IP Library Granted Patent US 12,331,221
Granted Patent B2
US 12,331,221 · App. 16/468,317 · Granted Jun 17, 2025

Use of a particular ethylene-butyl acrylate copolymer in a hot-melt adhesive composition that is transparent in the molten state

Inventors: Jean-Michel Bruneau (Gisors, FR); Martine Le Nobin (Saint-Aubin le Guichard, FR); Jean-Philippe Soriano (Lyons, FR); Florence Quetel (Combon, FR)
Assignee: SK GLOBAL CHEMICAL CO., LTD.
C09J123/0869C08K5/01C09J7/35C09J133/08C09J191/06C09J2203/334C09J2301/304C09J2301/312C09J2301/408C09J2423/04C09J2433/00
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Quick Facts
Patent No.
US 12,331,221
App. No.
16/468,317
Granted
Jun 17, 2025
Kind
B2
Abstract

A thermo-fusible adhesive composition comprising at least one ethylene and butyl acrylate copolymer cohesion agent. The thermo-fusible adhesive composition may further comprise at least one adhesive hydrocarbon resin, preferably hydrogenated, and at least one ethylene and acrylate copolymer. The present disclosure also relates to the use of the corresponding thermo-fusible adhesive compositions in the production of manufactured articles.

Claims (11)

1. A thermo-fusible adhesive composition comprising at least one cohesion agent, the agent comprising at least one copolymer of ethylene and n-butyl acrylate having a melt flow index of 460 to 650 g/10 minutes, measured at a temperature of 190° C., and having a content of 26 to 29% by weight of n-butyl acrylate, calculated with respect to total weight of the copolymer of ethylene and n-butyl acrylate,

wherein the thermo-fusible adhesive composition further comprises:

only one wax chosen from the group consisting of mixtures of paraffin wax and Fisher-Tropsch waxes, the mixtures containing at most 10 wt % of Fisher-Tropsch waxes; and

an aliphatic-modified aromatic hydrogenated hydrocarbon adhesive resin, different from the cohesion agent, is present in a content ranging from 40 to 60% by weight, relative to the total weight of the composition,

wherein the copolymer of ethylene and n-butyl acrylate is present in the thermo-fusible adhesive composition in a content ranging from 30 to 40% by weight, relative to the total weight of the composition,

wherein the composition does not comprise a copolymer of ethylene and vinyl acetate, and the cloud point of the mixture made up of 50% by weight of the at least one copolymer and 50% by weight of the at least one hydrogenated hydrocarbon adhesive is from 50° C. to 90° C., and

wherein the composition is transparent in a molten state when poured at a depth of 5 mm.

2. The thermo-fusible adhesive composition according to claim 1 , wherein the copolymer of ethylene and n-butyl acrylate comprises 28% by weight of n-butyl acrylate relative to the total weight of the copolymer of ethylene and n-butyl acrylate.

3. The composition according to claim 1 , wherein the composition has a viscosity ranging from 300 to 1500 mPa·s, measured at a temperature of 170° C.

4. An article of manufacture comprising a thermo-fusible adhesive composition according to claim 1 .

5. The article of manufacture of claim 4 , wherein the article comprises a package, a binding, a labeling or a banding.

Assignments (3)
CHANGE OF NAME Recorded Sep 2, 2022
From: SK GLOBAL CHEMICAL CO., LTD
To: SK GEO CENTRIC CO., LTD.
Reel/Frame 061371/0332 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Sep 25, 2020
From: ARKEMA FRANCE
To: SK GLOBAL CHEMICAL CO., LTD.
Reel/Frame 053891/0294 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Jul 31, 2019
From: BRUNEAU, JEAN-MICHEL; LE NOBIN, MARTINE; SORIANO, JEAN-PHILIPPE; QUETEL, FLORENCE
To: ARKEMA FRANCE
Reel/Frame 049912/0413 →