Annealing separator composition for oriented electrical steel sheet, oriented electrical steel sheet, and method for manufacturing oriented electrical steel sheet
The present invention has been made in an effort to provide an annealing separator component for an oriented electrical steel sheet, an oriented electrical steel sheet, and a manufacturing method thereof. According to an exemplary embodiment of the present invention, an annealing separator composition for an oriented electrical steel sheet, includes: 100 weight parts of at least one of magnesium oxide and magnesium hydroxide; and 5 to 200 weight parts of aluminum hydroxide.
1. An oriented electrical steel sheet comprising a coating including an Al-Si-Mg composite formed on one or opposite sides of a substrate of an oriented electrical steel sheet,
wherein an oxide layer is formed from an interface between the coating and the substrate to an interior of the substrate,
wherein the oxide layer contains an aluminum oxide,
wherein an average particle diameter of the aluminum oxide is 5 to 100 μm with respect to a cross-section in a thickness direction of the steel sheet, and
wherein an occupying area of the aluminum oxide relative to an area of the oxide layer is 0.1 to 50% with respect to the cross-section in the thickness direction of the steel sheet.
2. An oriented electrical steel sheet of claim 1 , wherein
the coating contains 0.1 to 40 wt % of Al, 40 to 85 wt % of Mg, 0.1 to 40 wt % of Si, 10 to 55 wt % of O, and Fe as a balance.
3. The oriented electrical steel sheet of claim 1 , wherein
the coating further includes an Mg—Si composite, an Al—Mg composite, or an Al—Si composite.
4. The oriented electrical steel sheet of claim 1 , wherein
the coating has a thickness of 0.1 to 10 μm.
5. The oriented electrical steel sheet of claim 1 , wherein
the substrate of the oriented electrical steel sheet contains 2.0 to 7.0 wt % of silicon (Si), 0.020 to 0.040 wt % of aluminum (Al), 0.01 to 0.20 wt % of manganese (Mn), 0.01 to 0.15 wt % of phosphorus (P), 0.01 wt % or less (excluding 0 wt %) of carbon (C), 0.005 to 0.05 wt % of nitrogen (N), and 0.01 to 0.15 wt % of antimony (Sb), tin (Sn), or a combination thereof, and the balance contains Fe and other inevitable impurities.
6. A method for manufacturing a grain-oriented electrical steel sheet of claim 1 comprising:
preparing a steel slab; heating the steel slab;
hot rolling the heated steel slab to produce a hot rolled sheet; cold rolling the hot rolled sheet to produce a cold rolled sheet; primary recrystallization annealing the cold rolled sheet;
applying an annealing separator to the surface of the primary recrystallization annealed steel sheet; and
secondary recrystallization annealing the steel sheet applied with the annealing separator thereto,
thereby producing the grain-oriented electrical steel of claim 1 ,
wherein the annealing separator comprises 100 parts by weight of at least one of magnesium oxide and magnesium hydroxide; 5 to 200 parts by weight of aluminum hydroxide; and 0.1 to 20 parts by weight of a boron compound.
7. The manufacturing method of claim 6 , wherein
the performing of the first recrystallization annealing on the cold-rolled sheet includes
simultaneously performing decarburizing annealing and nitriding annealing on the cold-rolled sheet or performing the nitriding annealing after the decarburizing annealing.