Sour-resistant heavy-wall steel plate having excellent low-temperature toughness and post-heat treatment characteristics and method for manufacturing same
Provided are: a SOUR-resistant heavy-wall steel plate having excellent low-temperature toughness and post-heat treatment characteristics; and a method for manufacturing the same. The SOUR-resistant heavy-wall steel plate of the present invention comprises: in terms of weight %, 0.02-0.06% of C; 0.5% or less of Si (excluding 0%); 0.8-2.0% of Mn; 0.03% or less of P; 0.003% or less of S; 0.06% or less of Al; 0.01% or less of N; 0.005-0.1% of Nb; 0.005-0.05% of Ti; 0.0005-0.005% of Ca; one or more selected from 0.05-0.5% of Ni, 0.05-0.5% of Cr, 0.02-0.4% of Mo, and 0.005-0.1% of V; and the remainder Fe and unavoidable impurities, wherein the heavy-wall steel plate satisfies relational expressions 1-3, and has a percent ductile fracture of 85% or more in the drop weight tear test (DWTT) at −20° C.
1. A SOUR-resistant heavy-wall steel plate, the SOUR-resistant heavy-wall steel plate comprises:
in terms of weight %, 0.02-0.06% of C; 0.5% or less of Si (excluding 0%); 0.8-2.0% of Mn; 0.03% or less of P; 0.003% or less of S; 0.06% or less of Al; 0.01% or less of N; 0.005-0.1% of Nb; 0.005-0.05% of Ti; 0.0005-0.005% of Ca; one or more selected from 0.05-0.5% of Ni, 0.05-0.5% of Cr, 0.02-0.4% of Mo, and 0.005-0.1% of V; and the remainder Fe and unavoidable impurities,
wherein the heavy-wall steel plate has a microstructure consisting of a complex structure of acicular ferrite and polygonal ferrite, and a fraction of upper bainite within 10 mm of upper and lower portions on a basis of a thickness central portion of the heavy-wall steel plate is 5 area or less,
wherein the heavy-wall steel plate satisfies relational expressions 1-3, and has a percent ductile fracture of 85% or more in the drop weight tear test (DWTT) at −20° C.,
Ca/S: 0.5˜5.0 [Relation Expression 1]
Ni+Cr+Mo+V≤0.8% [Relational Expression 2]
Nb−0.5*C+0.35*N>0% [Relational Expression 3]
where Ca, S, Ni, Cr, Mo, V, Nb, C, and N represent contents of respective elements by wt %.
2. The SOUR-resistant heavy-wall steel plate of claim 1 , wherein the heavy-wall steel plate has a thickness of 30 mm or more, a width of 3500 mm or more, and yield strength of 500 MPa or more.
3. The SOUR-resistant heavy-wall steel plate of claim 1 , wherein the yield strength of the heavy-wall steel plate is not decreased after Post Weld Heat Treatment (PWHT).
4. A method of manufacturing a SOUR-resistant heavy-wall steel plate having low-temperature toughness and hot-heat treatment characteristics, the method comprising:
rough rolling a steel slab including, in terms of weight %, 0.02-0.06% of C; 0.5% or less of Si (excluding 0%); 0.8-2.0% of Mn; 0.03% or less of P; 0.003% or less of S; 0.06% or less of Al;
0.01% or less of N; 0.005-0.1% of Nb; 0.005-0.05% of Ti; 0.0005-0.005% of Ca; one or more selected from 0.05-0.5% of Ni, 0.05-0.5% of Cr, 0.02-0.4% of Mo, and 0.005-0.1% of V; and the remainder Fe and unavoidable impurities, and satisfying relational expressions 1-3, after reheating the steel slab;
controlling maintaining time, until start of finish rolling after water-cooling the rough rolled steel slab, to be 300 seconds or less, and then finish rolling the steel slab at Ar3+200° C. to Ar3+30° C. at a cumulative reduction ratio of 50% or more; and
starting to cool the finish rolled steel slab at Ar3+100° C. to Ar3 at a cooling rate of 15° C./sec and ending the cooling at 500° C. or less,
wherein the heavy-wall steel plate, obtained by ending the cooling, has a microstructure consisting of a complex structure of acicular ferrite and polygonal ferrite, and
a fraction of the upper bainite within 10 mm of upper and lower portions on the basis of a thickness central portion is 5 area % or less, [Relation Expression 1]
Ca/S: 0.5˜5.0 [Relation Expression 1]
Ni+Cr+Mo+V≤0.8% [Relational Expression 2]
Nb−0.5*C+0.35*N>0% [Relational Expression 3]
where Ca, S, Ni, Cr, Mo, V, Nb, C, and N represent contents of respective elements by wt %.
5. The method of claim 4 , wherein the heavy-wall steel plate, obtained by ending the cooling, a thickness of 30 mm or more, a width of 3500 mm or more, and yield strength of 500 MPa or more.
6. The method of claim 4 , further comprising: performing a Post Weld Heat Treatment (PWHT) heat treatment on the heavy-wall steel plate obtained by ending the cooling.
7. The method of claim 6 , wherein the yield strength of the heavy-wall steel plate is not decreased even after performing the PWHT heat treatment.