Non-oriented electrical steel sheet and method for producing same
A non-grain oriented electrical steel sheet according to an exemplary embodiment of the present invention includes Si: 1.0 to 4.0%, Mn: 0.1 to 1.0%, Al: 0.1 to 1.5%, Zn: 0.001 to 0.01% B: 0.0005 to 0.005%, and a balance including Fe and inevitable impurities.
1. A non-grain oriented electrical steel sheet comprising Si: 1.0 to 4.0%, Mn: 0.1 to 1.0%, Al: 0.1 to 1.5%, Zn: 0.001 to 0.01%, B: 0.0005 to 0.005% by wt %, and a balance including Fe and inevitable impurities,
wherein for a surface of the steel sheet a density of a Si oxide with a particle diameter of 50 to 200 nm is 5 units/μm 2 or less.
2. The non-grain oriented electrical steel sheet of claim 1 , further comprising
P: 0.001 to 0.1 wt %, C: 0.005 wt % or less, S: 0.001 to 0.005 wt %, N: 0.005 wt % or less, and Ti: 0.005 wt % or less.
3. The non-grain oriented electrical steel sheet of claim 1 , further comprising one or more of Sn and Sb alone or as a sum amount of 0.06 wt % or less.
4. The non-grain oriented electrical steel sheet of claim 1 , further comprising
one or more of Cu: 0.05 wt % or less, Ni: 0.05 wt % or less, Cr: 0.05 wt % or less, Zr: 0.01 wt % or less, Mo: 0.01 wt % or less, and V: 0.01 wt % or less.
5. The non-grain oriented electrical steel sheet of claim 1 ,
wherein an iron loss (W 15/50 ) is 2.80 W/kg or less, and a magnetic flux density B 50 is 1.70 T or more.
6. A manufacturing method of a non-grain oriented electrical steel sheet comprising:
a step of heating a slab including Si: 1.0 to 4.0%, Mn: 0.1 to 1.0%, Al: 0.1 to 1.5%, Zn: 0.001 to 0.01%, B: 0.0005 to 0.005% and a balance including Fe and inevitable impurities by wt %;
a step of hot-rolling the slab to manufacturing a heat rolled sheet; a step of cold roiling the heat rolled sheet to manufacturing a cold roiled sheet; and a step of final annealing the cold rolled sheet;
wherein the step of the final annealing includes a hydrogen gas as an atmosphere gas and a content ratio of the hydrogen gas within the atmostpher gas satisfies the following Equation 1:
0.01≤([Zn]+[B])×100/[H 2 ]≤0.06 [Equation 1]
wherein in Equation 1, [Zn] and [B] represent each content by wt % of Zn and B, and [H 2 ] represents a content by vol % of hydrogen gas within an atmosphere gas, thereby producing the non-grain oriented electrical steel sheet of claim 1 .
7. The manufacturing method of the non-grain oriented electrical steel sheet of claim 6 , wherein
the slab further includes P: 0.001 to 0.1 wt %, C: 0.005 wt % or less, S; 0.001 to 0.005 wt %, N: 0.005 wt % or less, and Ti: 0.005 wt % or less.
8. The manufacturing method of the non-grain oriented electrical steel sheet of claim 6 ,
wherein the slab further includes one kind or more of Sn and Sb alone or as a sum amount of 0.06 wt % or less.
9. The manufacturing method of the non-grain oriented electrical steel sheet of claim 6 , wherein
the slab further includes one kind or more of Cu: 0.05 wt % or less, Ni: 0.05 wt % or less, Cr: 0.05 wt % or less, Zr: 0.01 wt % or less, Mo: 0.01 wt % or less, and V: 0.01 wt % or less.
10. The manufacturing method of the non-grain oriented electrical steel sheet of claim 6 , further comprising,
after the step of manufacturing the heat rolled sheet,
a step of annealing the heat rolled sheet.