SCR catalyst modules and associated catalytic reactors
In one aspect, catalyst modules are described herein comprises structural catalyst bodies having cross-sectional flow channel geometries and surface features for enhanced catalytic activity. In some embodiments, the catalyst modules and associated structural catalyst bodies are suitable for use in high particulate matter environments. Briefly, a catalyst module comprises a framework and a plurality of structural catalyst bodies positioned in the framework, a structural catalyst body comprising an outer peripheral wall and a plurality of inner partition walls forming individual flow channels of rectangular cross-section, the outer peripheral wall resistant to localized flexural failures induced by material between adjacent structural catalyst bodies of the module.
1. A catalyst module comprising:
a framework; and
a plurality of structural catalyst bodies positioned in the framework with a compressible matting material positioned between the structural catalyst bodies, wherein the structural catalyst bodies comprise an outer peripheral wall and a plurality of inner partition walls forming individual flow channels of rectangular cross-section, the outer peripheral wall and inner partition walls have dispersed throughout a chemical composition comprising 50-99.9 weight percent an inorganic oxide composition and at least 0.1 weight percent a catalytically active metal functional group, wherein 10 the inner partition walls intersect the outer peripheral wall to define segments of the outer peripheral wall greater than 10 mm in length and having flexural strength (σ) of at least 2.5 MPa, and wherein the compressible matting material has a Young's modulus less than 1 GPa under compression.
2. The catalyst module of claim 1 , wherein an outer peripheral wall segment exhibits a flexural strength (σ′) of at least 0.7 MPa when excised from the structural catalyst body.
3. The catalyst module of claim 1 , wherein the intersecting inner partition walls forming flow channels with the outer peripheral wall are at least 20 percent shorter than the outer peripheral wall segments.
4. The catalyst module of claim 1 , wherein the structural catalyst body has a flow channel density less than 1.5 cm −2 .
5. The catalyst module of claim 1 , wherein the matting material is at compression 10 percent of the uncompressed state.
6. The catalyst module of claim 1 , wherein the compressible matting material separates adjacent structural catalyst bodies.
7. The catalyst module of claim 6 , wherein at least 50 percent of interfaces between the structural catalyst bodies are sealed by the matting material.
8. The catalyst module of claim 1 , wherein the compressible matting material is positioned between the module framework and structural catalyst bodies adjacent to the module framework.
9. The catalyst module of claim 1 , wherein the module is subjected to cycling between 40° C. and 200° C. in a coal-fired SCR reactor.
10. The catalyst module of claim 1 , wherein less than 50 percent of outer peripheral wall segments in the module exhibit failure.
11. The catalyst module of claim 1 , wherein the outer peripheral wall segments have a length of 12-20 mm.
12. The catalyst module of claim 1 , wherein the outer peripheral wall segments are of the same length.
13. The catalyst module of claim 1 , wherein length of the outer peripheral wall segments varies along the structural catalyst body perimeter.
14. The catalyst module of claim 1 , wherein the structural catalyst bodies have an areal weight density less than 12 g/m 2 .
15. The catalyst module of claim 1 , wherein the structural catalyst bodies have an erosion weight loss of less than or equal to 0.13 g.
16. The catalyst module of claim 1 , wherein the structural catalyst bodies have an open frontal area of at least 80%.