ORGANIC ELECTROLUMINESCENT ELEMENT

1 . An organic electroluminescent element comprising a pair of electrodes composed of a positive electrode and a negative electrode and a light emitting layer disposed between the pair of electrodes, in which

the light emitting layer comprises at least one of a compound represented by the following general formula (1) and a multimer having a plurality of structures represented by the following general formula (1), and a compound represented by the following general formula (2A) or general formula (2B).

(In the above formula (1),

ring A, ring B and ring C each independently represent an aryl ring or a heteroaryl ring, while at least one hydrogen atom in these rings may be substituted,

X 1 and X 2 each independently represent >O or >N—R, R of the >N—R is an optionally substituted aryl, an optionally substituted heteroaryl or an optionally substituted alkyl, R of the >N—R may be bonded to the ring A, ring B, and/or ring C with a linking group or a single bond, and

at least one hydrogen atom in a compound or a structure represented by formula (1) may be substituted by a halogen atom, a cyano or a deuterium atom.)

(In the above formula (2A) or (2B),

X's each independently represent an aryl having 6 to 30 carbon atoms or a heteroaryl having 2 to 30 carbon atoms, which may be substituted by an alkyl,

Z represents a single bond or a divalent group represented by any one of the above formulas (2-Z1) to (2-Z7), and is bonded to an anthracene skeleton in formula (2A) or (2B) at * in formulas (2-Z1) to (2-Z7),

in formulas (2-Z1) to (2-Z5), n represents 1 or 2,

in formula (2-Z6) or (2-Z7), Y represents >O, >S, >N—R, or >C(—R) 2 , the R represents an alkyl having 1 to 4 carbon atoms or an aryl having 6 to 12 carbon atoms, and R's in >C(—R) 2 may be bonded to each other to form a spiro structure, and

at least one hydrogen atom in the compound represented by formula (2A) or (2B) may be substituted by a halogen atom, a cyano, or a deuterium atom.)

2 . The organic electroluminescent element described in claim 1 , wherein

in the above formula (2A) or (2B),

X's each independently represent phenyl, biphenylyl, terphenylyl, quaterphenylyl, naphthyl, fluorenyl, phenalenyl, phenanthrenyl, triphenylenyl, benzofluorenyl, dibenzofuranyl, dibenzothiophenyl, naphthobenzofuranyl, or naphthobenzothiophenyl, and at least one hydrogen atom in these may be substituted by an alkyl having 1 to 12 carbon atoms,

Z represents a single bond or a divalent group represented by any one of the above formulas (2-Z1) to (2-Z7), and is bonded to an anthracene skeleton in formula (2A) or (2B) at * in formulas (2-Z1) to (2-Z7),

in formula (2-Z2) or (2-Z3), n represents 1,

in formula (2-Z1), (2-Z4), or (2-Z5), n represents 1 or 2,

in formula (2-Z6) or (2-Z7), Y represents >O, >S, >N—R, or >C(—R) 2 , the R represents methyl, ethyl, phenyl, or naphthyl, and R's in >C(—R) 2 may be bonded to each other to form a spiro structure, and

at least one hydrogen atom in the compound represented by formula (2A) or (2B) may be substituted by a halogen atom, a cyano, or a deuterium atom.

3 . The organic electroluminescent element described in claim 1 , wherein

in the above formula (2A) or (2B),

X's each independently represent phenyl, biphenylyl, terphenylyl, naphthyl, fluorenyl, phenalenyl, phenanthrenyl, triphenylenyl, dibenzofuranyl, dibenzothiophenyl, naphthobenzofuranyl, or naphthobenzothiophenyl, and at least one hydrogen atom in these may be substituted by an alkyl having 1 to 4 carbon atoms,

Z represents a single bond or a divalent group represented by any one of the above formulas (2-Z1) to (2-Z7), and is bonded to an anthracene skeleton in formula (2A) or (2B) at * in formulas (2-Z1) to (2-Z7),

in formula (2-Z2) or (2-Z3), n represents 1,

in formula (2-Z1), (2-Z4), or (2-Z5), n represents 1 or 2,

in formula (2-Z6) or (2-Z7), Y represents >O, >S, or >N—R, and the R represents phenyl, and

at least one hydrogen atom in the compound represented by formula (2A) or (2B) may be substituted by a halogen atom, a cyano, or a deuterium atom.

