IP Library Granted Patent US 10,787,632
Granted Patent B2
US 10,787,632 · App. 16/463,620 · Granted Sep 29, 2020

Cleaning solvent compositions exhibiting azeotrope-like behavior and their use

Inventors: Wells Cunningham (New Hartford, CT); Elizabeth P. Norwood (Unionville, CT); Edward C. Mark, Jr. (Hockessin, DE); Venesia L. Hurtubise (Hartford, CT)
Assignee: ZYNON TECHNOLOGIES, LLC
C11D7/505C11D3/43C11D7/5063
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Quick Facts
Patent No.
US 10,787,632
App. No.
16/463,620
Granted
Sep 29, 2020
Kind
B2
Abstract

A cleaning solvent composition comprises from about 70 to about 95.7 weight percent trans-dichloroethylene, from about 15 to about 3.8 weight percent heptafluorocyclopentane, and from about 15 to about 0.5 weight percent of methylperfluoroheptene ethers. The composition may comprise from about 88 to about 94.2 weight percent trans-dichloroethylene, from about 6 to about 3.8 weight percent heptafluorocyclopentane, and from about 6 to about 2 weight percent of methylperfluoroheptene ethers. A method for cleaning articles of soiling substances comprises contacting the articles with the solvent composition by any suitable means such as a spray delivered by a propellant gas, or by contact with liquid and/or vapor solvent compositions, as in a conventional vapor degreaser apparatus.

Claims (54)

1. A solvent composition exhibiting azeotrope-like properties and comprising:

from about 70 to about 95.7 weight percent trans-dichloroethylene;

from about 15 to about 3.8 weight percent heptafluorocyclopentane; and

from about 15 to about 0.5 weight percent methylperfluoroheptene ethers.

2. The solvent composition of claim 1 comprising:

from about 88 to about 94.2 weight percent trans-dichloroethylene;

from about 6 to about 3.8 weight percent heptafluorocyclopentane; and

from about 6 to about 2 weight percent methylperfluoroheptene ethers.

3. The composition of claim 1 comprising:

from about 91 to about 92.7 weight percent trans-dichloroethylene;

from about 4.5 to about 3.8 weight percent heptafluorocyclopentane; and

from about 4.5 to about 3.5 weight percent methylperfluoroheptene ethers.

4. The composition of claim 1 comprising:

from about 70 to about 95.5 weight percent trans-dichloroethylene;

from about 15 to about 4 weight percent heptafluorocyclopentane; and

from about 15 to about 0.5 weight percent methylperfluoroheptene ethers.

5. The composition of claim 1 comprising:

about 92 weight percent trans-dichloroethylene;

about 4 weight percent heptafluorocyclopentane; and

about 4 weight percent methylperfluoroheptene ethers.

6. The composition of claim 1 comprising:

from about 88 to about 92 weight percent trans-dichloroethylene;

from about 6 to about 4 weight percent heptafluorocyclopentane; and

from about 6 to about 4 weight percent methylperfluoroheptene ethers.

7. The composition of claim 1 comprising:

about 90 weight percent trans-dichloroethylene;

about 5 weight percent heptafluorocyclopentane; and

about 5 weight percent methylperfluoroheptene ethers.

8. A method for cleaning soiling substances from metal, ceramic and synthetic polymer articles comprising:

contacting one or more of the articles with a solvent composition having azeotrope-like properties, the composition comprising:

from about 70 to about 95.7 weight percent trans-dichloroethylene;

from about 15 to about 3.8 weight percent heptafluorocyclopentane;

from about 15 to about 0.5 weight percent methylperfluoroheptene ethers; and

removing the composition from the one or more articles.

9. The method of claim 8 wherein the composition comprises:

from about 88 to about 94.2 weight percent trans-dichloroethylene;

from about 6 to about 3.8 weight percent heptafluorocyclopentane; and

from about 6 to about 2 weight percent methylperfluoroheptene ethers.

10. The method of claim 8 wherein the composition comprises:

from about 91 to about 92.7 weight percent trans-dichloroethylene;

from about 4.5 to about 3.8 weight percent heptafluorocyclopentane; and

from about 4.5 to about 3.5 weight percent methylperfluoroheptene ethers.

11. The method of claim 8 wherein the composition comprises:

from about 70 to about 95.5 weight percent trans-dichloroethylene;

from about 15 to about 4 weight percent heptafluorocyclopentane; and

from about 15 to about 0.5 weight percent methylperfluoroheptene ethers.

12. The method of claim 8 wherein the composition comprises:

about 92 weight percent trans-dichloroethylene;

about 4 weight percent heptafluorocyclopentane; and

about 4 weight percent methylperfluoroheptene ethers.

13. The method of claim 8 wherein the composition comprises:

from about 88 to about 92 weight percent trans-dichloroethylene;

from about 6 to about 4 weight percent heptafluorocyclopentane; and

from about 6 to about 4 weight percent methylperfluoroheptene ethers.

Assignments (4)
RELEASE OF PATENT SECURITY AGREEMENT AT R/F 54575-0391 Recorded Aug 12, 2025
From: KEYBANK NATIONAL ASSOCIATION
To: MICROCARE HOLDINGS, LLC; MICROCARE INTERCO, LLC; MICROCARE, LLC; ZYNON TECHNOLOGIES, LLC
Reel/Frame 072447/0167 →
SECURITY INTEREST Recorded Aug 8, 2025
From: MICROCARE, LLC; ZYNON TECHNOLOGIES, LLC
To: MANULIFE INVESTMENT MANAGEMENT PRIVATE EQUITY AND CREDIT (US) LLC, AS AGENT
Reel/Frame 071969/0806 →
SECURITY INTEREST Recorded Dec 8, 2020
From: ZYNON TECHNOLOGIES, LLC
To: KEYBANK NATIONAL ASSOCIATION
Reel/Frame 054575/0391 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Sep 19, 2019
From: CUNNINGHAM, WELLS; NORWOOD, ELIZABETH P.; MARK, EDWARD C., JR.; HURTUBISE, VENESIA L.
To: ZYNON TECHNOLOGIES, LLC
Reel/Frame 050428/0146 →