Polypropylene composition with excellent paint adhesion
The invention relates to a polypropylene composition (C) comprising: (i) 62 to 85 wt.-%, based on the total weight of the polypropylene composition (C), of a heterophasic propylene copolymer (HECO1) with a melt flow rate MFR 2 (230° C.) measured according to ISO 1133 in the range of 6.0 to 50.0 g/10 min; (ii) 10 to 30 wt.-%, based on the total weight of the polypropylene composition (C), of a heterophasic propylene copolymer (HECO2) with a melt flow rate MFR 2 (230° C.) measured according to ISO 1133 in the range of 0.1 to 5.5 g/10 min; (iii) 5 to 30 wt.-%, based on the total weight of the polypropylene composition (C), of an inorganic filler (F); wherein (a) the xylene cold soluble (XCS) fraction of the heterophasic propylene copolymer (HECO1) has a lower amount [in mol %] of C 2 and/or C 4 to C 12 α-olefin derived comonomer units than the xylene cold soluble (XCS) fraction of the heterophasic propylene copolymer (HECO2); (b) the xylene cold soluble (XCS) fraction of the heterophasic propylene copolymer (HECO1) has a lower the intrinsic viscosity (IV) than the xylene cold soluble (XCS) fraction of the heterophasic propylene copolymer (HECO2); and (c) the xylene cold soluble (XCS) fraction of the heterophasic propylene copolymer (HECO2) has an intrinsic viscosity (IV) in the range of 6.0 to 15.0 dl/g.
1. Polypropylene composition (C) comprising:
(i) 62 to 85 wt. %, based on the total weight of the polypropylene composition (C), of a heterophasic propylene copolymer (HECO1) with a melt flow rate MFR 2 measured according to ISO 1133 at 230° C., 2.16 kg load in the range of 6.0 to 50.0 g/10 min;
(ii) 10 to 30 wt. %, based on the total weight of the polypropylene composition (C), of a heterophasic propylene copolymer (HECO2) with a melt flow rate MFR 2 measured according to ISO 1133 at 230° C., 2.16 kg load in the range of 0.1 to 5.5 g/10 min;
(iii) 5 to 30 wt. %, based on the total weight of the polypropylene composition (C), of an inorganic filler (F);
wherein
(a) the xylene cold soluble (XCS) fraction of the heterophasic propylene copolymer (HECO1) has a lower amount [in mol %] of C 2 and/or C 4 to C 12 α-olefin derived comonomer units than the xylene cold soluble (XCS) fraction of the heterophasic propylene copolymer (HECO2);
(b) the xylene cold soluble (XCS) fraction of the heterophasic propylene copolymer (HECO1) has a lower the intrinsic viscosity (IV) than the xylene cold soluble (XCS) fraction of the heterophasic propylene copolymer (HECO2); and
(c) the xylene cold soluble (XCS) fraction of the heterophasic propylene copolymer (HECO2) has an intrinsic viscosity (IV) in the range of 6.0 to 15.0 dl/g, and wherein
(d) the xylene cold soluble (XCS) fraction of the heterophasic propylene copolymer (HECO2) comprises comonomer units derived from C2 and/or C4 to C12 α-olefin in an amount in the range of 62 to 85 mol %.
2. Polypropylene composition (C) according to claim 1 , wherein the xylene cold soluble (XCS) fraction of the heterophasic propylene copolymer (HECO1) comprises comonomer units derived from C 2 and/or C 4 to C 12 α-olefin in an amount in the range of 35 to 60 mol %.
3. Polypropylene composition (C) according to claim 1 , wherein the xylene cold soluble (XCS) fraction of the heterophasic propylene copolymer (HECO1) has an intrinsic viscosity (IV) in the range of 0.8 to 5.5 dl/g.
4. Polypropylene composition (C) according to claim 1 , wherein:
(i) the heterophasic propylene copolymer (HECO1) comprises a (semi)crystalline polypropylene matrix (PM1) and an elastomeric propylene copolymer rubber (EPR1) dispersed in said (semi)crystalline polypropylene matrix (PM1); and
(ii) the heterophasic propylene copolymer (HECO2) comprises a (semi)crystalline polypropylene matrix (PM2) and an elastomeric propylene copolymer rubber (EPR2) dispersed in said (semi)crystalline polypropylene matrix (PM2).
5. Polypropylene composition (C) according to claim 1 , wherein the heterophasic propylene copolymer (HECO1) and the heterophasic propylene copolymer (HECO2) are not modified by treatment with a peroxide (PO).
6. Polypropylene composition (C) according to claim 1 , wherein the inorganic filler (F) is a mineral filler.
7. Polypropylene composition (C) according to claim 6 , wherein the inorganic filler (F) is talc with an average particle size (D 50 ) in the range of 0.5 to 20.0 calculated from the particle size distribution [mass percent] as determined by gravitational liquid sedimentation according to ISO 13317-3 (Sedigraph).
8. Heterophasic propylene copolymer (HECO2), wherein:
(i) the xylene cold soluble (XCS) fraction of the heterophasic propylene copolymer (HECO2) has an intrinsic viscosity (IV) of in the range of 6.0 to 15.0 dl/g;
(ii) the xylene cold soluble (XCS) fraction of the heterophasic propylene copolymer (HECO2) comprises comonomer units derived from C 2 and/or C 4 to C 12 α-olefin in an amount in the range of 62 to 85 mol %; and
(iii) a melt flow rate MFR 2 measured according to ISO 1133 at 230° C., 2.16 kg load of the heterophasic propylene copolymer (HECO2) is in the range of 0.1 to 5.5 g/10 min.
9. Moulded article comprising the polypropylene composition (C) according to claim 1 .
10. Moulded article according to claim 9 , wherein the article is an automotive article.
11. Moulded article of claim 9 , wherein the polypropylene composition (C) enhances paint adhesion of the moulded article.