WIRE ROD FOR SPRINGS WITH EXCELLENT CORROSION FATIGUE RESISTANCE, STEEL WIRE, AND MANUFACTURING METHOD THEREOF
An aspect of the present invention relates to a wire rod for springs with high strength and excellent corrosion fatigue resistance, in which a combination of Cr, Cu, and Ni content is controlled to an appropriate level, the maximum depth of corrosion pits is set to be below a certain level, and fine carbides containing Mo are set to be at a certain level or greater.
1 . A wire rod for springs with excellent corrosion fatigue resistance, comprising:
C: 0.40 to 0.70%, Si: 1.30 to 2.30%, Mn: 0.20 to 0.80%, Cr: 0.20 to 0.80%, Cu: 0.01 to 0.40%, Ni: 0.10 to 0.60%, Mo: 0.01 to 0.40%, P: 0.02% or less, S: 0.015% or less, N: 0.01% or less, and a balance of Fe and inevitable impurities by weight %,
wherein the wire rod satisfies equation 1 below:
−0.14≤0.70[Cr]−0.76[Cu]−0.24[Ni]≤0.47 Equation 1
where each element symbol is a value of a content of each element measured by weight %,
wherein a microstructure comprises 50 area % or less of ferrite and a balance of pearlite, and
wherein the wire rod comprises 8.0×10 4 count/mm 2 or higher of Mo-based carbides.
2 . The wire rod for springs of claim 1 , further comprising:
one or more elements selected from among V: 0.01 to 0.20%, Ti: 0.01 to 0.15%, and Nb: 0.01 to 0.10% by weight %.
3 . The wire rod for springs of claim 1 , wherein the Mo-based carbide includes 5 weight % of higher of Mo based on carbide.
4 . A method of manufacturing a wire rod for springs with excellent corrosion fatigue resistance, comprising:
heating a billet to 900 to 1100° C., the billet comprising C: 0.40 to 0.70%, Si: 1.30 to 2.30%, Mn: 0.20 to 0.80%, Cr: 0.20 to 0.80%, Cu: 0.01 to 0.40%, Ni: 0.10 to 0.60%, Mo: 0.01 to 0.40%, P: 0.02% or less, S: 0.015% or less, N: 0.01% or less, and a balance of Fe and inevitable impurities by weight % and satisfying equation 1 below:
−0.14≤0.70[Cr]−0.76[Cu]−0.24[Ni]≤0.47 Equation 1
where each element symbol is a value of a content of each element measured by weight %;
obtaining a wire rod by finishing-hot-rolling the heated billet at 800 to 1000° C.; and
coiling the wire rod and cooling the wire rod such that the time for maintaining the wire rod at a temperature in a range of 600 to 700° C. is to be 31 seconds or longer.
5 . The method of claim 4 , wherein the billet further comprises one or more elements selected from among V: 0.01 to 0.20%, Ti: 0.01 to 0.15%, and Nb: 0.01 to 0.10% by weight %.
6 . A steel wire for springs with excellent corrosion fatigue resistance, comprising:
C: 0.40 to 0.70%, Si: 1.30 to 2.30%, Mn: 0.20 to 0.80%, Cr: 0.20 to 0.80%, Cu: 0.01 to 0.40%, Ni: 0.10 to 0.60%, Mo: 0.01 to 0.40%, P: 0.02% or less, S: 0.015% or less, N: 0.01% or less, and a balance of Fe and inevitable impurities by weight %,
wherein the steel wire satisfies equation 1 below:
−0.14≤0.70[Cr]−0.76[Cu]−0.24[Ni]≤0.47 Equation 1
where each element symbol is a value of a content of each element represented by weight %,
wherein a microstructure is tempered martensite, and
wherein the steel wire comprises 8.0×10 4 count/mm 2 or higher of Mo-based carbides.
7 . The steel wire for springs of claim 6 , further comprising:
one or more elements selected from among V: 0.01 to 0.20%, Ti: 0.01 to 0.15%, and Nb: 0.01 to 0.10% by weight %.
8 . The steel wire for springs of claim 6 , wherein the Mo-based carbide comprises 5 weight % or higher of Mo based on carbide.
9 . The steel wire for springs of claim 6 , wherein a maximum depth of a corrosion pit of the steel wire is 120 μm or less.
10 . The steel wire for springs of claim 6 , wherein tensile strength of the steel wire is 1800 MPa or higher.
11 . A method of manufacturing a steel wire for springs with excellent corrosion fatigue resistance, comprising:
obtaining the steel wire by drawing a wire rod manufactured by the method in claim 4 ;
austenitizing the steel wire by heating the steel wire to 850˜1000° C. and maintaining the heated steel wire for 1 minute or longer; and
oil-cooling the austenitized wire rod to 25˜80° C. and tempering the wire rod at 350˜500° C.