Polyamide-imide film and method for producing same
An embodiment can provide a polyamide-imide film and a method for producing same, the film comprising a polyamide-imide polymer formed by polymerizing an aromatic diamine compound, an aromatic dianhydride compound and a dicarbonyl compound, wherein, in an XRD graph with a section in which 2θ=8° to 32° as a baseline, the film shows a peak area of 50% or above around 2θ=23° with respect to a peak area seen around 2θ=15°.
1. A polyamide-imide film, which comprises a polyamide-imide polymer formed by polymerizing an aromatic diamine compound, an aromatic dianhydride compound, and a dicarbonyl compound, wherein the peak area in the vicinity of 2θ=23° is 65% or more based on the peak area in the vicinity of 2θ=15° when a base line is taken in the region between 2θ=8° and 32° in an XRD graph of the polyamide-imide film.
2. The polyamide-imide film of claim 1 , which has a modulus of 5.0 GPa or more based on a thickness of 50 μm.
3. The polyamide-imide film of claim 1 , which has a surface hardness of HB or higher.
4. The polyamide-imide film of claim 1 , which has a yellow index (YI) of 5 or less based on a thickness of 50 μm.
5. The polyamide-imide film of claim 1 , which has a haze of 2% or less based on a thickness of 50 μm.
6. The polyamide-imide film of claim 1 , which has a light transmittance measured at 550 nm of 85% or more based on a thickness of 50 μm.
7. The polyamide-imide film of claim 1 , wherein the aromatic dianhydride compound is composed of a compound having a fluorine-containing substituent.
8. The polyamide-imide film of claim 1 , wherein the aromatic diamine compound comprises 2,2′-bis(trifluoromethyl)-4,4′-diaminobiphenyl (TFDB), and the aromatic dianhydride compound comprises 2,2′-bis(3,4-dicarboxyphenyl) hexafluoropropane dianhydride (6-FDA).
9. The polyamide-imide film of claim 1 , wherein the molar ratio of the aromatic diamine compound to the aromatic dianhydride compound is 10:2 to 10:4.
10. The polyamide-imide film of claim 1 , wherein the dicarbonyl compound comprises at least two dicarbonyl compounds different from each other.
11. The polyamide-imide film of claim 1 , wherein the dicarbonyl compound comprises terephthaloyl chloride (TPC), 1,1′-biphenyl-4,4′-dicarbonyl dichloride (BPDC), or a combination thereof.