Electrochemical cell with improved high-rate discharge performance
An alkaline electrochemical cell has a central cathode having a corresponding cathode current collector electrically connected with a positive terminal of the electrochemical cell. The cathode current collector has a tubular shape, such as a cylindrical shape or rectangular shape, extending parallel with the length of the central cathode. The cathode current collector is embedded within the central cathode, such as at a medial point of a radius of the central cathode, thereby minimizing the distance between the cathode current collector and any portion of the central cathode, thereby increasing the mechanical strength of the cathode and facilitating charge transfer to the cathode current collector.
1. An alkaline electrochemical cell comprising:
a container; and
an anode ring positioned within the container and defining an opening therein, wherein the anode ring comprises a zinc active material;
an inner cathode positioned within the opening of the anode, wherein the inner cathode comprises a manganese oxide active material, and wherein the inner cathode is at least substantially cylindrical, defines a cylindrical sidewall surface, and has uniform characteristics across an entire radius of the substantially cylindrical inner cathode;
a cathode current collector comprising an at least substantially cylindrical conducting tube positioned within and at least substantially concentric with the inner cathode, wherein the cathode current collector is electrically connected with a positive terminal of the electrochemical cell, and wherein the at least substantially cylindrical conducting tube is located at and in contact with the cylindrical sidewall surface of the inner cathode; and
a separator positioned between the anode ring and the inner cathode.
2. The alkaline electrochemical cell of claim 1 , further comprising an outer cathode ring positioned between an outer surface of the anode ring and an interior surface of the container.
3. The alkaline electrochemical cell of claim 2 , wherein the cathode current collector is in electrical contact with the container via a conductive tab.
4. The alkaline electrochemical cell of claim 1 , wherein the conducting tube comprises a conducting mesh material.
5. The alkaline electrochemical cell of claim 4 , wherein the conducting tube comprises a nickel mesh material.
6. The alkaline electrochemical cell of claim 5 , wherein the nickel mesh material has a graphite coating.
7. The alkaline electrochemical cell of claim 4 , wherein the conducting tube comprises a perforated nickel foil material.
8. The alkaline electrochemical cell of claim 1 , wherein the conducting tube comprises a conducting wire coil.
9. The alkaline electrochemical cell of claim 1 , wherein the inner cathode comprises a plurality of cylindrical cathode pellets stacked axially within the opening of the anode, and wherein the plurality of cylindrical cathode pellets collectively define the cylindrical sidewall surface, and the cathode current collector is wrapped around the plurality of cylindrical cathode pellets.
10. The alkaline electrochemical cell of claim 9 , wherein the cathode current collector is a continuous, at least substantially cylindrical conducting tube that is embedded within the cylindrical sidewall surface of the plurality of cylindrical cathode pellets.
11. The alkaline electrochemical cell of claim 1 , wherein the anode ring comprises a gelled anode.
12. An alkaline electrochemical cell comprising:
a container;
an outer cathode ring positioned adjacent an interior surface of the container and defining an opening therein, wherein the outer cathode ring comprises a cathode active material;
at least one anode portion positioned within the opening of the outer cathode, wherein the at least one anode comprises a zinc active material;
an inner cathode positioned adjacent a side of the at least one anode portion, and wherein the inner cathode is at least substantially cylindrical, defines a cylindrical sidewall surface, and has uniform characteristics across an entire radius of the substantially cylindrical inner cathode;
a cathode current collector comprising an at least substantially cylindrical conducting tube positioned within and at least substantially concentric with the inner cathode, wherein the cathode current collector is electrically connected with a positive terminal of the electrochemical cell, and wherein the at least substantially cylindrical conducting tube is located at and in contact with the cylindrical sidewall surface of the inner cathode; and
a separator material;
positioned between the outer cathode ring and the at least one anode portion; and
positioned between the at least one anode portion and the inner cathode.
13. The alkaline electrochemical cell of claim 12 , wherein the cathode current collector is in electrical contact with container via a conductive tab.
14. The alkaline electrochemical cell of claim 12 , wherein the conducting tube comprises a conducting mesh material.