Electrical steel sheet adhesive coating composition, electrical steel sheet product, and manufacturing method therefor
An embodiment of the present invention provides: an adhesive coating composition capable of attaching (coupling) an electrical steel sheet without using an existing coupling method, such as welding, clamping, or interlocking; an electrical steel sheet laminate employing the same; and a manufacturing method therefor. The adhesive coating composition according to an embodiment of the present invention comprises: 40-95 wt % of a first component comprising an organic/inorganic composite in which inorganic nanoparticles are substituted in a water-soluble resin; 1-50 wt % of a second component comprising a composite metal phosphate; and 1-10 wt % of an additive.
1. An electrical steel sheet adhesive coating composition comprising,
with reference to an entire solid of 100 wt %:
10 to 50 wt % of a resin with a side chain including an aromatic hydrocarbon;
5 to 40 wt % of an organic/inorganic composite with inorganic nanoparticles substituted for the resin;
10 to 30 wt % of a composite metal phosphate including at least one of a first aluminum phosphate (Al(H 2 PO 4 ) 3 ), a first cobalt phosphate (Co(H 2 PO 4 ) 2 ), a first calcium phosphate (Ca(H 2 PO 4 ) 2 ), a first zinc phosphate (Zn(H 2 PO 4 ) 2 ), and a first magnesium phosphate (Mg(H 2 PO 4 ) 2 );
5 to 50 wt % of phosphoric acid; and
1 to 15 wt % of a cohesion reinforcing agent including at least one of an oxide, carbon nanotubes (CNT), carbon black, a pigment, and a coupling agent.
2. The electrical steel sheet adhesive coating composition of claim 1 , wherein
the aromatic hydrocarbon includes at least one of benzene, toluene, xylene, naphthalene, anthracene, and benzopyrene.
3. The electrical steel sheet adhesive coating composition of claim 1 , wherein
the resin includes at least one of an epoxy-based resin, a siloxane-based resin, an acryl-based resin, a phenol-based resin, a styrene-based resin, a vinyl-based resin, an ethylene-based resin, and a urethane-based resin.
4. The electrical steel sheet adhesive coating composition of claim 1 , wherein
the resin has a weight average molecular weight of 1000 to 100,000 and a softening point (Tg) of 30 to 150° C.
5. The electrical steel sheet adhesive coating composition of claim 1 , wherein
the inorganic nanoparticles include at least one of Sift, Al 2 O 3 , TiO 2 , MgO, ZnO, CaO, and ZrO 2 .
6. The electrical steel sheet adhesive coating composition of claim 1 , wherein
the inorganic nanoparticles are substituted in the organic/inorganic composite at 10 to 50 wt %.
7. An electrical steel sheet laminate comprising:
a plurality of electrical steel sheets; and
a thermal fusion layer provided between the plurality of electrical steel sheets,
wherein the thermal fusion layer includes:
10 to 50 wt % of a resin with a side chain including an aromatic hydrocarbon,
5 to 40 wt % of an organic/inorganic composite with inorganic nanoparticles substituted to the resin,
10 to 30 wt % of a composite metal phosphate including at least one of a first aluminum phosphate (Al(H 2 PO 4 ) 3 ), a first cobalt phosphate (Co(H 2 PO 4 ) 2 ), a first calcium phosphate (Ca(H 2 PO 4 ) 2 ), a first zinc phosphate (Zn(H 2 PO 4 ) 2 ), and a first magnesium phosphate (Mg(H 2 PO 4 ) 2 ),
5 to 50 wt % of a phosphoric acid, and
1 to 15 wt % of a cohesion reinforcing agent including at least one of an oxide, carbon nanotubes (CNT), carbon black, a pigment, and a coupling agent.