Adhesive composition for polarizing plate, polarizing plate, and optical display device
Provided are an adhesive composition for a polarizing plate, a polarizing plate, and an optical display device, the adhesive composition comprising an epoxy-based compound, a (meth)acrylate-based compound, a photo-acid generator, and an optical radical initiator, the (meth)acrylate-based compound comprising a mixture of a bifunctional (meth)acrylate-based compound and a monofunctional (meth)acrylate-based compound having a hydrophobic functional group, wherein the adhesive strength measured after the adhesive composition for a polarizing plate is separately applied to a PET film, a TAC film, and a COP film, to which a polarizer is then bound, followed by photo-curing, is about 200 gf/inch or more.
1. An adhesive composition for polarizing plates, comprising an epoxy compound, a (meth)acrylate compound, and a photoinitiator,
wherein the (meth)acrylate compound comprises a mixture of a bifunctional (meth)acrylate compound and a monofunctional (meth)acrylate compound having a hydrophobic functional group, and
wherein the adhesive composition for polarizing plates has an adhesive strength of about 200 gf/inch or more, as measured after depositing the adhesive composition onto each of a polyethylene terephthalate (PET) film, a triacetylcellulose (TAC) film, and a cycloolefin polymer (COP) film, and bonding a polarizer thereto, followed by photo-curing,
wherein the adhesive composition for polarizing plates is solvent-free and has a viscosity at 25° C. of about 20 cP to about 100 cP, and
wherein the epoxy compound comprises a bifunctional alicyclic epoxy compound, and the bifunctional alicyclic epoxy compound is present in an amount of 50 parts by weight to about 90 parts by weight relative to 100 parts by weight of the epoxy compound and the (meth)acrylate compound.
2. The adhesive composition for polarizing plates according to claim 1 , wherein the epoxy compound further comprises a monofunctional aromatic epoxy compound.
3. The adhesive composition for polarizing plates according to claim 1 , wherein a photo-cured product of the adhesive composition has a modulus at 85° C. of about 500 MPa to less than about 2,000 MPa.
4. The adhesive composition for polarizing plates according to claim 1 , wherein a photo-cured product of the adhesive composition has a maximum tanδ (tanδ max ) of about 0.5 to about 1.
5. The adhesive composition for polarizing plates according to claim 1 , wherein a photo-cured product of the adhesive composition has a glass transition temperature of about 90° C. to about 140° C.
6. The adhesive composition for polarizing plates according to claim 1 , wherein the bifunctional (meth)acrylate compound comprises a mono(alkylene glycol) or poly(alkylene glycol) bifunctional (meth)acrylate compound.
7. The adhesive composition for polarizing plates according to claim 1 , wherein the bifunctional (meth)acrylate compound comprises at least one of di(propylene glycol) di(meth)acrylate, tri(propylene glycol) di(meth)acrylate, di(ethylene glycol) di(meth)acrylate, and tri(ethylene glycol) di(meth)acrylate.
8. The adhesive composition for polarizing plates according to claim 1 , wherein the bifunctional (meth)acrylate compound is present in an amount of about 60 parts by weight to about 80 parts by weight relative to 100 parts by weight of the (meth)acrylate compound.
9. The adhesive composition for polarizing plates according to claim 1 , wherein the monofunctional (meth)acrylate compound has a glass transition temperature (Tg) of about −80° C. to about −10° C. in a homopolymer phase.
10. The adhesive composition for polarizing plates according to claim 1 , wherein the monofunctional (meth)acrylate compound comprises a C 10 to C 20 linear or branched hydrophobic alkyl group-containing monofunctional (meth)acrylate compound.
11. The adhesive composition for polarizing plates according to claim 1 , wherein the monofunctional (meth)acrylate compound is present in an amount of about 10 parts by weight to about 40 parts by weight relative to 100 parts by weight of the (meth)acrylate compound.
12. A polarizing plate comprising a polarizer and an optical film formed on at least one surface of the polarizer,
wherein the optical film is formed of the adhesive composition for polarizing plates according to claim 1 .
13. The polarizing plate according to claim 12 , wherein the polarizing plate has a color coordinate bs value of about 3 or less.
14. An optical display comprising the polarizing plate according to claim 12 .