IP Library Granted Patent US 11,299,799
Granted Patent B2
US 11,299,799 · App. 16/472,973 · Granted Apr 12, 2022

Austenitic stainless steel product having excellent surface properties and manufacturing method of the same

Inventors: Hyung Gu Kang (Pohang-si, KR); Jae-Hong Shim (Seoul, KR); Gyu Jin Jo (Pohang-si, KR); Dong Chul Chae (Pohang-si, KR)
Assignee: POSCO
C22C38/44C21D8/0205C21D8/0226C21D8/0236C21D8/0273C22C38/001C22C38/02C22C38/04C22C38/16C21D2211/001C21D2211/008
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Quick Facts
Patent No.
US 11,299,799
App. No.
16/472,973
Granted
Apr 12, 2022
Kind
B2
Abstract

An austenitic stainless steel product having excellent surface characteristics and a manufacturing method therefor are disclosed. The disclosed austenitic stainless steel product comprises an austenitic stainless steel comprising, by weight percent, 0.005 to 0.15% of C, 0.1 to 1.0% of Si, 0.1 to 2.0% of Mn, 6.0 to 8.0% of Ni, 16 to 18% of Cr, 0.1 to 4.0% of Cu, 0.005 to 0.2% of N, 0.01 to 0.2% of Mo, and the remainder comprising iron (Fe) and other unavoidable impurities, and a Ni surface negative segregation thereof defined by the following formula (1) is 0.6 to 0.9 and the martensite fraction thereof is 10 to 30%. (C Ni-Min )/(C Ni-Ave )  formula (1) Here, C Ni-min is the minimum concentration of Ni on the surface and C Ni-Ave is the average concentration of Ni on the surface.

Claims (22)

1. An austenitic stainless steel product, the stainless steel comprising:

by weight percent, 0.005 to 0.15% of C, 0.1 to 1.0% of Si, 0.1 to 2.0% of Mn, 6.0 to 8.0% of Ni, 16 to 18% of Cr, 0.1 to 4.0% of Cu, 0.005 to 0.2% of N, 0.01 to 0.2% of Mo, and the remainder comprising iron (Fe) and other unavoidable impurities, and a surface degree of negative segregation of Ni defined by the following formula (1) is in the range of 0.6 to 0.9 and the martensite fraction thereof is 10 to 30%

(CNi-Min)/(CNi-Ave)  Formula (1)

Where CNi-Min is the minimum concentration of Ni at the surface and CNi-Ave is the average concentration of Ni at the surface, and

wherein a surface hardness ratio defined by the following formula (2) is in the range of 1.1 to 1.6

A/B  Formula (2)

where A is the average value of the upper 10% of the product surface hardness, and B is the average value of the lower 10% the product surface hardness.

2. The austenitic stainless steel product according to claim 1 , wherein cracks having a depth of 20 μm or more from the surface is 10 or less.

3. The austenitic stainless steel product according to claim 1 , wherein a Ni surface segregation portion is less than 60% in area fraction and a Ni surface negative segregation portion is more than 5%.

4. A method of manufacturing an austenitic stainless steel product, the method comprising:

processing the austenitic stainless steel product, comprising:

by weight percent, 0.005 to 0.15% of C, 0.1 to 1.0% of Si, 0.1 to 2.0% of Mn, 6.0 to 8.0% of Ni, 16 to 18% of Cr, 0.1 to 4.0% of Cu, 0.005 to 0.2% of N, 0.01 to 0.2% of Mo, and the remainder comprising iron (Fe) and other unavoidable impurities; and

heat treating the austenitic stainless steel product at a temperature of 900-1,150° C. for 10 minutes or less; and

cooling the heat-treated austenitic stainless steel to 500° C. within 30 minutes;

wherein the austenitic stainless steel product has a surface degree of negative segregation of Ni defined by the following formula (1) is in the range of 0.6 to 0.9 and the martensite fraction thereof is 10 to 30%

(CNi-Min)/(CNi-Ave)  Formula (1)

Where CNi-Min is the minimum concentration of Ni at the surface and CNi-Ave is the average concentration of Ni at the surface, and

wherein a surface hardness ratio defined by the following formula (2) is in the range of 1.1 to 1.6

A/B  Formula (2)

where A is the average value of the upper 10% of the product surface hardness, and B is the average value of the lower 10% the product surface hardness.

5. The method of claim 4 , wherein the martensite fraction of the austenitic stainless steel product before the heat treatment is 10 to 50%.

6. The method of claim 5 , wherein the martensite fraction of the austenitic stainless steel product after cooling is 10 to 30%.

Assignments (3)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Oct 26, 2022
From: POSCO HOLDINGS INC.
To: POSCO CO., LTD
Reel/Frame 061778/0785 →
CHANGE OF NAME Recorded Sep 28, 2022
From: POSCO
To: POSCO HOLDINGS INC.
Reel/Frame 061561/0923 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Oct 22, 2020
From: KANG, HYUNG GU; SHIM, JAE-HONG; JO, GYU JIN; CHAE, DONG CHUL
To: POSCO
Reel/Frame 054134/0240 →
Priority Claims (1)
KR 10-2016-0177373 · Dec 23, 2016 · national
Continuity (1)
Related Publication 20200190643A1 · Jun 18, 2020