4 . The organic electroluminescent element described in claim 1 , wherein the compound represented by the above formula (2A) or (2B) is a compound represented by any one of the following structural formulas

5 . The organic electroluminescent element described in claim 1 , in which

in the above formula (1),

the ring A, ring B, and ring C each independently represent an aryl ring or a heteroaryl ring, while at least one hydrogen atom in these rings may be substituted by a substituted or unsubstituted aryl, a substituted or unsubstituted heteroaryl, a substituted or unsubstituted diarylamino, a substituted or unsubstituted diheteroarylamino, a substituted or unsubstituted arylheteroarylamino, a substituted or unsubstituted alkyl, a substituted or unsubstituted alkoxy, or a substituted or unsubstituted aryloxy, each of these rings has a 5-membered or 6-membered ring sharing a bond with a fused bicyclic structure at the center of the above formula constructed by B, X 1 , and X 2 ,

X 1 and X 2 each independently represent >O or >N—R, R of the >N—R each independently represents an aryl which may be substituted by an alkyl, a heteroaryl which may be substituted by an alkyl or alkyl, R of the >N—R may be bonded to the ring A, ring B, and/or ring C with —O—, —S—, —C(—R) 2 — or a single bond, R of the —C(—R) 2 — represents a hydrogen atom or an alkyl,

at least one hydrogen atom in a compound or structure represented by formula (1) may be substituted by a halogen atom, a cyano or a deuterium atom, and

in a case of a multimer, the multimer is a dimer or a trimer having two or three structures represented by formula (1).

6 . The organic electroluminescent element described in claim 1 , wherein the compound represented by the above general formula (1) is a compound represented by the following general formula (1′)

In the above formula (1′),

R 1 to R 11 each independently represent a hydrogen atom, an aryl, a heteroaryl, a diarylamino, a diheteroarylamino, an arylheteroarylamino, an alkyl, an alkoxy, or an aryloxy, while at least one hydrogen atom in these may be substituted by an aryl, a heteroaryl, or an alkyl, adjacent groups among R 1 to R 11 may be bonded to each other to form an aryl ring or a heteroaryl ring together with ring a, ring b, or ring c, at least one hydrogen atom in the ring thus formed may be substituted by an aryl, a heteroaryl, a diarylamino, a diheteroarylamino, an arylheteroarylamino, an alkyl, an alkoxy, or an aryloxy, at least one hydrogen atom in these may be substituted by an aryl, a heteroaryl or an alkyl,

X 1 and X 2 each independently represent >N—R, R of the >N—R represents an aryl having 6 to 12 carbon atoms, a heteroaryl having 2 to 15 carbon atoms, or an alkyl having 1 to 6 carbon atoms, R of the >N—R may be bonded to the ring a, ring b and/or ring c with —O—, —S—, —C(—R) 2 —, or a single bond, R of the —C(—R) 2 — represents an alkyl having 1 to 6 carbon atoms, and

at least one hydrogen atom in a compound represented by formula (1′) may be substituted by a halogen atom or a deuterium atom.

7 . The organic electroluminescent element described in claim 6 , in which

in the above formula (1′),

R 1 to R 11 each independently represent a hydrogen atom, an aryl having 6 to 30 carbon atoms, a heteroaryl having 2 to 30 carbon atoms or a diarylamino (the aryl is an aryl having 6 to 12 carbon atoms), adjacent groups among R 1 to R 11 may be bonded to each other to form an aryl having 9 to 16 carbon atoms or a heteroaryl ring having 6 to 15 carbon atoms together with the ring a, ring b, or ring c, at least one hydrogen atom in the ring thus formed may be substituted by an aryl having 6 to 10 carbon atoms,

X 1 and X 2 each independently represent >N—R, R of the >N—R is an aryl having 6 to 10 carbon atoms, and

at least one hydrogen atom in a compound represented by formula (1′) may be substituted by a halogen atom or a deuterium atom.

8 . The organic electroluminescent element described in claim 1 , wherein the compound represented by the above formula (1) is a compound represented by any of the following structural formulas

9 . The organic electroluminescent element described in claim 1 , further comprising an electron transport layer and/or an electron injection layer disposed between the negative electrode and the light emitting layer, in which at least one of the electron transport layer and the electron injection layer comprises at least one selected from the group consisting of a borane derivative, a pyridine derivative, a fluoranthene derivative, a BO-based derivative, an anthracene derivative, a benzofluorene derivative, a phosphine oxide derivative, a pyrimidine derivative, a carbazole derivative, a triazine derivative, a benzimidazole derivative, a phenanthroline derivative, and a quinolinol-based metal complex.

10 . The organic electroluminescent element described in claim 9 , in which the electron transport layer and/or electron injection layer further comprise/comprises at least one selected from the group consisting of an alkali metal, an alkaline earth metal, a rare earth metal, an oxide of an alkali metal, a halide of an alkali metal, an oxide of an alkaline earth metal, a halide of an alkaline earth metal, an oxide of a rare earth metal, a halide of a rare earth metal, an organic complex of an alkali metal, an organic complex of an alkaline earth metal, and an organic complex of a rare earth metal.

11 . A display apparatus comprising the organic electroluminescent element described in claim 1 .

12 . A lighting apparatus comprising the organic electroluminescent element described in claim 1 .