Polyamide compositions
Described herein are polyamide compositions comprising poly alpha-1,3-glucan in combination with a compatibilizer and processes for preparing such compositions. Such polyamide compositions exhibit improved elongation at break compared to polyamide compositions which lack a compatibilizer. These polyamide compositions exhibit an elongation at break of at least 9 percent when measured according to ASTM D638 after exposure to water at 120° C. at 2 atm pressure for 192 hours.
1. A polyamide composition comprising:
(a) about 20 to about 99 weight percent of a polyamide,
(b) about 0.5 to about 40 weight percent of poly alpha-1,3-glucan, and
(c) about 0.5 to about 40 weight percent of a compatibilizer,
wherein said polyamide composition has an initial elongation at break of at least 5 percent when measured according to ASTM D638, and
wherein the compatibilizer is a maleic anhydride-grafted ethylene/α-olefin copolymer, maleic anhydride-grafted ethylene-propylene-diene polymer, or a combination thereof.
2. The polyamide composition of claim 1 , wherein the polyamide is poly(hexamethylene terephthalamide/2-methylpentamethylene terephthalamide), poly(hexamethylene hexanediamide), poly(hexamethylene decanediamide), poly(ε-caprolactam), or a combination thereof.
3. The polyamide composition of claim 1 , wherein the compatibilizer is the maleic anhydride-grafted ethylene/α-olefin copolymer.
4. An article prepared from the polyamide composition of claim 1 .
5. The polyamide composition of claim 1 ,
wherein said polyamide composition exhibits an elongation at break after 192 hours exposure to water at 120° C. at 2 atm pressure of at least 9 percent when measured according to ASTM D638.
6. The polyamide composition of claim 1 , wherein the polyamide is poly(hexamethylene dodecanediamide).
7. The polyamide composition of claim 6 , wherein the compatibilizer is the maleic anhydride-grafted ethylene/α-olefin copolymer.
8. An article prepared from the polyamide composition of claim 7 .
9. The polyamide composition of claim 1 , wherein the polyamide composition comprises 5 weight percent or less of the poly alpha-1,3-glucan, and the concentration ratio of the poly alpha-1,3-glucan to the compatibilizer is about 1:0.75.
10. The polyamide composition of claim 1 , wherein the polyamide composition comprises 5 weight percent or less of the poly alpha-1,3-glucan, and the concentration ratio of the poly alpha-1,3-glucan to the compatibilizer is about 1:1.
11. The polyamide composition of claim 1 , wherein the polyamide composition comprises 5 weight percent or less of the poly alpha-1,3-glucan, and the concentration ratio of the poly alpha-1,3-glucan to the compatibilizer is at least about 1:1.5.