GRAIN-ORIENTED ELECTRICAL STEEL SHEET AND MANUFACTURING METHOD THEREFOR
A grain-oriented electrical steel sheet according to an embodiment of the prevent invention comprises: Si: 1.0% to 7.0%, C: 0.005% or less (excluding 0%), P: 0.0010 to 0.1%, Sn: 0.005 to 0.2%, S: 0.0005 to 0.020%, Se: 0.0005 to 0.020% and B: 0.0001 to 0.01% by weight, and the remainder comprising Fe and other inevitable impurities.
1 . A grain-oriented electrical steel sheet comprising:
Si: 1.0% to 7.0%, C: 0.005% or less (excluding 0%), P: 0.0010 to 0.1%, Sn: 0.005 to 0.2%, S: 0.0005 to 0.020%, Se: 0.0005 to 0.020% and B: 0.0001 to 0.01% by weight, and the remainder comprising Fe and other inevitable impurities.
2 . The grain-oriented electrical steel sheet of claim 1 , comprising 0.005 to 0.04 wt % of S and Se in a total amount.
3 . The grain-oriented electrical steel sheet of claim 1 , further comprising
Al: 0.010 wt % or less, Mn: 0.08 wt % or less and N: 0.005 wt % or less.
4 . The grain-oriented electrical steel sheet of claim 1 , further comprising 0.005 wt % or less of at least one of Ti, Mg and Ca, respectively.
5 . The grain-oriented electrical steel sheet of claim 1 , comprising
composite grain boundary segregation of S and Se, and composite inclusion of Fe (S, Se).
6 . The grain-oriented electrical steel sheet of claim 1 , comprising 0.01 to 500 pieces/mm 2 of inclusions comprising Al, Mn, Si, Mg, Ca, B or Ti.
7 . A method for manufacturing a grain-oriented electrical steel sheet, the method comprising:
heating a slab comprising Si: 1.0 to 7.0%, C: 0.001 to 0.10%, P: 0.0010 to 0.1%, Sn: 0.005 to 0.2%, S: 0.0005 to 0.020%, Se: 0.0005 to 0.020%, and B: 0.0001 to 0.01% by weight, and the remainder comprising Fe and other inevitable impurities;
hot-rolling the slab to produce a hot-rolled sheet;
cold-rolling the hot-rolled sheet to produce a cold-rolled sheet;
primary recrystallization annealing the cold-rolled sheet; and
secondary recrystallization annealing the cold-rolled sheet which is the primary recrystallization annealed.
8 . The method of claim 7 , wherein,
the slab comprises 0.005 to 0.04 wt % of S and Se in a total amount.
9 . The method of claim 7 , wherein,
the slab further comprises Al: 0.010 wt % or less, Mn: 0.08 wt % or less and N: 0.005 wt % or less.
10 . The method of claim 7 , wherein,
the slab further comprises 0.005 wt % or less of at least one of Ti, Mg and Ca, respectively.
11 . The method of claim 7 , wherein,
a side edge crack of the hot-rolled sheet occurs 20 mm or less after the step of producing the hot-rolled sheet.
12 . The method of claim 7 , further comprising
a step of annealing the hot-rolled sheet after the step of producing the hot-rolled sheet.
13 . The method of claim 7 , wherein,
the step of cold-rolling the hot-rolled sheet to produce a cold-rolled sheet comprises a step of cold-rolling at least two times, and a step of intermediate annealing between cold-rolling.
14 . The method of claim 7 , wherein,
the step of secondary recrystallization annealing comprises a step of temperature-raising and a step of soaking, wherein the step of temperature-raising is performed in mixed atmosphere of nitrogen and hydrogen, and the step of soaking is performed in hydrogen atmosphere.
15 . The method of claim 14 , wherein,
the step of soaking is performed at a temperature of 1000 to 1250° C. for 20 hours or less.