IP Library Granted Patent US 11,268,175
Granted Patent B2
US 11,268,175 · App. 16/468,886 · Granted Mar 8, 2022

High-strength steel having excellent fracture initiation resistance and fracture propagation arrestability at low temperature and method of manufacturing the same

Inventors: Kyung-Keun Um (Pohang-si, KR); Woo-Gyeom Kim (Pohang-si, KR); Woo-Yeol Cha (Pohang-si, KR); Jin-Woo Chae (Pohang-si, KR)
Assignee: POSCO
C22C38/20C21D8/021C21D8/0205C21D8/0226C21D9/0081C21D9/46C22C38/34C21D1/18C21D2211/001C21D2211/005C21D2211/008
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Quick Facts
Patent No.
US 11,268,175
App. No.
16/468,886
Granted
Mar 8, 2022
Kind
B2
Abstract

An aspect of the present invention relates to a high-strength steel, having excellent fracture initiation resistance and fracture propagation arrestability at low temperature.

Claims (22)

1. A high-strength steel comprising:

by wt %, 0.02 to 0.09% of C, 0.005 to 0.019% of Si, 0.5 to 1.68% of Mn, 0.001 to 0.035% of Sol.Al, 0.03% or less of Nb, excluding 0%, 0.01% or less of V, excluding 0%, 0.001 to 0.02% or Ti, 0.01 to 1.0% of Cu, 0.01 to 2.0% of Ni, 0.01 to 0.03% of Cr, 0.001 to 0.5% of Mo, 0.0002 to 0.005% of Ca, 0.001 to 0.006% of N, 0.02% or less of P, excluding 0%, 0.003% or less of S, excluding 0%, 0.002% or less of 0, excluding 0%, and a balance of Fe and inevitable impurities,

wherein the high-strength steel satisfies Relational Expression 1 below,

5*C+Si+10*sol.Al≤0.6  Relational Expression 1

where each element symbol indicates a content of each element by wt %,

wherein a microstructure comprises a sum of polygonal ferrite and acicular ferrite of 50 area % or higher, and comprises a martensite-austenite multiphase, an MA phase, of 3.5 area % or lower, and

wherein the steel comprises inclusions, and a number of inclusions having a size of 10 μm or greater is 11 count/cm 2 or lower.

2. The high-strength steel of claim 1 , wherein an average size of the MA phase measured in equivalent circular diameter is 2.5 μm or less.

3. The high-strength steel of claim 1 , wherein polygonal ferrite and acicular ferrite are not process-hardened by a hot-rolling process.

4. The high-strength steel of claim 1 , wherein the steel has yield strength of 355 MPa or higher, an impact energy value of 300 J or higher at −60° C., and a Crack Tip Opening Displacement Test (CTOD) value of 0.3 mm or higher at −40° C.

5. The high-strength steel of claim 1 , wherein the steel has tensile strength of 450 MPa or higher.

6. A method of manufacturing a high-strength steel, the method comprising:

preparing a slab comprising, by wt %, 0.02 to 0.09% of C, 0.005 to 0.019% of Si, 0.5 to 1.68% of Mn, 0.001 to 0.035% of Sol.Al, 0.03% or less of Nb, excluding 0%, 0.01% or less of V, excluding 0%, 0.001 to 0.02% or Ti, 0.01 to 1.0% of Cu, 0.01 to 2.0% of Ni, 0.01 to 0.03% of Cr, 0.001 to 0.5% of Mo, 0.0002 to 0.005% of Ca, 0.001 to 0.006% of N, 0.02% or less of P, excluding 0%, 0.003% or less of S, excluding 0%, 0.002% or less of 0, excluding 0%, and a balance of Fe and inevitable impurities, and satisfying Relational Expression 1 below,

5*C+Si+10*sol.Al≤0.6  Relational Expression 1

where each element symbol indicates a content of each element by wt %; heating the slab to 1000 to 1200° C.;

finish-hot-rolling the heated slab at 680° C. or higher and obtaining a hot-rolled steel sheet;

cooling the hot-rolled steel sheet, and

a tempering process in which the cooled hot-rolled steel sheet is heated to 450 to 700° C., and the heated hot-rolled steel sheet is maintained for 1.3*t+10 minutes to 1.3*t+200 minutes and is cooled, where t is a value of a thickness of the hot-rolled steel sheet measured in mm unit,

wherein the cooling comprises cooling the hot-rolled steel sheet to a cooling terminating temperature of 300 to 650° C. at a cooling rate of 2 to 10° C./s, and

wherein the preparing the slab comprises:

adding Ca or Ca alloys to molten steel in a final stage of a secondary refining process; and

performing bubbling and refluxing processes using an Ar gas for at least three minutes after adding Ca or Ca alloys.

Assignments (3)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Oct 26, 2022
From: POSCO HOLDINGS INC.
To: POSCO CO., LTD
Reel/Frame 061778/0785 →
CHANGE OF NAME Recorded Sep 28, 2022
From: POSCO
To: POSCO HOLDINGS INC.
Reel/Frame 061561/0923 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Jun 13, 2019
From: UM, KYUNG KEUN; KIM, WOO-GYEOM; CHA, WOO-YEOL; CHAE, JIN-WOO
To: POSCO
Reel/Frame 049456/0383 →
Priority Claims (1)
KR 10-2016-0178102 · Dec 23, 2016 · national
Continuity (1)
Related Publication 20200080179A1 · Mar 12, 2020
Cited By (1)
US 12,559,813