Grease composition
The invention provides a grease composition, being a grease composition containing a base oil and, as a thickener a calcium complex soap, and being a grease composition using for the carboxylic acids forming the aforementioned calcium complex soap substituted or unsubstituted C18-22 straight-chain higher fatty acids, aromatic monocarboxylic aromatic acids having substituted or unsubstituted benzene rings and C2-4 straight-chain saturated lower fatty acids, wherein the aforementioned substituted or unsubstituted C18-22 straight-chain higher fatty acids include behenic acid and the amount of behenic acid used, as a mass ratio in terms of the total amount of the aforementioned substituted or unsubstituted C18-22 straight-chain higher fatty acids used, is from 25 mass % up to 70 mass %.
1. A grease composition comprising:
(a) a base oil; and
(b) a calcium complex soap thickener content ranging from 5 mass % to 20 mass %, by mass of the grease composition, wherein the calcium complex soap thickener is a reaction product of a plurality of carboxylic acids and a calcium hydroxide, the plurality of carboxylic acids comprising:
(i) 2 mass % to 15 mass % of a C18-C22 straight chain higher fatty acids having a behenic acid content ranging from 25 mass % to 70 mass %, by mass of the C18-C22 straight chain higher fatty acids;
(ii) 0.5 mass % to 3 mass % of an aromatic monocarboxylic acids comprising substituted or unsubstituted benzene rings, and
(iii) 1 mass % to 5 mass % of a C2-C4 straight-chain saturated lower fatty acids.
2. The grease composition in accordance with claim 1 ,
wherein the plurality of carboxylic acids has a greater concentration of the C18-C22 straight-chain higher fatty acids than of the C2-C4 straight-chain saturated lower fatty acids, and
wherein the plurality of carboxylic acids has a greater concentration of the C2-C4 straight-chain saturated lower fatty acids than of the aromatic monocarboxylic acids.
3. The grease composition in accordance with claim 1 , wherein the C18-C22 straight chain higher fatty acids comprise one or more of stearic acid, oleic acid and 12-hydroxystearic acid.
4. The grease composition in accordance with claim 1 ,
wherein the aromatic monocarboxylic acids comprises one or more of acetic acid and butyric acid, and
wherein the C18-C22 straight chain higher fatty acids further comprise stearic acid at a mass ratio of stearic acid to behenic acid ranging from 75:25-30:70.
5. The grease composition in accordance with claim 1 , wherein the aromatic monocarboxylic acids are selected from the group consisting of benzoic acid, methylbenzoic acid, toluic acid, dimethylbenzoic acid, xylylic acid, hemellitc acid, mesitylenic acid, trimethylbenzoic acid, prehnitylic acid, durylic acid, isodurylic acid, 4-isopropylbenzoic acid, hydroxybenzoic acid, dihydroxybenzoic acid, pyrocatachuic acid, resorcylic acid, gentisic acid, protocatechuic acid, trihydroxybenzoic acid, hydroxy-methylbenzoic acid, cresotic acid, dihydroxy-methylbenzoic acid, orsellinic acid, methoxybenzoic acid, anisic acid, dimethoxybenzoic acid, trimethoxybenzoic acid, hydroxy-methoxybenzoic acid, vanillic acid, isovanillic acid, and hydroxydimethoxybenzoic acid.
6. The grease composition in accordance with claim 1 , wherein the C2-C4 straight-chain saturated lower fatty acids are selected from the group consisting of acetic acid, propionic acid, and butyric acid.
7. The grease composition in accordance with claim 1 , wherein the C18-C22 straight chain higher fatty acids comprise one or more of a stearic acid, an oleic acid, arachidinic acid, heneicosanoic acid, 12-hydroxystearic acid, oleic acid, linolenic acid, gadoleic acid, eicosadienoic acid, mead acid, erucic acid, and docosadienoic acid.