Method for manufacturing catalysts with reduced attrition
The present invention discloses an inventive method for manufacturing a catalyst using alloy granules having a high-Ni content. The inventive method may include providing alloy granules comprising aluminum and nickel, and treating the alloy granules with an alkaline solution to form the catalyst. A content of the nickel in the alloy granules may be within a range of about 43 wt % to about 60 wt %. The alloy granules may have effective diameters within a range of about 1 mm to about 10 mm. The catalyst may have an attrition value of less than about 7.0%.
1. A method for manufacturing a catalyst, comprising providing alloy granules comprising aluminum and nickel, and treating the alloy granules with an alkaline solution comprising 1 wt % to 20 wt % sodium hydroxide to form the catalyst, wherein a content of the nickel in the alloy granules is 53 wt % to 60 wt %, wherein at least 40% of the aluminum from the alloy granules is leached upon treating with the alkaline solution, wherein the catalyst exhibits an attrition value of less than 5.0%, and wherein the catalyst comprises nickel and aluminum, and wherein a content of the nickel in the catalyst is about 57 wt % to about 75 wt %.
2. The method of claim 1 , wherein the alloy granules have effective diameters within a range of about 1 mm to about 10 mm.
3. The method of claim 1 , wherein the content of the nickel in the alloy granules is 53 wt %.
4. The method of claim 1 , wherein the content of the nickel in the alloy granules is 53 wt % to 56 wt %.
5. The method of claim 1 , wherein the alloy granules have effective diameters of about 2 mm to about 6 mm.
6. The method of claim 1 , wherein a concentration of the sodium hydroxide in the alkaline solution is 1 wt % to 15 wt %.
7. The method of claim 1 , wherein a concentration of the sodium hydroxide in the alkaline solution is 1 wt % to 10 wt %.
8. The method of claim 1 , wherein the alloy granules are treated with the alkaline solution at a temperature of about 20° C. to about 110° C.
9. The method of claim 1 , further comprising promoting the catalyst using an additional process step chosen from:
a. treating the catalyst with a solution comprising a soluble salt of a metal selected from the group consisting of Mo, Cr, W, Cu, Fe, and mixtures of any two or more thereof, or
b. adding a component chosen from Mo, Cr, W, Cu, Fe, and mixtures of any two or more thereof in forming the alloy granules.
10. The method of claim 1 , wherein a content of the nickel in the catalyst is about 60 wt % to about 70 wt %.
11. The method of claim 1 , wherein the catalyst exhibits an attrition value of 3.0% or less.
12. The method of claim 1 , wherein a concentration of the sodium hydroxide in the alkaline solution is from 6 wt % to 15 wt %.