IP Library Granted Patent US 12,446,574
Granted Patent B2
US 12,446,574 · App. 16/469,128 · Granted Oct 21, 2025

Adjuvants for agrochemical formulations

Inventors: Gordon Alastair Bell (Bracknell, GB); Flavio Castagnini (Münchwilen, CH)
Assignee: SYNGENTA CROP PROTECTION AG
A01N25/04A01N25/30A01N43/50A01N31/02A01N43/08A01N43/16
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Quick Facts
Patent No.
US 12,446,574
App. No.
16/469,128
Granted
Oct 21, 2025
Kind
B2
Abstract

The present invention relates to an aqueous formulation comprising an agrochemical at a concentration of up to 45% w/w; a non-ionic surfactant with a cloud point of from 35° C. to 55° C. at a concentration of up to 60% w/w; an ethoxylated or propoxylated sorbitan ester at a concentration from 1% to 40% w/w; an alkyl polyglucoside, propylene glycol, glycerol or a glycol ether or two or more of these compounds, at a concentration from 1% to 40% w/w; and water at a concentration of at least 1% w/w. The formulation provides low and high temperature stability.

Claims (19)

1. A formulation, comprising:

(i) imazamox at a concentration of 1 to 20% w/w;

(ii) a non-ionic surfactant with a cloud point of from 35° C. to 55° C. and which is not component (iii) or (iv) at a concentration of from 10 to 60% w/w;

(iii) an ethoxylated or propoxylated sorbitan ester at a concentration from 8 to 20% w/w;

(iv) propylene glycol at a concentration from 8 to 20% w/w; and

(v) water at a concentration of at least 1% w/w;

wherein the formulation is a soluble liquid; and

wherein the formulation remains clear and isotropic after 24 hours at any temperature between −10° C. and 50° C.

2. The formulation of claim 1 , wherein the non-ionic surfactant has a viscosity in water at 23° C., at a concentration of from 10 to 90% w/w, of less than 5000 mPas, and wherein (iii) is a polysorbate-type nonionic surfactant formed by the ethoxylation of sorbitan before the addition of lauric acid.

3. The formulation of claim 1 , wherein

the ratio of (iv) to (i) is greater than 1:1;

the ratio of (ii) to (iv) is 0.625 to 5:1; and

the ratio of (iii) to (iv) is 0.625 to 2:1.

4. The formulation of claim 1 , wherein the non-ionic surfactant has a cloud point from 40° C. to 50° C.

5. The formulation of claim 1 , wherein (iii) is a polysorbate-type nonionic surfactant formed by the ethoxylation of sorbitan before the addition of lauric, palmitic, stearic or oleic acid.

6. The formulation of claim 1 , wherein (iii) is a polysorbate-type nonionic surfactant formed by the ethoxylation of sorbitan before the addition of lauric acid.

7. The formulation of claim 1 , wherein

the ratio of (ii) to (iv) is 0.625 to 5:1; and

the ratio of (iii) to (iv) is 0.625 to 2:1.

Assignments (2)
MERGER Recorded Jul 29, 2024
From: SYNGENTA PARTICIPATIONS AG
To: SYNGENTA CROP PROTECTION AG
Reel/Frame 068114/0282 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Aug 19, 2019
From: BELL, GORDON ALASTAIR; CASTAGNINI, FLAVIO
To: SYNGENTA PARTICIPATIONS AG
Reel/Frame 050084/0627 →
Priority Claims (1)
GB 1621375 · Dec 15, 2016 · national
Continuity (1)
Related Publication 20200022365A1 · Jan 23, 2020
References Cited (13)
US 7135437B2 · Pallas · 2006 [cited by examiner]
US 7135438B1 · Batlogg et al. · 2006 [cited by applicant]
US 20150080273A1 · Hatchman · 2015 [cited by examiner]
US 20150237861A1 · Gobbi · 2015 [cited by examiner]
US 20160244562A1 · Lindner · 2016 [cited by examiner]
EP 0943241A1 · 1999 [cited by examiner]
EP 2545774A1 · 2013 [cited by examiner]
JP 2015511594A · 2015 [cited by applicant]
WO 2010003889A1 · 2010 [cited by applicant]
WO 2013135604A1 · 2013 [cited by applicant]
Plurafac LF types, Mar. 2013, BASF The Chemical Company, p. 1-9 (Year: 2013). [cited by examiner]
Reza Najjar, Microemulsions—A brief introduction, 2012, InTech, (Year: 2012). [cited by examiner]
International Search Report for International Patent Application No. PCT/EP2017/082260 mailed Feb. 13, 2018. [cited by applicant]