Integrated methods for chemical synthesis
The integrated processes herein provide improved carbon efficiency for processes based on coal or biomass gasification or steam methane reforming. Provided are also ethylene oxide carbonylation products such as beta-propiolactone and succinic anhydride having a bio-based content between 0% and 100%, and methods for producing and analyzing the same.
1. A method comprising:
a) selecting a target bio-based content for beta-propiolactone;
b) combining a bio-based ethylene oxide stream and a fossil-based ethylene oxide stream to produce a combined ethylene oxide feed stream; and
c) carbonylating the combined ethylene oxide feed stream using the combined carbon monoxide feed stream in the presence of carbonylation catalyst to produce beta-propiolactone having the target bio-based content selected in step (a).
2. The method of claim 1 , wherein the bio-based ethylene oxide stream is produced by a process comprising biomass fermentation.
3. The method of claim 1 , wherein the bio-based ethylene oxide stream is produced by a process comprising biomass gasification.
4. The method of claim 3 , wherein the biomass gasification is municipal solid waste gasification.
5. The method of claim 1 , wherein the fossil-based ethylene oxide stream is prepared by:
cracking the fossil-based feedstock to produce ethylene; and
oxidizing the ethylene to produce the fossil-based ethylene oxide stream.
6. The method of claim 1 , wherein the fossil-based feedstock comprises naphtha, shale gas, oil, or coal, or any combination thereof.
7. The method of claim 1 , wherein the bio-based syngas stream is prepared by:
performing biomass gasification to produce methanol, and
processing the methanol to produce the bio-based syngas stream.
8. The method of claim 1 , wherein the bio-based ethylene oxide stream is produced by electrolysis of carbon dioxide to produce the bio-based carbon monoxide stream.
9. The method of claim 1 , wherein the fossil-based syngas stream has a H 2 to CO ratio in the range from 0.4:1 to 1.2:1.
10. The method of claim 1 , wherein the carbonylating of the combined ethylene oxide feed stream using the combined carbon monoxide feed stream further produces an upgraded syngas stream having a higher H 2 to CO ratio than the combined carbon monoxide feed stream.
11. The method of claim 10 , further comprising feeding the upgraded syngas stream to a Fischer Tropsch reactor to produce liquid fuels, oils, waxes, olefins, or alcohols, or any combination thereof.
12. The method of claim 11 , further comprising treating the upgraded syngas stream to remove residual solvent, residual ethylene oxide, or residual carbon dioxide, or any combination thereof, prior to feeding the upgraded syngas stream to the Fischer Tropsch reactor.