about 5 microns and being incorporated into the paper substrate in an infrared (IR) detectable amount of from about 0.1 to about 1,000 mg/m 2 , wherein the covert marking pigment is incorporated into the paper substrate at a wet end of the paper making process such that the covert marking pigment is distributed within the paper substrate,
the covert marking pigment being one or more IR anti-Stokes shift pigments selected from one or more of: yttrium oxide; sodium yttrium fluoride; lanthanum oxide; lanthanum fluoride; lanthanum oxysulfide; Gadolinium (Gd2O2S); Ytterbium (Yb); or mixtures thereof.
2. The article of claim 1 , wherein the covert marking pigment is incorporated into the paper substrate in an IR detectable amount of from about 2 to about 10 mg/m 2 .
3. The article of claim 1 , wherein the IR anti-Stokes shift pigments are selected from one or more of: yttrium oxide; sodium yttrium fluoride; lanthanum oxide; Gadolinium (Gd2O2S); or Ytterbium (Yb).
4. The article of claim 1 , wherein the covert marking pigment is distributed randomly in the paper substrate.
5. The article of claim 1 , wherein the paper substrate has two outer surfaces and wherein the covert marking pigment is further applied to one of the two outer surfaces.
6. The article of claim 1 , wherein the paper substrate has two outer surfaces and wherein the covert marking pigment is incorporated between the two outer surfaces.
7. The article of claim 1 , which is in the form of a ream of paper substrate sheets, at least a portion of the ream comprising covertly marked paper substrate sheets.
8. The article of claim 7 , wherein the covertly marked paper substrate sheets in the ream comprise from one in three to from one in five paper substrate sheets in the ream.
9. The article of claim 7 , wherein the paper substrate sheets have two opposed side edges, and wherein the cover marking pigment is further incorporated on one of the side edges of each covertly marked paper substrate sheet in the ream.
10. The article of claim 1 , wherein the paper substrate includes an optical brightening agent.
11. A process for preparing a covertly marked paper substrate, the process comprising the following steps:
(a) providing a composition having a covert marking pigment having a particle size in the range of from about 0.1 to about 5 microns, the covert marking pigment being one or more IR anti-Stokes shift pigments selected from one or more of: yttrium oxide; sodium yttrium fluoride; lanthanum oxide;
lanthanum fluoride; yttrium oxysulfide; lanthanum oxysulfide; Gadolinium (Gd2O2S); Ytterbium (Yb); or mixtures thereof; and
(b) incorporating the composition of step (a) by a non-printing technique into a paper substrate in an IR detectable amount of from about 0.1 to about 1,000 mg/m 2 , wherein the non-printing technique comprises incorporating the composition of step (a) into the paper furnish at a wet end of a paper making machine and wherein the covert marking pigment is distributed within the paper substrate.
12. The process of claim 11 , wherein the composition of step (a) comprises a size press composition which further comprises a sizing agent, and wherein the size press composition is incorporated into the paper substrate in step (b) at a size press.
13. The process of claim 11 , wherein the covert marking pigment is incorporated into the paper substrate during step (b) in an IR detectable amount of from about 2 to about 10 mg/m 2 .
14. The process of claim 11 , wherein the IR anti-Stokes shift pigments of step (a) are selected from one or more of: yttrium oxide; sodium yttrium fluoride; lanthanum oxide; Gadolinium (Gd2O2S); or Ytterbium (Yb).
15. The process of claim 11 , wherein step (b) is carried out by randomly distributing the covert marking pigment in the paper substrate.
16. The process of claim 11 , wherein the paper substrate of step (b) has two outer surfaces and wherein the covert marking pigment is further applied to one of the two outer surfaces during step (b).
17. The process of claim 11 , wherein the paper substrate of step (b) is formed into a ream of paper substrate sheets, and wherein from one in three to from one in five paper substrate sheets in the ream are covertly marked paper substrate sheets.
18. The process of claim 17 , wherein the paper substrate of step (b) has two opposed side edges, and wherein the cover marking pigment is further incorporated on one of the side edges of each covertly marked paper substrate sheet in the ream.